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\n  \n 2015\n \n \n (87)\n \n \n
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\n \n\n \n \n \n \n \n \n Dynamical arrest with zero complexity: The unusual behavior of the spherical Blume-Emery-Griffiths disordered model.\n \n \n \n \n\n\n \n Rainone, C.; Ferrari, U.; Paoluzzi, M.; and Leuzzi, L.\n\n\n \n\n\n\n Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, 92(6). 2015.\n cited By 0\n\n\n\n
\n\n\n\n \n \n \"DynamicalPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Rainone2015,\nauthor={Rainone, C. and Ferrari, U. and Paoluzzi, M. and Leuzzi, L.},\ntitle={Dynamical arrest with zero complexity: The unusual behavior of the spherical Blume-Emery-Griffiths disordered model},\njournal={Physical Review E - Statistical, Nonlinear, and Soft Matter Physics},\nyear={2015},\nvolume={92},\nnumber={6},\ndoi={10.1103/PhysRevE.92.062150},\nart_number={062150},\nnote={cited By 0},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84954161230&doi=10.1103%2fPhysRevE.92.062150&partnerID=40&md5=3372fe9ee1e654b135b568fb5fe4bc49},\nabstract={The short- and long-time dynamics of model systems undergoing a glass transition with apparent inversion of Kauzmann and dynamical arrest glass transition lines is investigated. These models belong to the class of the spherical mean-field approximation of a spin-1 model with p-body quenched disordered interaction, with p>2, termed spherical Blume-Emery-Griffiths models. Depending on temperature and chemical potential the system is found in a paramagnetic or in a glassy phase and the transition between these phases can be of a different nature. In specific regions of the phase diagram coexistence of low-density and high-density paramagnets can occur, as well as the coexistence of spin-glass and paramagnetic phases. The exact static solution for the glassy phase is known to be obtained by the one-step replica symmetry breaking ansatz. Different scenarios arise for both the dynamic and the thermodynamic transitions. These include: (i) the usual random first-order transition (Kauzmann-like) for mean-field glasses preceded by a dynamic transition, (ii) a thermodynamic first-order transition with phase coexistence and latent heat, and (iii) a regime of apparent inversion of static transition line and dynamic transition lines, the latter defined as a nonzero complexity line. The latter inversion, though, turns out to be preceded by a dynamical arrest line at higher temperature. Crossover between different regimes is analyzed by solving mode-coupling-theory equations near the boundaries of paramagnetic solutions and the relationship with the underlying statics is discussed. © 2015 American Physical Society.},\npublisher={American Physical Society},\nissn={15393755},\ncoden={PLEEE},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The short- and long-time dynamics of model systems undergoing a glass transition with apparent inversion of Kauzmann and dynamical arrest glass transition lines is investigated. These models belong to the class of the spherical mean-field approximation of a spin-1 model with p-body quenched disordered interaction, with p>2, termed spherical Blume-Emery-Griffiths models. Depending on temperature and chemical potential the system is found in a paramagnetic or in a glassy phase and the transition between these phases can be of a different nature. In specific regions of the phase diagram coexistence of low-density and high-density paramagnets can occur, as well as the coexistence of spin-glass and paramagnetic phases. The exact static solution for the glassy phase is known to be obtained by the one-step replica symmetry breaking ansatz. Different scenarios arise for both the dynamic and the thermodynamic transitions. These include: (i) the usual random first-order transition (Kauzmann-like) for mean-field glasses preceded by a dynamic transition, (ii) a thermodynamic first-order transition with phase coexistence and latent heat, and (iii) a regime of apparent inversion of static transition line and dynamic transition lines, the latter defined as a nonzero complexity line. The latter inversion, though, turns out to be preceded by a dynamical arrest line at higher temperature. Crossover between different regimes is analyzed by solving mode-coupling-theory equations near the boundaries of paramagnetic solutions and the relationship with the underlying statics is discussed. © 2015 American Physical Society.\n
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\n \n\n \n \n \n \n \n \n Soft Modes, Localization, and Two-Level Systems in Spin Glasses.\n \n \n \n \n\n\n \n Baity-Jesi, M.; Martín-Mayor, V.; Parisi, G.; and Perez-Gaviro, S.\n\n\n \n\n\n\n Physical Review Letters, 115(26). 2015.\n cited By 25\n\n\n\n
\n\n\n\n \n \n \"SoftPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Baity-Jesi2015,\nauthor={Baity-Jesi, M. and Martín-Mayor, V. and Parisi, G. and Perez-Gaviro, S.},\ntitle={Soft Modes, Localization, and Two-Level Systems in Spin Glasses},\njournal={Physical Review Letters},\nyear={2015},\nvolume={115},\nnumber={26},\ndoi={10.1103/PhysRevLett.115.267205},\nart_number={267205},\nnote={cited By 25},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84953333201&doi=10.1103%2fPhysRevLett.115.267205&partnerID=40&md5=d0a280faba98c5fc44863d43d4a2d0b1},\nabstract={In the three-dimensional Heisenberg spin glass in a random field, we study the properties of the inherent structures that are obtained by an instantaneous cooling from infinite temperature. For a not too large field the density of states g(ω) develops localized soft plastic modes and reaches zero as ω4 (for large fields a gap appears). When we perturb the system adding a force along the softest mode, one reaches very similar minima of the energy, separated by small barriers, that appear to be good candidates for classical two-level systems. © 2015 American Physical Society.},\npublisher={American Physical Society},\nissn={00319007},\ncoden={PRLTA},\npubmed_id={26765021},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n In the three-dimensional Heisenberg spin glass in a random field, we study the properties of the inherent structures that are obtained by an instantaneous cooling from infinite temperature. For a not too large field the density of states g(ω) develops localized soft plastic modes and reaches zero as ω4 (for large fields a gap appears). When we perturb the system adding a force along the softest mode, one reaches very similar minima of the energy, separated by small barriers, that appear to be good candidates for classical two-level systems. © 2015 American Physical Society.\n
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\n \n\n \n \n \n \n \n \n Ratiometric Organic Fibers for Localized and Reversible Ion Sensing with Micrometer-Scale Spatial Resolution.\n \n \n \n \n\n\n \n Del Mercato, L.; Moffa, M.; Rinaldi, R.; and Pisignano, D.\n\n\n \n\n\n\n Small, 11(48): 6417-6424. 2015.\n cited By 12\n\n\n\n
\n\n\n\n \n \n \"RatiometricPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{DelMercato20156417,\nauthor={Del Mercato, L.L. and Moffa, M. and Rinaldi, R. and Pisignano, D.},\ntitle={Ratiometric Organic Fibers for Localized and Reversible Ion Sensing with Micrometer-Scale Spatial Resolution},\njournal={Small},\nyear={2015},\nvolume={11},\nnumber={48},\npages={6417-6424},\ndoi={10.1002/smll.201502171},\nnote={cited By 12},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84954472297&doi=10.1002%2fsmll.201502171&partnerID=40&md5=c2fb162e4a3e343930d5abf0e8f44d79},\nabstract={A fundamental issue in biomedical and environmental sciences is the development of sensitive and robust sensors able to probe the analyte of interest, under physiological and pathological conditions or in environmental samples, and with very high spatial resolution. In this work, novel hybrid organic fibers that can effectively report the analyte concentration within the local microenvironment are reported. The nanostructured and flexible wires are prepared by embedding fluorescent pH sensors based on seminaphtho-rhodafluor-1-dextran conjugate. By adjusting capsule/polymer ratio and spinning conditions, the diameter of the fibers and the alignment of the reporting capsules are both tuned. The hybrid wires display excellent stability, high sensitivity, as well as reversible response, and their operation relies on effective diffusional kinetic coupling of the sensing regions and the embedding polymer matrix. These devices are believed to be a powerful new sensing platform for clinical diagnostics, bioassays and environmental monitoring. Novel pH-sensing organic fibers are prepared by capsule-based sensors. Appropriate choice of capsule loading during electrospinning ensures alignment within the fibers, leading to pH-sensing devices with excellent stability, high sensitivity, μm-spatial resolution as well as reversible response to proton switches. These results show a promising strategy for the development of sensitive and robust self-reporting fiber-optic sensors for bioassays and environmental monitoring. © 2015 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.},\npublisher={Wiley-VCH Verlag},\nissn={16136810},\ncoden={SMALB},\npubmed_id={26539625},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
\n
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\n A fundamental issue in biomedical and environmental sciences is the development of sensitive and robust sensors able to probe the analyte of interest, under physiological and pathological conditions or in environmental samples, and with very high spatial resolution. In this work, novel hybrid organic fibers that can effectively report the analyte concentration within the local microenvironment are reported. The nanostructured and flexible wires are prepared by embedding fluorescent pH sensors based on seminaphtho-rhodafluor-1-dextran conjugate. By adjusting capsule/polymer ratio and spinning conditions, the diameter of the fibers and the alignment of the reporting capsules are both tuned. The hybrid wires display excellent stability, high sensitivity, as well as reversible response, and their operation relies on effective diffusional kinetic coupling of the sensing regions and the embedding polymer matrix. These devices are believed to be a powerful new sensing platform for clinical diagnostics, bioassays and environmental monitoring. Novel pH-sensing organic fibers are prepared by capsule-based sensors. Appropriate choice of capsule loading during electrospinning ensures alignment within the fibers, leading to pH-sensing devices with excellent stability, high sensitivity, μm-spatial resolution as well as reversible response to proton switches. These results show a promising strategy for the development of sensitive and robust self-reporting fiber-optic sensors for bioassays and environmental monitoring. © 2015 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.\n
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\n \n\n \n \n \n \n \n \n Multiple approach to model unpaired spin density effects in H-ZSM5 zeolite with extra-framework O atom: H-abstraction reaction from methane.\n \n \n \n \n\n\n \n Rutigliano, M.; Sanna, N.; and Palma, A.\n\n\n \n\n\n\n Computational and Theoretical Chemistry, 1074: 9-18. 2015.\n cited By 3\n\n\n\n
