Monomeric aluminum complex based on A3B-type mono-hydroxy-functionalized phthalocyanine and its stable supramolecular J-type dimer: Selective synthesis and physicochemical properties. Korostei, Y. S., Tolbin, A. Y., Dzuban, A. V., Pushkarev, V. E., Sedova, M. V., Maklakov, S. S., & Tomilova, L. G. Dyes and Pigments, 149:201–211, 2018.
Monomeric aluminum complex based on A3B-type mono-hydroxy-functionalized phthalocyanine and its stable supramolecular J-type dimer: Selective synthesis and physicochemical properties [link]Paper  doi  abstract   bibtex   
Efficient direct synthesis of new monomeric and stable J-type dimeric species of 2-hydroxy-9(10),16(17),23(24)-tri-tert-butylphthalocyaninato aluminum with high yields, including preparation of the corresponding dimeric free-base ligand at ambient conditions, has been developed. The compounds were characterized by the UV–Vis spectroscopy as well as MALDI-TOF mass-spectrometry and thermogravimetry data. The in-depth study of the produced aluminum complexes by 1D and 2D 1H NMR techniques was carried out owing to elaboration of disaggregating CD3ONa/CD3OD system featuring formation of phthalocyanine phenolate anions. Surface morphology of thin films formed by the complexes was studied by scanning (FE-SEM) and atomic force (AFM) microscopies. According to the AFM data, the films are characterized by granular structure, while the grain diameter accounts for 50 and 100 nm for the monomeric and dimeric complex, respectively.
@article{korostei_monomeric_2018,
	title = {Monomeric aluminum complex based on {A}3B-type mono-hydroxy-functionalized phthalocyanine and its stable supramolecular {J}-type dimer: {Selective} synthesis and physicochemical properties},
	volume = {149},
	issn = {0143-7208},
	url = {http://www.sciencedirect.com/science/article/pii/S0143720817315607},
	doi = {10.1016/j.dyepig.2017.09.066},
	abstract = {Efficient direct synthesis of new monomeric and stable J-type dimeric species of 2-hydroxy-9(10),16(17),23(24)-tri-tert-butylphthalocyaninato aluminum with high yields, including preparation of the corresponding dimeric free-base ligand at ambient conditions, has been developed. The compounds were characterized by the UV–Vis spectroscopy as well as MALDI-TOF mass-spectrometry and thermogravimetry data. The in-depth study of the produced aluminum complexes by 1D and 2D 1H NMR techniques was carried out owing to elaboration of disaggregating CD3ONa/CD3OD system featuring formation of phthalocyanine phenolate anions. Surface morphology of thin films formed by the complexes was studied by scanning (FE-SEM) and atomic force (AFM) microscopies. According to the AFM data, the films are characterized by granular structure, while the grain diameter accounts for 50 and 100 nm for the monomeric and dimeric complex, respectively.},
	language = {english},
	journal = {Dyes and Pigments},
	author = {Korostei, Yuliya S. and Tolbin, Alexander Yu and Dzuban, Alexander V. and Pushkarev, Victor E. and Sedova, Marina V. and Maklakov, Sergey S. and Tomilova, Larisa G.},
	year = {2018},
	pages = {201--211}
}

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