Probing the chain segment mobility at the interface of semi-crystalline polylactide/clay nanocomposites. Saiter, A., Delpouve, N., Dargent, E., Oberhauser, W., Conzatti, L., Cicogna, F., & Passaglia, E. European Polymer Journal, 78:274–289, 2016.
Probing the chain segment mobility at the interface of semi-crystalline polylactide/clay nanocomposites [link]Paper  doi  abstract   bibtex   
The concept of Cooperative Rearranging Region (CRR), an efficient probe of the interaction level in nanocomposites, has been used in Poly(lactic acid) (PLA)-based composites with phyllosilicates prepared in the melt with organomontmorillonite (O-MMT) and using poly(butylene adipate-co-terephthalate) (PBAT) as coupling agent. The samples were crystallized from various thermal treatments in order to obtain a wide range of morphologies and microstructures and accurately characterized by XRD, TEM, standard DSC and MT-DSC with the aim to highlight the effect of lamellae dispersion and distribution at nanoscale onto the thermal features of resulting nanocomposites. The presence of different interaction levels at the interface PLA/O-MMT, even tuned by the presence of PBAT, affects both the crystalline phase structure (by differently promoting crystallization of α and α′ forms) and the distribution between the amorphous fractions (rigid and mobile). The variations of molecular dynamics are classified in two categories depending on the composite microstructure. Only in amorphous materials the cooperativity is driven by the filler/matrix interactions. In semi-crystalline materials, the morphological features linked to the presence of O-MMT and PBAT are overwhelmed by the confinement of the amorphous phase. Comparison between the two crystallization modes evidences a stronger change in the glass transition dynamics for systems exhibiting preponderant nucleation and high percentage of rigid amorphous fraction.
@article{saiter_probing_2016,
	title = {Probing the chain segment mobility at the interface of semi-crystalline polylactide/clay nanocomposites},
	volume = {78},
	issn = {0014-3057},
	url = {http://www.sciencedirect.com/science/article/pii/S0014305716301422},
	doi = {10.1016/j.eurpolymj.2016.03.040},
	abstract = {The concept of Cooperative Rearranging Region (CRR), an efficient probe of the interaction level in nanocomposites, has been used in Poly(lactic acid) (PLA)-based composites with phyllosilicates prepared in the melt with organomontmorillonite (O-MMT) and using poly(butylene adipate-co-terephthalate) (PBAT) as coupling agent. The samples were crystallized from various thermal treatments in order to obtain a wide range of morphologies and microstructures and accurately characterized by XRD, TEM, standard DSC and MT-DSC with the aim to highlight the effect of lamellae dispersion and distribution at nanoscale onto the thermal features of resulting nanocomposites. The presence of different interaction levels at the interface PLA/O-MMT, even tuned by the presence of PBAT, affects both the crystalline phase structure (by differently promoting crystallization of α and α′ forms) and the distribution between the amorphous fractions (rigid and mobile). The variations of molecular dynamics are classified in two categories depending on the composite microstructure. Only in amorphous materials the cooperativity is driven by the filler/matrix interactions. In semi-crystalline materials, the morphological features linked to the presence of O-MMT and PBAT are overwhelmed by the confinement of the amorphous phase. Comparison between the two crystallization modes evidences a stronger change in the glass transition dynamics for systems exhibiting preponderant nucleation and high percentage of rigid amorphous fraction.},
	urldate = {2016-03-31},
	journal = {European Polymer Journal},
	author = {Saiter, A. and Delpouve, N. and Dargent, E. and Oberhauser, W. and Conzatti, L. and Cicogna, F. and Passaglia, E.},
	year = {2016},
	keywords = {Chain mobility, Cooperativity, Crystalline fractions, Exfoliated, PLA, nanocomposite},
	pages = {274--289}
}

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