\n\n\n\n \n \n \"MultiplePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Rutigliano20159,\nauthor={Rutigliano, M. and Sanna, N. and Palma, A.},\ntitle={Multiple approach to model unpaired spin density effects in H-ZSM5 zeolite with extra-framework O atom: H-abstraction reaction from methane},\njournal={Computational and Theoretical Chemistry},\nyear={2015},\nvolume={1074},\npages={9-18},\ndoi={10.1016/j.comptc.2015.10.002},\nnote={cited By 3},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84944744341&doi=10.1016%2fj.comptc.2015.10.002&partnerID=40&md5=944aa5ef714f2ca73f18b170ba63cfc9},\nabstract={The interaction of methane with an extra-framework oxygen atom in acidic zeolite (H-ZSM5) porous substrate has been investigated by means of different state of the art calculations using two model systems in their triplet spin state: zeolite was modelled both by its crystallographic structure subject to periodic boundary condition and by cluster approach in gas-phase. We have evaluated the energetics of H-abstraction reaction from methane within the (0. 1. 0) straight channel of acidic zeolite by different computational approaches. First by in bulk plane waves Density Functional Theory (with and without dispersion energy correction) and then, in gas-phase cluster, by typical quantum chemistry approaches based on molecular orbital theory, where electronic wave function is expanded in Gaussian basis sets, within variational or perturbative schemes. Reaction paths have been determined either by Climbing Image Nudged Elastic Band method (c-NEB) in bulk or by Intrinsic Reaction Coordinate (IRC) method in gas phase. Transition State has been characterized in cluster models using Becke-3-Lee Yang Parr (B3LYP) and BeckeHalf&HalfLeeYangParr (BHLYP) hybrid functionals. Calculated energy barriers and all results allow an interesting vis-à-vis of commonly used, alternative, often exclusive models. This study indicates that open shell systems composed of O atoms and H-ZSM5 are worth to be considered in H-abstraction from small hydrocarbons in applicative processes. © 2015 Elsevier B.V.},\npublisher={Elsevier},\nissn={2210271X},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
\n
\n\n\n
\n The interaction of methane with an extra-framework oxygen atom in acidic zeolite (H-ZSM5) porous substrate has been investigated by means of different state of the art calculations using two model systems in their triplet spin state: zeolite was modelled both by its crystallographic structure subject to periodic boundary condition and by cluster approach in gas-phase. We have evaluated the energetics of H-abstraction reaction from methane within the (0. 1. 0) straight channel of acidic zeolite by different computational approaches. First by in bulk plane waves Density Functional Theory (with and without dispersion energy correction) and then, in gas-phase cluster, by typical quantum chemistry approaches based on molecular orbital theory, where electronic wave function is expanded in Gaussian basis sets, within variational or perturbative schemes. Reaction paths have been determined either by Climbing Image Nudged Elastic Band method (c-NEB) in bulk or by Intrinsic Reaction Coordinate (IRC) method in gas phase. Transition State has been characterized in cluster models using Becke-3-Lee Yang Parr (B3LYP) and BeckeHalf&HalfLeeYangParr (BHLYP) hybrid functionals. Calculated energy barriers and all results allow an interesting vis-à-vis of commonly used, alternative, often exclusive models. This study indicates that open shell systems composed of O atoms and H-ZSM5 are worth to be considered in H-abstraction from small hydrocarbons in applicative processes. © 2015 Elsevier B.V.\n
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\n \n\n \n \n \n \n \n \n Intramolecular catalyst transfer polymerisation of conjugated monomers: From lessons learned to future challenges.\n \n \n \n \n\n\n \n Grisorio, R.; and Suranna, G.\n\n\n \n\n\n\n Polymer Chemistry, 6(45): 7781-7795. 2015.\n cited By 33\n\n\n\n
\n\n\n\n \n \n \"IntramolecularPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Grisorio20157781,\nauthor={Grisorio, R. and Suranna, G.P.},\ntitle={Intramolecular catalyst transfer polymerisation of conjugated monomers: From lessons learned to future challenges},\njournal={Polymer Chemistry},\nyear={2015},\nvolume={6},\nnumber={45},\npages={7781-7795},\ndoi={10.1039/c5py01042j},\nnote={cited By 33},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947068970&doi=10.1039%2fc5py01042j&partnerID=40&md5=f28f027074e191138fcbc71f97cb9d52},\nabstract={2015 marks the 11th anniversary of the independent discovery carried out by McCullough and Yokozawa for obtaining regio-regular poly(3-alkylthiophene)s with defined molecular weights and distributions via chain-growth Ni-catalysed polymerisations of suitable AB-type organometallic monomers. This finding stirred a tremendous interest in catalyst transfer polycondensations (CTPs) that has resulted in a remarkable broadening of its scope. In this contribution, we will provide our view on the lessons that can be drawn from the major aspects influencing CTPs, indicating, especially in light of the most recent reports, plausible research outlooks for the near future. © The Royal Society of Chemistry 2015.},\npublisher={Royal Society of Chemistry},\nissn={17599954},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n 2015 marks the 11th anniversary of the independent discovery carried out by McCullough and Yokozawa for obtaining regio-regular poly(3-alkylthiophene)s with defined molecular weights and distributions via chain-growth Ni-catalysed polymerisations of suitable AB-type organometallic monomers. This finding stirred a tremendous interest in catalyst transfer polycondensations (CTPs) that has resulted in a remarkable broadening of its scope. In this contribution, we will provide our view on the lessons that can be drawn from the major aspects influencing CTPs, indicating, especially in light of the most recent reports, plausible research outlooks for the near future. © The Royal Society of Chemistry 2015.\n
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\n \n\n \n \n \n \n \n \n Real-space collapse of a polariton condensate.\n \n \n \n \n\n\n \n Dominici, L.; Petrov, M.; Matuszewski, M.; Ballarini, D.; De Giorgi, M.; Colas, D.; Cancellieri, E.; Silva Fernández, B.; Bramati, A.; Gigli, G.; Kavokin, A.; Laussy, F.; and Sanvitto, D.\n\n\n \n\n\n\n Nature Communications, 6. 2015.\n cited By 38\n\n\n\n
\n\n\n\n \n \n \"Real-spacePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Dominici2015,\nauthor={Dominici, L. and Petrov, M. and Matuszewski, M. and Ballarini, D. and De Giorgi, M. and Colas, D. and Cancellieri, E. and Silva Fernández, B. and Bramati, A. and Gigli, G. and Kavokin, A. and Laussy, F. and Sanvitto, D.},\ntitle={Real-space collapse of a polariton condensate},\njournal={Nature Communications},\nyear={2015},\nvolume={6},\ndoi={10.1038/ncomms9993},\nart_number={8993},\nnote={cited By 38},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84949208761&doi=10.1038%2fncomms9993&partnerID=40&md5=a3aa8e29896b6aaa21c6158e9bdc31d0},\nabstract={Microcavity polaritons are two-dimensional bosonic fluids with strong nonlinearities, composed of coupled photonic and electronic excitations. In their condensed form, they display quantum hydrodynamic features similar to atomic Bose-Einstein condensates, such as long-range coherence, superfluidity and quantized vorticity. Here we report the unique phenomenology that is observed when a pulse of light impacts the polariton vacuum: the fluid which is suddenly created does not splash but instead coheres into a very bright spot. The real-space collapse into a sharp peak is at odd with the repulsive interactions of polaritons and their positive mass, suggesting that an unconventional mechanism is at play. Our modelling devises a possible explanation in the self-trapping due to a local heating of the crystal lattice, that can be described as a collective polaron formed by a polariton condensate. These observations hint at the polariton fluid dynamics in conditions of extreme intensities and ultrafast times.},\npublisher={Nature Publishing Group},\nissn={20411723},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Microcavity polaritons are two-dimensional bosonic fluids with strong nonlinearities, composed of coupled photonic and electronic excitations. In their condensed form, they display quantum hydrodynamic features similar to atomic Bose-Einstein condensates, such as long-range coherence, superfluidity and quantized vorticity. Here we report the unique phenomenology that is observed when a pulse of light impacts the polariton vacuum: the fluid which is suddenly created does not splash but instead coheres into a very bright spot. The real-space collapse into a sharp peak is at odd with the repulsive interactions of polaritons and their positive mass, suggesting that an unconventional mechanism is at play. Our modelling devises a possible explanation in the self-trapping due to a local heating of the crystal lattice, that can be described as a collective polaron formed by a polariton condensate. These observations hint at the polariton fluid dynamics in conditions of extreme intensities and ultrafast times.\n
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\n \n\n \n \n \n \n \n \n Characterization of amphiphilic block-copolymers constituted of a low band gap rigid segment (PCPDTBT) and P4VP based coil block synthesized by two different strategies.\n \n \n \n \n\n\n \n Zappia, S.; Mendichi, R.; Battiato, S.; Scavia, G.; Mastria, R.; Samperi, F.; and Destri, S.\n\n\n \n\n\n\n Polymer, 80: 245-258. 2015.\n cited By 5\n\n\n\n
\n\n\n\n \n \n \"CharacterizationPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Zappia2015245,\nauthor={Zappia, S. and Mendichi, R. and Battiato, S. and Scavia, G. and Mastria, R. and Samperi, F. and Destri, S.},\ntitle={Characterization of amphiphilic block-copolymers constituted of a low band gap rigid segment (PCPDTBT) and P4VP based coil block synthesized by two different strategies},\njournal={Polymer},\nyear={2015},\nvolume={80},\npages={245-258},\ndoi={10.1016/j.polymer.2015.10.062},\nnote={cited By 5},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947067220&doi=10.1016%2fj.polymer.2015.10.062&partnerID=40&md5=0ab532c706efdb4115eff703b2d3d8a0},\nabstract={Two homologous series of rod-coil block-copolymers, composed by a low band gap rod moiety (poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b:3.4-b']dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)], PCPDTBT) and a flexible poly(4-vinylpyridine) based polar block, were synthesized by two different approaches. Step Growth-like procedure provided copolymers with longer coil, whilst copolymers with longer rod arise from Chain Growth-like process. Both the series were deeply investigated with different analytical techniques (1H NMR, SEC-DV, and MALDI-TOF MS) in order to prove the coupling process and elucidate the composition of the obtained materials. Chemical composition was evaluated by 1H NMR analysis. DSC heating traces of rod-coil copolymers synthesized by Step Growth-like route present two well resolved glass transition temperatures corresponding to the rod and coil blocks. The low band-gap rod-coil block copolymers especially these with short coil can find application in hybrid solar cells. © 2015 Elsevier B.V. All rights reserved.},\npublisher={Elsevier Ltd},\nissn={00323861},\ncoden={POLMA},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Two homologous series of rod-coil block-copolymers, composed by a low band gap rod moiety (poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b:3.4-b']dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)], PCPDTBT) and a flexible poly(4-vinylpyridine) based polar block, were synthesized by two different approaches. Step Growth-like procedure provided copolymers with longer coil, whilst copolymers with longer rod arise from Chain Growth-like process. Both the series were deeply investigated with different analytical techniques (1H NMR, SEC-DV, and MALDI-TOF MS) in order to prove the coupling process and elucidate the composition of the obtained materials. Chemical composition was evaluated by 1H NMR analysis. DSC heating traces of rod-coil copolymers synthesized by Step Growth-like route present two well resolved glass transition temperatures corresponding to the rod and coil blocks. The low band-gap rod-coil block copolymers especially these with short coil can find application in hybrid solar cells. © 2015 Elsevier B.V. All rights reserved.\n
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\n \n\n \n \n \n \n \n \n Synthesis of biocompatible polymeric nano-capsules based on calcium carbonate: A potential cisplatin delivery system.\n \n \n \n \n\n\n \n Vergaro, V.; Papadia, P.; Leporatti, S.; De Pascali, S.; Fanizzi, F.; and Ciccarella, G.\n\n\n \n\n\n\n Journal of Inorganic Biochemistry, 153: 284-292. 2015.\n cited By 22\n\n\n\n
