DART Fourier transform ion cyclotron resonance mass spectrometry for analysis of complex organic mixtures. Lobodin, V. V., Nyadong, L., Ruddy, B. M., Curtis, M., Jones, P. R., Rodgers, R. P., & Marshall, A. G. International Journal of Mass Spectrometry, 378:186–192, February, 2015.
Paper doi abstract bibtex We report the first combination of a commercial direct analysis in real time (DART) source with FT-ICR MS and its application to analysis of complex organic mixtures. DART enables ionization of compounds with little or no sample preparation, and FT-ICR provides ultrahigh mass resolution and mass accuracy. The combination provides a rapid, robust, and reliable method for analysis of components spanning a wide range of chemical functionality. DART 9.4 T FT-ICR MS generates abundant molecular or quasimolecular ions from C60, heavy petroleum, naphthenate deposits, and biotar, without fragmentation. Moreover, we demonstrate desorption/ionization of compounds with boiling points significantly higher than the DART source temperature. DART FT-ICR MS thus offers a new and useful atmospheric pressure ionization mass spectrometry technique for analysis of complex organic mixtures.
@article{lobodin_dart_2015,
title = {{DART} {Fourier} transform ion cyclotron resonance mass spectrometry for analysis of complex organic mixtures},
volume = {378},
issn = {13873806},
url = {http://linkinghub.elsevier.com/retrieve/pii/S1387380614003212},
doi = {10.1016/j.ijms.2014.07.050},
abstract = {We report the first combination of a commercial direct analysis in real time (DART) source with FT-ICR MS and its application to analysis of complex organic mixtures. DART enables ionization of compounds with little or no sample preparation, and FT-ICR provides ultrahigh mass resolution and mass accuracy. The combination provides a rapid, robust, and reliable method for analysis of components spanning a wide range of chemical functionality. DART 9.4 T FT-ICR MS generates abundant molecular or quasimolecular ions from C60, heavy petroleum, naphthenate deposits, and biotar, without fragmentation. Moreover, we demonstrate desorption/ionization of compounds with boiling points significantly higher than the DART source temperature. DART FT-ICR MS thus offers a new and useful atmospheric pressure ionization mass spectrometry technique for analysis of complex organic mixtures.},
language = {en},
urldate = {2016-01-28},
journal = {International Journal of Mass Spectrometry},
author = {Lobodin, Vladislav V. and Nyadong, Leonard and Ruddy, Brian M. and Curtis, Matthew and Jones, Patrick R. and Rodgers, Ryan P. and Marshall, Alan G.},
month = feb,
year = {2015},
pages = {186--192},
}
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