\n\n\n\n \n \n \"SynthesisPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Vergaro2015284,\nauthor={Vergaro, V. and Papadia, P. and Leporatti, S. and De Pascali, S.A. and Fanizzi, F.P. and Ciccarella, G.},\ntitle={Synthesis of biocompatible polymeric nano-capsules based on calcium carbonate: A potential cisplatin delivery system},\njournal={Journal of Inorganic Biochemistry},\nyear={2015},\nvolume={153},\npages={284-292},\ndoi={10.1016/j.jinorgbio.2015.10.014},\nnote={cited By 22},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84951179534&doi=10.1016%2fj.jinorgbio.2015.10.014&partnerID=40&md5=12214f3669ca1bdc3add0d0f497a9735},\nabstract={A smart nanocarrier system for cancer therapy, based on a recently developed technique for preparing pure nanometric calcium carbonate (CaCO3), was studied. Different approaches were used to obtain sustained release of cisplatin: at first, pure CaCO3 nanoparticles were evaluated as carriers, then the nanoparticles were functionalized with polymer or silanes, and finally they were employed as a substrate to build layer by layer (LbL) self-assembled polyelectrolyte nanocapsules. Loading efficiency and release kinetics were measured. The best loadings were obtained with the LbL nanocapsules, allowing for high loading efficiency and the possibility of controlling the release rate of the drug. The behavior of all the carriers was evaluated on four neoplastic cell lines, representative of different types of neoplastic disease, namely MCF-7 (breast cancer), SKOV-3 (ovarian cancer), HeLa (cervical cancer) and CACO-2 (human epithelial colorectal adenocarcinoma). Negligible cytotoxicity of the nanoparticles, functionalized nanoparticles, and nanocapsules was observed in experiments with all cell lines. Nanocapsules were functionalized with fluorescein isothiocyanate (FITC) in order to track their kinetic of internalization and localization in the cell line by confocal laser scanning microscopy (CLSM). The cytotoxicity of the loaded capsules was evaluated, showing cell survival rates close to those expected for non-encapsulated cisplatin at the same nominal concentration. © 2015 Elsevier Inc.},\npublisher={Elsevier Inc.},\nissn={01620134},\ncoden={JIBID},\npubmed_id={26560986},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n A smart nanocarrier system for cancer therapy, based on a recently developed technique for preparing pure nanometric calcium carbonate (CaCO3), was studied. Different approaches were used to obtain sustained release of cisplatin: at first, pure CaCO3 nanoparticles were evaluated as carriers, then the nanoparticles were functionalized with polymer or silanes, and finally they were employed as a substrate to build layer by layer (LbL) self-assembled polyelectrolyte nanocapsules. Loading efficiency and release kinetics were measured. The best loadings were obtained with the LbL nanocapsules, allowing for high loading efficiency and the possibility of controlling the release rate of the drug. The behavior of all the carriers was evaluated on four neoplastic cell lines, representative of different types of neoplastic disease, namely MCF-7 (breast cancer), SKOV-3 (ovarian cancer), HeLa (cervical cancer) and CACO-2 (human epithelial colorectal adenocarcinoma). Negligible cytotoxicity of the nanoparticles, functionalized nanoparticles, and nanocapsules was observed in experiments with all cell lines. Nanocapsules were functionalized with fluorescein isothiocyanate (FITC) in order to track their kinetic of internalization and localization in the cell line by confocal laser scanning microscopy (CLSM). The cytotoxicity of the loaded capsules was evaluated, showing cell survival rates close to those expected for non-encapsulated cisplatin at the same nominal concentration. © 2015 Elsevier Inc.\n
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\n \n\n \n \n \n \n \n \n Vortex and half-vortex dynamics in a nonlinear spinor quantum fluid.\n \n \n \n \n\n\n \n Dominici, L.; Dagvadorj, G.; Fellows, J.; Ballarini, D.; De Giorgi, M.; Marchetti, F.; Piccirillo, B.; Marrucci, L.; Bramati, A.; Gigli, G.; Szymañska, M.; and Sanvitto, D.\n\n\n \n\n\n\n Science Advances, 1(11). 2015.\n cited By 34\n\n\n\n
\n\n\n\n \n \n \"VortexPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Dominici2015,\nauthor={Dominici, L. and Dagvadorj, G. and Fellows, J.M. and Ballarini, D. and De Giorgi, M. and Marchetti, F.M. and Piccirillo, B. and Marrucci, L. and Bramati, A. and Gigli, G. and Szymañska, M.H. and Sanvitto, D.},\ntitle={Vortex and half-vortex dynamics in a nonlinear spinor quantum fluid},\njournal={Science Advances},\nyear={2015},\nvolume={1},\nnumber={11},\ndoi={10.1126/sciadv.1500807},\nart_number={e1500807},\nnote={cited By 34},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84962299058&doi=10.1126%2fsciadv.1500807&partnerID=40&md5=4e9e4ebaec2b4a46cdbdbea7816b3b0c},\nabstract={Vortices are archetypal objects that recur in the universe across the scale of complexity, from subatomic particles to galaxies and black holes. Their appearance is connected with spontaneous symmetry breaking and phase transitions. In Bose-Einstein condensates and superfluids, vortices are both point-like and quantized quasiparticles. We use a two-dimensional (2D) fluid of polaritons, bosonic particles constituted by hybrid photonic and electronic oscillations, to study quantum vortex dynamics. Polaritons benefit from easiness of wave function phase detection, a spinor nature sustaining half-integer vorticity, strong nonlinearity, and tuning of the background disorder. We can directly generate by resonant pulsed excitations a polariton condensate carrying either a full or half-integer vortex as initial condition and follow their coherent evolution using ultrafast imaging on the picosecond scale. The observations highlight a rich phenomenology, such as the spiraling of the half-vortex and the joint path of the twin charges of a full vortex, until the moment of their splitting. Furthermore, we observe the ordered branching into newly generated secondary couples, associatedwith the breaking of radial and azimuthal symmetries. This allows us to devise the interplay of nonlinearity and sample disorder in shaping the fluid and driving the vortex dynamics. In addition, our observations suggest that phase singularitiesmay be seen as fundamental particles whose quantized events span from pair creation and recombination to 2D+t topological vortex strings. © 2015 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science.},\npublisher={American Association for the Advancement of Science},\nissn={23752548},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Vortices are archetypal objects that recur in the universe across the scale of complexity, from subatomic particles to galaxies and black holes. Their appearance is connected with spontaneous symmetry breaking and phase transitions. In Bose-Einstein condensates and superfluids, vortices are both point-like and quantized quasiparticles. We use a two-dimensional (2D) fluid of polaritons, bosonic particles constituted by hybrid photonic and electronic oscillations, to study quantum vortex dynamics. Polaritons benefit from easiness of wave function phase detection, a spinor nature sustaining half-integer vorticity, strong nonlinearity, and tuning of the background disorder. We can directly generate by resonant pulsed excitations a polariton condensate carrying either a full or half-integer vortex as initial condition and follow their coherent evolution using ultrafast imaging on the picosecond scale. The observations highlight a rich phenomenology, such as the spiraling of the half-vortex and the joint path of the twin charges of a full vortex, until the moment of their splitting. Furthermore, we observe the ordered branching into newly generated secondary couples, associatedwith the breaking of radial and azimuthal symmetries. This allows us to devise the interplay of nonlinearity and sample disorder in shaping the fluid and driving the vortex dynamics. In addition, our observations suggest that phase singularitiesmay be seen as fundamental particles whose quantized events span from pair creation and recombination to 2D+t topological vortex strings. © 2015 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science.\n
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\n \n\n \n \n \n \n \n \n Enhancement of surface electrical current on silicon via nanodiamond particles deposited by pulsed spray technique.\n \n \n \n \n\n\n \n Cicala, G.; Massaro, A.; Velardi, L.; Senesi, G.; Perna, G.; Marzulli, D.; Melisi, D.; De Pascali, G.; Valentini, A.; and Capozzi, V.\n\n\n \n\n\n\n Physica Status Solidi (A) Applications and Materials Science, 212(12): 2862-2868. 2015.\n cited By 10\n\n\n\n
\n\n\n\n \n \n \"EnhancementPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Cicala20152862,\nauthor={Cicala, G. and Massaro, A. and Velardi, L. and Senesi, G.S. and Perna, G. and Marzulli, D. and Melisi, D. and De Pascali, G. and Valentini, A. and Capozzi, V.},\ntitle={Enhancement of surface electrical current on silicon via nanodiamond particles deposited by pulsed spray technique},\njournal={Physica Status Solidi (A) Applications and Materials Science},\nyear={2015},\nvolume={212},\nnumber={12},\npages={2862-2868},\ndoi={10.1002/pssa.201532080},\nnote={cited By 10},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84949729195&doi=10.1002%2fpssa.201532080&partnerID=40&md5=0df00a03a0e5f8a7bfe0477b80c28e03},\nabstract={The deposition of as-received nanodiamond (ND) particles on silicon substrate was performed by the pulsed spray technique, using a dispersion of 250 nm ND in 1,2-dichloroethane. A set of samples was sprayed by varying the number of pulses from 1 to 500. The morphology of the samples was characterized and monitored by means of optical, atomic force, and confocal microscopies. At a low number of pulses, sparse diamond particles were observed, whereas at a high number of pulses dense/quasi-continuous ND layers were formed. The electrical conductivity measurements of surface silicon substrate evidenced a remarkable change for the presence of ND particles. This behavior is also found by theoretical simulations (finite element method). Finally, a comparison between the electrical resistances measured on these samples versus the pulse number and the inverse current density calculated as a function of the number of ND particles, showed a good agreement. The experimental results highlighted an increase of the electrical current by using a number of pulses &lt;100, whereas the simulation results proved the enhancement of current density and its surface rectification by employing a specific number of particles. The current increased by increasing the temperature and during the heating-cooling cycles hysteresis was observed. (a) Scheme of the sprayed ND particles on silicon substrate, (b) 3D AFM image 5 × 5 μm2 of 10 pulses sample, (c) trends of measured R and calculated 1/J. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.},\npublisher={Wiley-VCH Verlag},\nissn={18626300},\ncoden={PSSAB},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The deposition of as-received nanodiamond (ND) particles on silicon substrate was performed by the pulsed spray technique, using a dispersion of 250 nm ND in 1,2-dichloroethane. A set of samples was sprayed by varying the number of pulses from 1 to 500. The morphology of the samples was characterized and monitored by means of optical, atomic force, and confocal microscopies. At a low number of pulses, sparse diamond particles were observed, whereas at a high number of pulses dense/quasi-continuous ND layers were formed. The electrical conductivity measurements of surface silicon substrate evidenced a remarkable change for the presence of ND particles. This behavior is also found by theoretical simulations (finite element method). Finally, a comparison between the electrical resistances measured on these samples versus the pulse number and the inverse current density calculated as a function of the number of ND particles, showed a good agreement. The experimental results highlighted an increase of the electrical current by using a number of pulses <100, whereas the simulation results proved the enhancement of current density and its surface rectification by employing a specific number of particles. The current increased by increasing the temperature and during the heating-cooling cycles hysteresis was observed. (a) Scheme of the sprayed ND particles on silicon substrate, (b) 3D AFM image 5 × 5 μm2 of 10 pulses sample, (c) trends of measured R and calculated 1/J. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.\n
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\n \n\n \n \n \n \n \n \n Investigation of air-DBD effects on biological liquids for in vitro studies on eukaryotic cells.\n \n \n \n \n\n\n \n Trizio, I.; Sardella, E.; Francioso, E.; Dilecce, G.; Rizzi, V.; Cosma, P.; Schmidt, M.; Hänsch, M.; von Woedtke, T.; Favia, P.; and Gristina, R.\n\n\n \n\n\n\n Clinical Plasma Medicine, 3(2): 62-71. 2015.\n cited By 8\n\n\n\n
\n\n\n\n \n \n \"InvestigationPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Trizio201562,\nauthor={Trizio, I. and Sardella, E. and Francioso, E. and Dilecce, G. and Rizzi, V. and Cosma, P. and Schmidt, M. and Hänsch, M. and von Woedtke, T. and Favia, P. and Gristina, R.},\ntitle={Investigation of air-DBD effects on biological liquids for in vitro studies on eukaryotic cells},\njournal={Clinical Plasma Medicine},\nyear={2015},\nvolume={3},\nnumber={2},\npages={62-71},\ndoi={10.1016/j.cpme.2015.09.003},\nnote={cited By 8},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84949794660&doi=10.1016%2fj.cpme.2015.09.003&partnerID=40&md5=eb44210990ecd9569be16bb7788fcc18},\nabstract={Atmospheric pressure (AP) Dielectric Barrier Discharges (DBD) generated in air were performed on water, Phosphate Buffer Saline (PBS) and Dulbecco's Modified Eagle's Medium (DMEM) in order to evaluate their potential to generate hydrogen peroxide (H2O2), nitrite (NO2-) and nitrate (NO3-) species. Differences in cell growth and morphology were found in two different types of eukaryotic cells, immortal and stem cells, incubated for 1h in plasma treated DMEM, revealing a selectivity of the treatment. © 2015 Elsevier GmbH.},\npublisher={Elsevier GmbH},\nissn={22128166},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Atmospheric pressure (AP) Dielectric Barrier Discharges (DBD) generated in air were performed on water, Phosphate Buffer Saline (PBS) and Dulbecco's Modified Eagle's Medium (DMEM) in order to evaluate their potential to generate hydrogen peroxide (H2O2), nitrite (NO2-) and nitrate (NO3-) species. Differences in cell growth and morphology were found in two different types of eukaryotic cells, immortal and stem cells, incubated for 1h in plasma treated DMEM, revealing a selectivity of the treatment. © 2015 Elsevier GmbH.\n
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\n \n\n \n \n \n \n \n \n Two-fluid numerical simulations of turbulence inside Kelvin-Helmholtz vortices: Intermittency and reconnecting current sheets.\n \n \n \n \n\n\n \n Rossi, C.; Califano, F.; Retinò, A.; Sorriso-Valvo, L.; Henri, P.; Servidio, S.; Valentini, F.; Chasapis, A.; and Rezeau, L.\n\n\n \n\n\n\n Physics of Plasmas, 22(12). 2015.\n cited By 10\n\n\n\n
\n\n\n\n \n \n \"Two-fluidPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Rossi2015,\nauthor={Rossi, C. and Califano, F. and Retinò, A. and Sorriso-Valvo, L. and Henri, P. and Servidio, S. and Valentini, F. and Chasapis, A. and Rezeau, L.},\ntitle={Two-fluid numerical simulations of turbulence inside Kelvin-Helmholtz vortices: Intermittency and reconnecting current sheets},\njournal={Physics of Plasmas},\nyear={2015},\nvolume={22},\nnumber={12},\ndoi={10.1063/1.4936795},\nart_number={122303},\nnote={cited By 10},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84950154831&doi=10.1063%2f1.4936795&partnerID=40&md5=c805119f092e4071713fc48d46469a9b},\nabstract={The turbulence developing inside Kelvin-Helmholtz vortices has been studied using a two-fluid numerical simulation. From an initial large-scale velocity shear, the nonlinear evolution of the instability leads to the formation of a region inside the initial vortex characterized by small-scale fluctuations and structures. The magnetic energy spectrum is compatible with a Kolmogorov-like power-law decay, followed by a steeper power-law below proton scales, in agreement with other studies. The magnetic field increments show non-Gaussian distributions with increasing tails going towards smaller scales, consistent with presence of intermittency. The strong magnetic field fluctuations populating the tails of the distributions have been identified as current sheets by using the Partial Variance of the Increments (PVI) method. The strongest current sheets (largest PVI) appear around proton scales and below. By selecting several of such current sheets, it has been found that most of them are consistent with ongoing magnetic reconnection. The detailed study of one reconnecting current sheet as crossed by a virtual spacecraft is also presented. Inflow and outflow regions have been identified and the reconnection rate has been estimated. The observation of reconnection rates higher than typical fast rate ∼0.1 suggests that reconnection in turbulent plasma can be faster than laminar reconnection. This study indicates that intermittency and reconnecting current sheets are important ingredients of turbulence within Kelvin-Helmholtz vortices and that reconnection can play an important role for energy dissipation therein. © 2015 AIP Publishing LLC.},\npublisher={American Institute of Physics Inc.},\nissn={1070664X},\ncoden={PHPAE},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The turbulence developing inside Kelvin-Helmholtz vortices has been studied using a two-fluid numerical simulation. From an initial large-scale velocity shear, the nonlinear evolution of the instability leads to the formation of a region inside the initial vortex characterized by small-scale fluctuations and structures. The magnetic energy spectrum is compatible with a Kolmogorov-like power-law decay, followed by a steeper power-law below proton scales, in agreement with other studies. The magnetic field increments show non-Gaussian distributions with increasing tails going towards smaller scales, consistent with presence of intermittency. The strong magnetic field fluctuations populating the tails of the distributions have been identified as current sheets by using the Partial Variance of the Increments (PVI) method. The strongest current sheets (largest PVI) appear around proton scales and below. By selecting several of such current sheets, it has been found that most of them are consistent with ongoing magnetic reconnection. The detailed study of one reconnecting current sheet as crossed by a virtual spacecraft is also presented. Inflow and outflow regions have been identified and the reconnection rate has been estimated. The observation of reconnection rates higher than typical fast rate ∼0.1 suggests that reconnection in turbulent plasma can be faster than laminar reconnection. This study indicates that intermittency and reconnecting current sheets are important ingredients of turbulence within Kelvin-Helmholtz vortices and that reconnection can play an important role for energy dissipation therein. © 2015 AIP Publishing LLC.\n
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\n \n\n \n \n \n \n \n \n The glassy random laser: Replica symmetry breaking in the intensity fluctuations of emission spectra.\n \n \n \n \n\n\n \n Antenucci, F.; Crisanti, A.; and Leuzzi, L.\n\n\n \n\n\n\n Scientific Reports, 5. 2015.\n cited By 26\n\n\n\n
\n\n\n\n \n \n \"ThePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Antenucci2015,\nauthor={Antenucci, F. and Crisanti, A. and Leuzzi, L.},\ntitle={The glassy random laser: Replica symmetry breaking in the intensity fluctuations of emission spectra},\njournal={Scientific Reports},\nyear={2015},\nvolume={5},\ndoi={10.1038/srep16792},\nart_number={16792},\nnote={cited By 26},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84948665261&doi=10.1038%2fsrep16792&partnerID=40&md5=74a4a5ac322338b46bf9a76635fa58df},\nabstract={The behavior of a newly introduced overlap parameter, measuring the correlation between intensity fluctuations of waves in random media, is analyzed in different physical regimes, with varying amount of disorder and non-linearity. This order parameter allows to identify the laser transition in random media and describes its possible glassy nature in terms of emission spectra data, the only data so far accessible in random laser measurements. The theoretical analysis is performed in terms of the complex spherical spin-glass model, a statistical mechanical model describing the onset and the behavior of random lasers in open cavities. Replica Symmetry Breaking theory allows to discern different kinds of randomness in the high pumping regime, including the most complex and intriguing glassy randomness. The outcome of the theoretical study is, eventually, compared to recent intensity fluctuation overlap measurements demonstrating the validity of the theory and providing a straightforward interpretation of qualitatively different spectral behaviors in different random lasers.},\npublisher={Nature Publishing Group},\nissn={20452322},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The behavior of a newly introduced overlap parameter, measuring the correlation between intensity fluctuations of waves in random media, is analyzed in different physical regimes, with varying amount of disorder and non-linearity. This order parameter allows to identify the laser transition in random media and describes its possible glassy nature in terms of emission spectra data, the only data so far accessible in random laser measurements. The theoretical analysis is performed in terms of the complex spherical spin-glass model, a statistical mechanical model describing the onset and the behavior of random lasers in open cavities. Replica Symmetry Breaking theory allows to discern different kinds of randomness in the high pumping regime, including the most complex and intriguing glassy randomness. The outcome of the theoretical study is, eventually, compared to recent intensity fluctuation overlap measurements demonstrating the validity of the theory and providing a straightforward interpretation of qualitatively different spectral behaviors in different random lasers.\n
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\n \n\n \n \n \n \n \n \n Optically Transparent Microwave Polarizer Based on Quasi-Metallic Graphene.\n \n \n \n \n\n\n \n Grande, M.; Bianco, G.; Vincenti, M.; De Ceglia, D.; Capezzuto, P.; Scalora, M.; D'Orazio, A.; and Bruno, G.\n\n\n \n\n\n\n Scientific Reports, 5. 2015.\n cited By 29\n\n\n\n
\n\n\n\n \n \n \"OpticallyPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Grande2015,\nauthor={Grande, M. and Bianco, G.V. and Vincenti, M.A. and De Ceglia, D. and Capezzuto, P. and Scalora, M. and D'Orazio, A. and Bruno, G.},\ntitle={Optically Transparent Microwave Polarizer Based on Quasi-Metallic Graphene},\njournal={Scientific Reports},\nyear={2015},\nvolume={5},\ndoi={10.1038/srep17083},\nart_number={17083},\nnote={cited By 29},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84948155355&doi=10.1038%2fsrep17083&partnerID=40&md5=ee859aaa8dc63e6e8bc3a4e255f665d1},\nabstract={In this paper, we report on the engineering and the realization of optically transparent graphene-based microwave devices using Chemical Vapour Deposition (CVD) graphene whose sheet resistance may be tailored down to values below 30Ω/sq. In particular, we show that the process was successfully used to realize and characterize a simple, optically transparent graphene-based wire-grid polarizer at microwave frequencies (X band). The availability of graphene operating in a quasi-metallic region may allow the integration of graphene layers in several microwave components, thus leading to the realization of fully transparent (and flexible) microwave devices. © 2015, Nature Publishing Group. All rights reserved.},\npublisher={Nature Publishing Group},\nissn={20452322},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n In this paper, we report on the engineering and the realization of optically transparent graphene-based microwave devices using Chemical Vapour Deposition (CVD) graphene whose sheet resistance may be tailored down to values below 30Ω/sq. In particular, we show that the process was successfully used to realize and characterize a simple, optically transparent graphene-based wire-grid polarizer at microwave frequencies (X band). The availability of graphene operating in a quasi-metallic region may allow the integration of graphene layers in several microwave components, thus leading to the realization of fully transparent (and flexible) microwave devices. © 2015, Nature Publishing Group. All rights reserved.\n
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\n \n\n \n \n \n \n \n \n Quantum states of confined hydrogen plasma species: Monte Carlo calculations.\n \n \n \n \n\n\n \n Micca Longo, G.; Longo, S.; and Giordano, D.\n\n\n \n\n\n\n Plasma Sources Science and Technology, 24(6). 2015.\n cited By 1\n\n\n\n
\n\n\n\n \n \n \"QuantumPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{MiccaLongo2015,\nauthor={Micca Longo, G. and Longo, S. and Giordano, D.},\ntitle={Quantum states of confined hydrogen plasma species: Monte Carlo calculations},\njournal={Plasma Sources Science and Technology},\nyear={2015},\nvolume={24},\nnumber={6},\ndoi={10.1088/0963-0252/24/6/065019},\nart_number={065019},\nnote={cited By 1},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84948988441&doi=10.1088%2f0963-0252%2f24%2f6%2f065019&partnerID=40&md5=d8e2ded16ed812f22362ad8abc843ec0},\nabstract={The diffusion Monte Carlo method with symmetry-based state selection is used to calculate the quantum energy states of H2 + confined into potential barriers of atomic dimensions (a model for these ions in solids). Special solutions are employed, permitting one to obtain satisfactory results with rather simple native code. As a test case, 2πu and 2Πg states of H2 + ions under spherical confinement are considered. The results are interpreted using the correlation of H2 + states to atomic orbitals of H atoms lying on the confining surface and perturbation calculations. The method is straightforwardly applied to cavities of any shape and different hydrogen plasma species (at least one-electron ones, including H) for future studies with real crystal symmetries. © 2015 IOP Publishing Ltd Printed in the UK.},\npublisher={Institute of Physics Publishing},\nissn={09630252},\ncoden={PSTEE},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The diffusion Monte Carlo method with symmetry-based state selection is used to calculate the quantum energy states of H2 + confined into potential barriers of atomic dimensions (a model for these ions in solids). Special solutions are employed, permitting one to obtain satisfactory results with rather simple native code. As a test case, 2πu and 2Πg states of H2 + ions under spherical confinement are considered. The results are interpreted using the correlation of H2 + states to atomic orbitals of H atoms lying on the confining surface and perturbation calculations. The method is straightforwardly applied to cavities of any shape and different hydrogen plasma species (at least one-electron ones, including H) for future studies with real crystal symmetries. © 2015 IOP Publishing Ltd Printed in the UK.\n
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\n \n\n \n \n \n \n \n \n Polar POLICRYPS diffractive structures generate cylindrical vector beams.\n \n \n \n \n\n\n \n Alj, D.; Paladugu, S.; Volpe, G.; Caputo, R.; and Umeton, C.\n\n\n \n\n\n\n Applied Physics Letters, 107(20). 2015.\n cited By 3\n\n\n\n
\n\n\n\n \n \n \"PolarPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Alj2015,\nauthor={Alj, D. and Paladugu, S. and Volpe, G. and Caputo, R. and Umeton, C.},\ntitle={Polar POLICRYPS diffractive structures generate cylindrical vector beams},\njournal={Applied Physics Letters},\nyear={2015},\nvolume={107},\nnumber={20},\ndoi={10.1063/1.4935605},\nart_number={201101},\nnote={cited By 3},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84948429940&doi=10.1063%2f1.4935605&partnerID=40&md5=4917375f19f15a1be9612bc2dbb1cb9c},\nabstract={Local shaping of the polarization state of a light beam is appealing for a number of applications. This can be achieved by employing devices containing birefringent materials. In this article, we present one such enables converting a uniformly circularly polarized beam into a cylindrical vector beam (CVB). This device has been fabricated by exploiting the POLICRYPS (POlymer-LIquid CRYstals-Polymer-Slices) photocuring technique. It is a liquid-crystal-based optical diffraction grating featuring polar symmetry of the director alignment. We have characterized the resulting CVB profile and polarization for the cases of left and right circularly polarized incoming beams. © 2015 AIP Publishing LLC.},\npublisher={American Institute of Physics Inc.},\nissn={00036951},\ncoden={APPLA},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Local shaping of the polarization state of a light beam is appealing for a number of applications. This can be achieved by employing devices containing birefringent materials. In this article, we present one such enables converting a uniformly circularly polarized beam into a cylindrical vector beam (CVB). This device has been fabricated by exploiting the POLICRYPS (POlymer-LIquid CRYstals-Polymer-Slices) photocuring technique. It is a liquid-crystal-based optical diffraction grating featuring polar symmetry of the director alignment. We have characterized the resulting CVB profile and polarization for the cases of left and right circularly polarized incoming beams. © 2015 AIP Publishing LLC.\n
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\n \n\n \n \n \n \n \n \n Regio- and Stereoselective Synthesis of Sulfur-Bearing Four-Membered Heterocycles: Direct Access to 2,4-Disubstituted Thietane 1-Oxides.\n \n \n \n \n\n\n \n Degennaro, L.; Carroccia, L.; Parisi, G.; Zenzola, M.; Romanazzi, G.; Fanelli, F.; Pisano, L.; and Luisi, R.\n\n\n \n\n\n\n Journal of Organic Chemistry, 80(24): 12201-12211. 2015.\n cited By 14\n\n\n\n
\n\n\n\n \n \n \"Regio-Paper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Degennaro201512201,\nauthor={Degennaro, L. and Carroccia, L. and Parisi, G. and Zenzola, M. and Romanazzi, G. and Fanelli, F. and Pisano, L. and Luisi, R.},\ntitle={Regio- and Stereoselective Synthesis of Sulfur-Bearing Four-Membered Heterocycles: Direct Access to 2,4-Disubstituted Thietane 1-Oxides},\njournal={Journal of Organic Chemistry},\nyear={2015},\nvolume={80},\nnumber={24},\npages={12201-12211},\ndoi={10.1021/acs.joc.5b02126},\nnote={cited By 14},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84952785888&doi=10.1021%2facs.joc.5b02126&partnerID=40&md5=a183efbdfd42ef233be5535e3aa3959e},\nabstract={Starting from readily available C2-substituted thietane 1-oxides, a straightforward synthesis of new C2,C4-disubstituted thietane 1-oxides has been developed by using a lithiation/electrophilic trapping sequence. The chemical and configurational stability of lithiated C2-substituted thietane 1-oxides has been investigated as well as the stereochemical implications for this process. The results demonstrate that a stereoselective functionalization at the C2, C4 positions of a thietane is feasible, leaving intact the four-membered ring. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={00223263},\ncoden={JOCEA},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Starting from readily available C2-substituted thietane 1-oxides, a straightforward synthesis of new C2,C4-disubstituted thietane 1-oxides has been developed by using a lithiation/electrophilic trapping sequence. The chemical and configurational stability of lithiated C2-substituted thietane 1-oxides has been investigated as well as the stereochemical implications for this process. The results demonstrate that a stereoselective functionalization at the C2, C4 positions of a thietane is feasible, leaving intact the four-membered ring. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Two-Color Single Hybrid Plasmonic Nanoemitters with Real Time Switchable Dominant Emission Wavelength.\n \n \n \n \n\n\n \n Zhou, X.; Wenger, J.; Viscomi, F.; Le Cunff, L.; Béal, J.; Kochtcheev, S.; Yang, X.; Wiederrecht, G.; Colas Des Francs, G.; Bisht, A.; Jradi, S.; Caputo, R.; Demir, H.; Schaller, R.; Plain, J.; Vial, A.; Sun, X.; and Bachelot, R.\n\n\n \n\n\n\n Nano Letters, 15(11): 7458-7466. 2015.\n cited By 25\n\n\n\n
\n\n\n\n \n \n \"Two-ColorPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Zhou20157458,\nauthor={Zhou, X. and Wenger, J. and Viscomi, F.N. and Le Cunff, L. and Béal, J. and Kochtcheev, S. and Yang, X. and Wiederrecht, G.P. and Colas Des Francs, G. and Bisht, A.S. and Jradi, S. and Caputo, R. and Demir, H.V. and Schaller, R.D. and Plain, J. and Vial, A. and Sun, X.W. and Bachelot, R.},\ntitle={Two-Color Single Hybrid Plasmonic Nanoemitters with Real Time Switchable Dominant Emission Wavelength},\njournal={Nano Letters},\nyear={2015},\nvolume={15},\nnumber={11},\npages={7458-7466},\ndoi={10.1021/acs.nanolett.5b02962},\nnote={cited By 25},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84946962393&doi=10.1021%2facs.nanolett.5b02962&partnerID=40&md5=6b055d24a9012f5ed869898b9754bd99},\nabstract={We demonstrate two-color nanoemitters that enable the selection of the dominant emitting wavelength by varying the polarization of excitation light. The nanoemitters were fabricated via surface plasmon-triggered two-photon polymerization. By using two polymerizable solutions with different quantum dots, emitters of different colors can be positioned selectively in different orientations in the close vicinity of the metal nanoparticles. The dominant emission wavelength of the metal/polymer anisotropic hybrid nanoemitter thus can be selected by altering the incident polarization. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={15306984},\ncoden={NALEF},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We demonstrate two-color nanoemitters that enable the selection of the dominant emitting wavelength by varying the polarization of excitation light. The nanoemitters were fabricated via surface plasmon-triggered two-photon polymerization. By using two polymerizable solutions with different quantum dots, emitters of different colors can be positioned selectively in different orientations in the close vicinity of the metal nanoparticles. The dominant emission wavelength of the metal/polymer anisotropic hybrid nanoemitter thus can be selected by altering the incident polarization. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Endothelial-like nitric oxide synthase immunolocalization by using gold nanoparticles and dyes.\n \n \n \n \n\n\n \n Gary, R.; Amelio, D.; Garofalo, F.; Petriashvili, G.; De Santo, M.; Ip, Y.; and Barberi, R.\n\n\n \n\n\n\n Biomedical Optics Express, 6(12): 4738-4748. 2015.\n cited By 2\n\n\n\n
\n\n\n\n \n \n \"Endothelial-likePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Gary20154738,\nauthor={Gary, R. and Amelio, D. and Garofalo, F. and Petriashvili, G. and De Santo, M.P. and Ip, Y.K. and Barberi, R.},\ntitle={Endothelial-like nitric oxide synthase immunolocalization by using gold nanoparticles and dyes},\njournal={Biomedical Optics Express},\nyear={2015},\nvolume={6},\nnumber={12},\npages={4738-4748},\ndoi={10.1364/BOE.6.004738},\nart_number={246684},\nnote={cited By 2},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84961784540&doi=10.1364%2fBOE.6.004738&partnerID=40&md5=bc8e3e3e349a68508d092c15d84967f8},\nabstract={Immunofluorescence is a biological technique that allows displaying the localization of the target molecule through a fluorescent microscope. We used a combination of gold nanoparticles and the fluorescein isothiocianate, FITC, as optical contrast agents for laser scanning confocal microscopy imaging to localize the endothelial-like nitric oxide synthase in skeletal muscle cells in a three-dimensional tissue phantom at the depth of 4μm. The FITC detected fluorescence intensity from gold-nanoparticles-labelled cells was brighter than the emission intensity from unlabelled cells. © 2015 Optical Society of America.},\npublisher={OSA - The Optical Society},\nissn={21567085},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Immunofluorescence is a biological technique that allows displaying the localization of the target molecule through a fluorescent microscope. We used a combination of gold nanoparticles and the fluorescein isothiocianate, FITC, as optical contrast agents for laser scanning confocal microscopy imaging to localize the endothelial-like nitric oxide synthase in skeletal muscle cells in a three-dimensional tissue phantom at the depth of 4μm. The FITC detected fluorescence intensity from gold-nanoparticles-labelled cells was brighter than the emission intensity from unlabelled cells. © 2015 Optical Society of America.\n
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\n \n\n \n \n \n \n \n \n Polarization shaping of Poincaré beams by polariton oscillations.\n \n \n \n \n\n\n \n Colas, D.; Dominici, L.; Donati, S.; Pervishko, A.; Liew, T.; Shelykh, I.; Ballarini, D.; De Giorgi, M.; Bramati, A.; Gigli, G.; Del Valle, E.; Laussy, F.; Kavokin, A.; and Sanvitto, D.\n\n\n \n\n\n\n Light: Science and Applications, 4. 2015.\n cited By 32\n\n\n\n
\n\n\n\n \n \n \"PolarizationPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Colas2015,\nauthor={Colas, D. and Dominici, L. and Donati, S. and Pervishko, A.A. and Liew, T.C.H. and Shelykh, I.A. and Ballarini, D. and De Giorgi, M. and Bramati, A. and Gigli, G. and Del Valle, E. and Laussy, F.P. and Kavokin, A.V. and Sanvitto, D.},\ntitle={Polarization shaping of Poincaré beams by polariton oscillations},\njournal={Light: Science and Applications},\nyear={2015},\nvolume={4},\ndoi={10.1038/lsa.2015.123},\nart_number={e350},\nnote={cited By 32},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84946915671&doi=10.1038%2flsa.2015.123&partnerID=40&md5=cb79568c9952f4f093070f631a133350},\nabstract={We propose theoretically and demonstrate experimentally the generation of light pulses whose polarization varies temporally to cover selected areas of the Poincaré sphere with both tunable swirling speed and total duration (1 ps and 10 ps, respectively, in our implementation). The effect relies on the Rabi oscillations of two polariton polarized fields excited by two counter-polarized and delayed pulses. The superposition of the oscillating fields result in the precession of the Stokes vector of the emitted light while polariton lifetime imbalance results in its drift from a circle of controllable radius on the Poincaré sphere to a single point at long times. The positioning of the initial circle and final point allows to engineer the type of polarization spanning, including a full sweeping of the Poincaré sphere. The universality and simplicity of the scheme should allow for the deployment of time-varying full-Poincaré polarization fields in a variety of platforms, timescales, and regimes. © 2015 CIOMP. All rights reserved.},\npublisher={Nature Publishing Group},\nissn={20477538},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We propose theoretically and demonstrate experimentally the generation of light pulses whose polarization varies temporally to cover selected areas of the Poincaré sphere with both tunable swirling speed and total duration (1 ps and 10 ps, respectively, in our implementation). The effect relies on the Rabi oscillations of two polariton polarized fields excited by two counter-polarized and delayed pulses. The superposition of the oscillating fields result in the precession of the Stokes vector of the emitted light while polariton lifetime imbalance results in its drift from a circle of controllable radius on the Poincaré sphere to a single point at long times. The positioning of the initial circle and final point allows to engineer the type of polarization spanning, including a full sweeping of the Poincaré sphere. The universality and simplicity of the scheme should allow for the deployment of time-varying full-Poincaré polarization fields in a variety of platforms, timescales, and regimes. © 2015 CIOMP. All rights reserved.\n
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\n \n\n \n \n \n \n \n \n Tailoring Anisotropic Interactions between Soft Nanospheres Using Dense Arrays of Smectic Liquid Crystal Edge Dislocations.\n \n \n \n \n\n\n \n Coursault, D.; Blach, J.; Grand, J.; Coati, A.; Vlad, A.; Zappone, B.; Babonneau, D.; Lévi, G.; Félidj, N.; Donnio, B.; Gallani, J.; Alba, M.; Garreau, Y.; Borensztein, Y.; Goldmann, M.; and Lacaze, E.\n\n\n \n\n\n\n ACS Nano, 9(12): 11678-11689. 2015.\n cited By 19\n\n\n\n
\n\n\n\n \n \n \"TailoringPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Coursault201511678,\nauthor={Coursault, D. and Blach, J.-F. and Grand, J. and Coati, A. and Vlad, A. and Zappone, B. and Babonneau, D. and Lévi, G. and Félidj, N. and Donnio, B. and Gallani, J.-L. and Alba, M. and Garreau, Y. and Borensztein, Y. and Goldmann, M. and Lacaze, E.},\ntitle={Tailoring Anisotropic Interactions between Soft Nanospheres Using Dense Arrays of Smectic Liquid Crystal Edge Dislocations},\njournal={ACS Nano},\nyear={2015},\nvolume={9},\nnumber={12},\npages={11678-11689},\ndoi={10.1021/acsnano.5b02538},\nnote={cited By 19},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84952333247&doi=10.1021%2facsnano.5b02538&partnerID=40&md5=7a45f03da0c53a0660d783db23d4ec56},\nabstract={We investigated composite films of gold nanoparticles (NPs)/liquid crystal (LC) defects as a model system to understand the key parameters, which allow for an accurate control of NP anisotropic self-assemblies using soft templates. We combined spectrophotometry, Raman spectroscopy, and grazing incidence small-angle X-ray scattering with calculations of dipole coupling models and soft sphere interactions. We demonstrate that dense arrays of elementary edge dislocations can strongly localize small NPs along the defect cores, resulting in formation of parallel chains of NPs. Furthermore, we show that within the dislocation cores the inter-NP distances can be tuned. This phenomenon appears to be driven by the competition between "soft (nano)sphere" attraction and LC-induced repulsion. We evidence two extreme regimes controlled by the solvent evaporation: (i) when the solvent evaporates abruptly, the spacing between neighboring NPs in the chains is dominated by van der Waals interactions between interdigitated capping ligands, leading to chains of close-packed NPs; (ii) when the solvent evaporates slowly, strong interdigitation between the is avoided, leading to a dominating LC-induced repulsion between NPs associated with the replacement of disordered cores by NPs. The templating of NPs by topological defects, beyond the technological inquiries, may enable creation, investigation, and manipulation of unique collective features for a wide range of nanomaterials. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={19360851},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We investigated composite films of gold nanoparticles (NPs)/liquid crystal (LC) defects as a model system to understand the key parameters, which allow for an accurate control of NP anisotropic self-assemblies using soft templates. We combined spectrophotometry, Raman spectroscopy, and grazing incidence small-angle X-ray scattering with calculations of dipole coupling models and soft sphere interactions. We demonstrate that dense arrays of elementary edge dislocations can strongly localize small NPs along the defect cores, resulting in formation of parallel chains of NPs. Furthermore, we show that within the dislocation cores the inter-NP distances can be tuned. This phenomenon appears to be driven by the competition between \"soft (nano)sphere\" attraction and LC-induced repulsion. We evidence two extreme regimes controlled by the solvent evaporation: (i) when the solvent evaporates abruptly, the spacing between neighboring NPs in the chains is dominated by van der Waals interactions between interdigitated capping ligands, leading to chains of close-packed NPs; (ii) when the solvent evaporates slowly, strong interdigitation between the is avoided, leading to a dominating LC-induced repulsion between NPs associated with the replacement of disordered cores by NPs. The templating of NPs by topological defects, beyond the technological inquiries, may enable creation, investigation, and manipulation of unique collective features for a wide range of nanomaterials. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Electron trajectory simulations of time-of-flight spectrometers for core level high-energy photoelectron spectroscopy at pulsed X-ray sources.\n \n \n \n \n\n\n \n Lollobrigida, V.; Greco, G.; Simeone, D.; Offi, F.; Verna, A.; and Stefani, G.\n\n\n \n\n\n\n Journal of Electron Spectroscopy and Related Phenomena, 205: 98-105. 2015.\n cited By 4\n\n\n\n
\n\n\n\n \n \n \"ElectronPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Lollobrigida201598,\nauthor={Lollobrigida, V. and Greco, G. and Simeone, D. and Offi, F. and Verna, A. and Stefani, G.},\ntitle={Electron trajectory simulations of time-of-flight spectrometers for core level high-energy photoelectron spectroscopy at pulsed X-ray sources},\njournal={Journal of Electron Spectroscopy and Related Phenomena},\nyear={2015},\nvolume={205},\npages={98-105},\ndoi={10.1016/j.elspec.2015.09.005},\nnote={cited By 4},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84945268030&doi=10.1016%2fj.elspec.2015.09.005&partnerID=40&md5=ca625db1eea2f428ea6a52cf20139c3a},\nabstract={The advent of Free Electron Lasers (FELs), able to provide short (2-100 fs) and intense (1033 photons/s/mm2/mrad2/0.1%bandwidth) pulses of light also in the hard X-ray regime (ω&gt; 2000 eV), opens new possibilities to study the ultrafast dynamics of processes, exploiting the capability of Hard X-ray Photoelectron Spectroscopy (HAXPES) to measure core-level spectra of elements with bulk sensitivity. In order to detect the intense bursts of high kinetic energy electrons generated by the X-ray pulses with an energy resolution comparable to the existing category of electron analyzers, a new class of spectrometers must be designed. We present a characterization of two different TOF spectrometers, namely one based on a retarding cylindrical lens and another one based on the spherical reflector geometry. SIMION® software has been used in order to evaluate electron trajectories of high kinetic energy electrons (5000-10,000 eV) and extract transmission properties, angular acceptance and energy resolution. It resulted that while the linear system is able to accept a larger solid angle (∼50 msr), the spherical mirror offers a better resolving power (around 71,000). Both analyzers are capable of a transmission above 90% within range of kinetic energies wide enough to measure the full line-shape of a core photoionization peak. Furthermore, we proved that both instruments are able to discriminate between two consecutive electron bunches having a temporal separation inferior than 220 ns, which is the distance between two consecutive photon pulses at the European X-ray Free Electron Laser (EXFEL), which is currently under construction in Hamburg. © 2015 Elsevier B.V.},\npublisher={Elsevier},\nissn={03682048},\ncoden={JESRA},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The advent of Free Electron Lasers (FELs), able to provide short (2-100 fs) and intense (1033 photons/s/mm2/mrad2/0.1%bandwidth) pulses of light also in the hard X-ray regime (ω> 2000 eV), opens new possibilities to study the ultrafast dynamics of processes, exploiting the capability of Hard X-ray Photoelectron Spectroscopy (HAXPES) to measure core-level spectra of elements with bulk sensitivity. In order to detect the intense bursts of high kinetic energy electrons generated by the X-ray pulses with an energy resolution comparable to the existing category of electron analyzers, a new class of spectrometers must be designed. We present a characterization of two different TOF spectrometers, namely one based on a retarding cylindrical lens and another one based on the spherical reflector geometry. SIMION® software has been used in order to evaluate electron trajectories of high kinetic energy electrons (5000-10,000 eV) and extract transmission properties, angular acceptance and energy resolution. It resulted that while the linear system is able to accept a larger solid angle (∼50 msr), the spherical mirror offers a better resolving power (around 71,000). Both analyzers are capable of a transmission above 90% within range of kinetic energies wide enough to measure the full line-shape of a core photoionization peak. Furthermore, we proved that both instruments are able to discriminate between two consecutive electron bunches having a temporal separation inferior than 220 ns, which is the distance between two consecutive photon pulses at the European X-ray Free Electron Laser (EXFEL), which is currently under construction in Hamburg. © 2015 Elsevier B.V.\n
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\n \n\n \n \n \n \n \n \n Enhanced adhesion of electron beam resist by grafted monolayer poly(methylmethacrylate- co -methacrylic acid) brush.\n \n \n \n \n\n\n \n Viscomi, F.; Dey, R.; Caputo, R.; and Cui, B.\n\n\n \n\n\n\n Journal of Vacuum Science and Technology B: Nanotechnology and Microelectronics, 33(6). 2015.\n cited By 1\n\n\n\n
\n\n\n\n \n \n \"EnhancedPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Viscomi2015,\nauthor={Viscomi, F.N. and Dey, R.K. and Caputo, R. and Cui, B.},\ntitle={Enhanced adhesion of electron beam resist by grafted monolayer poly(methylmethacrylate- co -methacrylic acid) brush},\njournal={Journal of Vacuum Science and Technology B: Nanotechnology and Microelectronics},\nyear={2015},\nvolume={33},\nnumber={6},\ndoi={10.1116/1.4935506},\nart_number={06FD06},\nnote={cited By 1},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947230331&doi=10.1116%2f1.4935506&partnerID=40&md5=f842228c311f85d20732460a152e8c11},\nabstract={In electron beam lithography, poor resist adhesion to a substrate may lead to resist structure detachment upon development. One popular method to promote resist adhesion is to modify the substrate surface. In this study, the authors will show that a poly(methylmethacrylate-co-methacrylic acid) [P(MMA-co-MAA)] monolayer "brush" can be grafted onto a silicon substrate using thermal annealing that leads to chemical bonding of the P(MMA-co-MAA) copolymer to the hydroxyl group-terminated substrate, followed by acetic acid wash to remove the bulk, unbonded copolymer. The monolayer brush has a thickness of 12 nm. The authors will show that it can greatly improve the adhesion of positive resist, the ZEP-520A, and negative resist polystyrene to bare silicon surfaces, which led to high resolution patterning without resist detachment upon development. The improvement was more dramatic when patterning dense sub-100 nm period grating structures. But the improvement was negligible for an aluminum substrate, because, even without the brush layer, resist adhesion to aluminum is found already to be strong enough to prevent resist structure peeling off. The current simple and low cost method could be very useful when resist adhesion to the substrate for a given developer is weak. © 2015 American Vacuum Society.},\npublisher={American Institute of Physics Inc.},\nissn={21662746},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n In electron beam lithography, poor resist adhesion to a substrate may lead to resist structure detachment upon development. One popular method to promote resist adhesion is to modify the substrate surface. In this study, the authors will show that a poly(methylmethacrylate-co-methacrylic acid) [P(MMA-co-MAA)] monolayer \"brush\" can be grafted onto a silicon substrate using thermal annealing that leads to chemical bonding of the P(MMA-co-MAA) copolymer to the hydroxyl group-terminated substrate, followed by acetic acid wash to remove the bulk, unbonded copolymer. The monolayer brush has a thickness of 12 nm. The authors will show that it can greatly improve the adhesion of positive resist, the ZEP-520A, and negative resist polystyrene to bare silicon surfaces, which led to high resolution patterning without resist detachment upon development. The improvement was more dramatic when patterning dense sub-100 nm period grating structures. But the improvement was negligible for an aluminum substrate, because, even without the brush layer, resist adhesion to aluminum is found already to be strong enough to prevent resist structure peeling off. The current simple and low cost method could be very useful when resist adhesion to the substrate for a given developer is weak. © 2015 American Vacuum Society.\n
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\n \n\n \n \n \n \n \n \n Self-Sustained Density Oscillations of Swimming Bacteria Confined in Microchambers.\n \n \n \n \n\n\n \n Paoluzzi, M.; Di Leonardo, R.; and Angelani, L.\n\n\n \n\n\n\n Physical Review Letters, 115(18). 2015.\n cited By 19\n\n\n\n
\n\n\n\n \n \n \"Self-SustainedPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Paoluzzi2015,\nauthor={Paoluzzi, M. and Di Leonardo, R. and Angelani, L.},\ntitle={Self-Sustained Density Oscillations of Swimming Bacteria Confined in Microchambers},\njournal={Physical Review Letters},\nyear={2015},\nvolume={115},\nnumber={18},\ndoi={10.1103/PhysRevLett.115.188303},\nart_number={188303},\nnote={cited By 19},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84946594166&doi=10.1103%2fPhysRevLett.115.188303&partnerID=40&md5=e3b759649266c87277605484dbd49684},\nabstract={We numerically study the dynamics of run-and-tumble particles confined in two chambers connected by thin channels. Two dominant dynamical behaviors emerge: (i) an oscillatory pumping state, in which particles periodically fill the two vessels, and (ii) a circulating flow state, dynamically maintaining a near constant population level in the containers when connected by two channels. We demonstrate that the oscillatory behavior arises from the combination of a narrow channel, preventing bacteria reorientation, and a density-dependent motility inside the chambers. © 2015 American Physical Society.},\npublisher={American Physical Society},\nissn={00319007},\ncoden={PRLTA},\npubmed_id={26565506},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
\n
\n\n\n
\n We numerically study the dynamics of run-and-tumble particles confined in two chambers connected by thin channels. Two dominant dynamical behaviors emerge: (i) an oscillatory pumping state, in which particles periodically fill the two vessels, and (ii) a circulating flow state, dynamically maintaining a near constant population level in the containers when connected by two channels. We demonstrate that the oscillatory behavior arises from the combination of a narrow channel, preventing bacteria reorientation, and a density-dependent motility inside the chambers. © 2015 American Physical Society.\n
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\n \n\n \n \n \n \n \n \n Mussel adhesion is dictated by time-regulated secretion and molecular conformation of mussel adhesive proteins.\n \n \n \n \n\n\n \n Petrone, L.; Kumar, A.; Sutanto, C.; Patil, N.; Kannan, S.; Palaniappan, A.; Amini, S.; Zappone, B.; Verma, C.; and Miserez, A.\n\n\n \n\n\n\n Nature Communications, 6. 2015.\n cited By 76\n\n\n\n
\n\n\n\n \n \n \"MusselPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Petrone2015,\nauthor={Petrone, L. and Kumar, A. and Sutanto, C.N. and Patil, N.J. and Kannan, S. and Palaniappan, A. and Amini, S. and Zappone, B. and Verma, C. and Miserez, A.},\ntitle={Mussel adhesion is dictated by time-regulated secretion and molecular conformation of mussel adhesive proteins},\njournal={Nature Communications},\nyear={2015},\nvolume={6},\ndoi={10.1038/ncomms9737},\nart_number={8737},\nnote={cited By 76},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84945545709&doi=10.1038%2fncomms9737&partnerID=40&md5=90210d74d77c4f3d86b400eb6d3ec65a},\nabstract={Interfacial water constitutes a formidable barrier to strong surface bonding, hampering the development of water-resistant synthetic adhesives. Notwithstanding this obstacle, the Asian green mussel Perna viridis attaches firmly to underwater surfaces via a proteinaceous secretion (byssus). Extending beyond the currently known design principles of mussel adhesion, here we elucidate the precise time-regulated secretion of P. viridis mussel adhesive proteins. The vanguard 3,4-dihydroxy-L-phenylalanine (Dopa)-rich protein Pvfp-5 acts as an adhesive primer, overcoming repulsive hydration forces by displacing surface-bound water and generating strong surface adhesion. Using homology modelling and molecular dynamics simulations, we find that all mussel adhesive proteins are largely unordered, with Pvfp-5 adopting a disordered structure and elongated conformation whereby all Dopa residues reside on the protein surface. Time-regulated secretion and structural disorder of mussel adhesive proteins appear essential for optimizing extended nonspecific surface interactions and byssus assembly. Our findings reveal molecular-scale principles to help the development of wet-resistant adhesives. © 2015 Macmillan Publishers Limited. All rights reserved.},\npublisher={Nature Publishing Group},\nissn={20411723},\npubmed_id={26508080},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Interfacial water constitutes a formidable barrier to strong surface bonding, hampering the development of water-resistant synthetic adhesives. Notwithstanding this obstacle, the Asian green mussel Perna viridis attaches firmly to underwater surfaces via a proteinaceous secretion (byssus). Extending beyond the currently known design principles of mussel adhesion, here we elucidate the precise time-regulated secretion of P. viridis mussel adhesive proteins. The vanguard 3,4-dihydroxy-L-phenylalanine (Dopa)-rich protein Pvfp-5 acts as an adhesive primer, overcoming repulsive hydration forces by displacing surface-bound water and generating strong surface adhesion. Using homology modelling and molecular dynamics simulations, we find that all mussel adhesive proteins are largely unordered, with Pvfp-5 adopting a disordered structure and elongated conformation whereby all Dopa residues reside on the protein surface. Time-regulated secretion and structural disorder of mussel adhesive proteins appear essential for optimizing extended nonspecific surface interactions and byssus assembly. Our findings reveal molecular-scale principles to help the development of wet-resistant adhesives. © 2015 Macmillan Publishers Limited. All rights reserved.\n
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\n \n\n \n \n \n \n \n \n Quasi equilibrium construction for the long time limit of glassy dynamics.\n \n \n \n \n\n\n \n Franz, S.; Parisi, G.; Ricci-Tersenghi, F.; and Urbani, P.\n\n\n \n\n\n\n Journal of Statistical Mechanics: Theory and Experiment, 2015(10). 2015.\n cited By 0\n\n\n\n
\n\n\n\n \n \n \"QuasiPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Franz2015,\nauthor={Franz, S. and Parisi, G. and Ricci-Tersenghi, F. and Urbani, P.},\ntitle={Quasi equilibrium construction for the long time limit of glassy dynamics},\njournal={Journal of Statistical Mechanics: Theory and Experiment},\nyear={2015},\nvolume={2015},\nnumber={10},\ndoi={10.1088/1742-5468/2015/10/P10010},\nart_number={P10010},\nnote={cited By 0},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84945143616&doi=10.1088%2f1742-5468%2f2015%2f10%2fP10010&partnerID=40&md5=e1b9e32db0d61b9b7d4da97dc97d2cab},\nabstract={In this paper we review a recent proposal to understand the long time limit of glassy dynamics in terms of an appropriate Markov chain [1]. The advantages of the resulting construction are many. The first one is that it gives a quasi equilibrium description on how glassy systems explore the phase space in the slow relaxation part of their dynamics. The second one is that it gives an alternative way to obtain dynamical equations starting from a dynamical rule that is static in spirit. This provides a way to overcome the difficulties encountered in the short time part of the dynamics where current conservation must be enforced. We study this approach in detail in a prototypical mean field disordered spin system, namely the p-spin spherical model, showing how we can obtain the well known equations that describe its dynamics. Then we apply the same approach to structural glasses. We first derive a set of dynamical Ornstein- Zernike equations which are very general in nature. Finally we consider two possible closure schemes for them, namely the hypernetted chain approximation of liquid theory and a closure of the BBGKY hierarchy that has been recently introduced by Szamel. From both approaches we finally find a set of dynamical mode-coupling-like equations that are supposed to describe the system in the long time/slow dynamics regime. � 2015 IOP Publishing Ltd and SISSA Medialab srl.},\npublisher={Institute of Physics Publishing},\nissn={17425468},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n In this paper we review a recent proposal to understand the long time limit of glassy dynamics in terms of an appropriate Markov chain [1]. The advantages of the resulting construction are many. The first one is that it gives a quasi equilibrium description on how glassy systems explore the phase space in the slow relaxation part of their dynamics. The second one is that it gives an alternative way to obtain dynamical equations starting from a dynamical rule that is static in spirit. This provides a way to overcome the difficulties encountered in the short time part of the dynamics where current conservation must be enforced. We study this approach in detail in a prototypical mean field disordered spin system, namely the p-spin spherical model, showing how we can obtain the well known equations that describe its dynamics. Then we apply the same approach to structural glasses. We first derive a set of dynamical Ornstein- Zernike equations which are very general in nature. Finally we consider two possible closure schemes for them, namely the hypernetted chain approximation of liquid theory and a closure of the BBGKY hierarchy that has been recently introduced by Szamel. From both approaches we finally find a set of dynamical mode-coupling-like equations that are supposed to describe the system in the long time/slow dynamics regime. � 2015 IOP Publishing Ltd and SISSA Medialab srl.\n
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\n \n\n \n \n \n \n \n \n Polymer-Coated Magnetic Nanoparticles for Curcumin Delivery to Cancer Cells.\n \n \n \n \n\n\n \n Mancarella, S.; Greco, V.; Baldassarre, F.; Vergara, D.; Maffia, M.; and Leporatti, S.\n\n\n \n\n\n\n Macromolecular Bioscience, 15(10): 1365-1374. 2015.\n cited By 38\n\n\n\n
\n\n\n\n \n \n \"Polymer-CoatedPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Mancarella20151365,\nauthor={Mancarella, S. and Greco, V. and Baldassarre, F. and Vergara, D. and Maffia, M. and Leporatti, S.},\ntitle={Polymer-Coated Magnetic Nanoparticles for Curcumin Delivery to Cancer Cells},\njournal={Macromolecular Bioscience},\nyear={2015},\nvolume={15},\nnumber={10},\npages={1365-1374},\ndoi={10.1002/mabi.201500142},\nnote={cited By 38},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84945487259&doi=10.1002%2fmabi.201500142&partnerID=40&md5=4ff92f38a8477798760b3275137f0eef},\nabstract={The new goal of anticancer agent research is the screening of natural origin drugs with lower systemic adverse effects than synthetic compounds. Here, we focus on curcumin, an important polyphenolic pigment classically used as spice in the Indian cuisine. The molecule has high pleiotropic activities including strong antioxidant and anti-inflammatory properties. However, its clinical potential is limited due its low solubility and bioavailability. We have developed a layer by layer functionalization of Fe3O4 nanoparticles (nano-Fe3O4) by coating biodegradable polyelectrolyte multilayers such as Dextran (DXS) and Poly(l-lysine) (PLL). Physico-chemical studies were performed to obtain a high upload of curcumin in Fe3O4 nanoparticles. Nano-Fe3O4 were then tested against an ovarian cancer cell line, SKOV-3, to demonstrate their therapeutic efficacy. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.},\npublisher={Wiley-VCH Verlag},\nissn={16165187},\ncoden={MBAIB},\npubmed_id={26085082},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The new goal of anticancer agent research is the screening of natural origin drugs with lower systemic adverse effects than synthetic compounds. Here, we focus on curcumin, an important polyphenolic pigment classically used as spice in the Indian cuisine. The molecule has high pleiotropic activities including strong antioxidant and anti-inflammatory properties. However, its clinical potential is limited due its low solubility and bioavailability. We have developed a layer by layer functionalization of Fe3O4 nanoparticles (nano-Fe3O4) by coating biodegradable polyelectrolyte multilayers such as Dextran (DXS) and Poly(l-lysine) (PLL). Physico-chemical studies were performed to obtain a high upload of curcumin in Fe3O4 nanoparticles. Nano-Fe3O4 were then tested against an ovarian cancer cell line, SKOV-3, to demonstrate their therapeutic efficacy. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.\n
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\n \n\n \n \n \n \n \n \n Optical bistability in Ag-Al2O3 one-dimensional photonic crystals.\n \n \n \n \n\n\n \n Sreekanth, K.; Rashed, A.; Veltri, A.; Elkabbash, M.; and Strangi, G.\n\n\n \n\n\n\n EPL, 112(1). 2015.\n cited By 1\n\n\n\n
\n\n\n\n \n \n \"OpticalPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Sreekanth2015,\nauthor={Sreekanth, K.V. and Rashed, A.R. and Veltri, A. and Elkabbash, M. and Strangi, G.},\ntitle={Optical bistability in Ag-Al2O3 one-dimensional photonic crystals},\njournal={EPL},\nyear={2015},\nvolume={112},\nnumber={1},\ndoi={10.1209/0295-5075/112/14005},\nart_number={14005},\nnote={cited By 1},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947253505&doi=10.1209%2f0295-5075%2f112%2f14005&partnerID=40&md5=963a9f5161d6dc3909e019cebc5c79e4},\nabstract={Here, we demonstrate the nonlinear optical responses of Ag-Al2O3 one-dimensional photonic crystals (1D PCs). The linear transmission spectra of the proposed 1D PC show higher transmission at shorter wavelengths and lower transmission at longer wavelengths with "N" pairs of Ag-Al2O3 will support "N - 1" transmission peaks. By using 5 pairs of Ag-Al2O3, the optical bistability behavior of light transmission at low input intensity for the resonant modes is numerically demonstrated. Then, we performed a Z-scan experimental technique to show the enhanced nonlinear optical transmission of Ag-Al2O3 1D PC. These results can pave the way for achieving all-optical control of light for potential applications such as all-optical switching, optical logic, optical computation, etc. © EPLA, 2015.},\npublisher={Institute of Physics Publishing},\nissn={02955075},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Here, we demonstrate the nonlinear optical responses of Ag-Al2O3 one-dimensional photonic crystals (1D PCs). The linear transmission spectra of the proposed 1D PC show higher transmission at shorter wavelengths and lower transmission at longer wavelengths with \"N\" pairs of Ag-Al2O3 will support \"N - 1\" transmission peaks. By using 5 pairs of Ag-Al2O3, the optical bistability behavior of light transmission at low input intensity for the resonant modes is numerically demonstrated. Then, we performed a Z-scan experimental technique to show the enhanced nonlinear optical transmission of Ag-Al2O3 1D PC. These results can pave the way for achieving all-optical control of light for potential applications such as all-optical switching, optical logic, optical computation, etc. © EPLA, 2015.\n
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\n \n\n \n \n \n \n \n \n Light-controllable linear dichroism in nematics.\n \n \n \n \n\n\n \n Petriashvili, G.; Hamdi, R.; De Santo, M.; Gary, R.; and Barberi, R.\n\n\n \n\n\n\n Applied Optics, 54(28): 8293-8297. 2015.\n cited By 2\n\n\n\n
\n\n\n\n \n \n \"Light-controllablePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Petriashvili20158293,\nauthor={Petriashvili, G. and Hamdi, R. and De Santo, M.P. and Gary, R. and Barberi, R.},\ntitle={Light-controllable linear dichroism in nematics},\njournal={Applied Optics},\nyear={2015},\nvolume={54},\nnumber={28},\npages={8293-8297},\ndoi={10.1364/AO.54.008293},\nnote={cited By 2},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84948696219&doi=10.1364%2fAO.54.008293&partnerID=40&md5=6293ec60ca7e20a0a7578ba2c44aad1d},\nabstract={We report a method to obtain a light-controllable dichroism. The main effect is achieved using spiropyran-doped (SP-doped) nematic liquid crystal mixtures. SP molecules exhibit a high solubility in the liquid crystal host, which can vary between 1% and 4% in weight, without destroying the liquid crystalline phase. Due to their elongated shape, SP molecules are oriented along the nematic liquid crystal director. The obtained linear dichroism was measured to be 1.08 with a dichroic ratio of 7.12. Further, a two-direction linear dichroism was obtained by adding a dichroic dye to the mixture. The angle between the two dichroic axes was found to be 11°. Two-direction linear dichroism is also light controllable and can be switched back to one-direction dichroism. © 2015 Optical Society of America.},\npublisher={OSA - The Optical Society},\nissn={1559128X},\ncoden={APOPA},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We report a method to obtain a light-controllable dichroism. The main effect is achieved using spiropyran-doped (SP-doped) nematic liquid crystal mixtures. SP molecules exhibit a high solubility in the liquid crystal host, which can vary between 1% and 4% in weight, without destroying the liquid crystalline phase. Due to their elongated shape, SP molecules are oriented along the nematic liquid crystal director. The obtained linear dichroism was measured to be 1.08 with a dichroic ratio of 7.12. Further, a two-direction linear dichroism was obtained by adding a dichroic dye to the mixture. The angle between the two dichroic axes was found to be 11°. Two-direction linear dichroism is also light controllable and can be switched back to one-direction dichroism. © 2015 Optical Society of America.\n
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\n \n\n \n \n \n \n \n \n Room temperature Ultraviolet B emission from InAlGaN films synthesized by plasma-assisted molecular beam epitaxy.\n \n \n \n \n\n\n \n Kong, W.; Roberts, A.; Jiao, W.; Fournelle, J.; Kim, T.; Losurdo, M.; Everitt, H.; and Brown, A.\n\n\n \n\n\n\n Applied Physics Letters, 107(13). 2015.\n cited By 2\n\n\n\n
\n\n\n\n \n \n \"RoomPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Kong2015,\nauthor={Kong, W. and Roberts, A.T. and Jiao, W.Y. and Fournelle, J. and Kim, T.H. and Losurdo, M. and Everitt, H.O. and Brown, A.S.},\ntitle={Room temperature Ultraviolet B emission from InAlGaN films synthesized by plasma-assisted molecular beam epitaxy},\njournal={Applied Physics Letters},\nyear={2015},\nvolume={107},\nnumber={13},\ndoi={10.1063/1.4931942},\nart_number={132102},\nnote={cited By 2},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84942572196&doi=10.1063%2f1.4931942&partnerID=40&md5=7489f8ae82383bc2e69d4ee9e8b167e1},\nabstract={Thin films of the wide bandgap quaternary semiconductor In<inf>x</inf>Al<inf>y</inf>Ga<inf>(1-x-y)</inf>N with low In (x=0.01-0.05) and high Al composition (y=0.40-0.49) were synthesized on GaN templates by plasma-assisted molecular beam epitaxy. High-resolution X-ray diffraction was used to correlate the strain accommodation of the films to composition. Room temperature ultraviolet B (280nm-320nm) photoluminescence intensity increased with increasing In composition, while the Stokes shift remained relatively constant. The data suggest a competition between radiative and non-radiative recombination occurs for carriers, respectively, localized at centers produced by In incorporation and at dislocations produced by strain relaxation. © 2015 AIP Publishing LLC.},\npublisher={American Institute of Physics Inc.},\nissn={00036951},\ncoden={APPLA},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Thin films of the wide bandgap quaternary semiconductor InxAlyGa(1-x-y)N with low In (x=0.01-0.05) and high Al composition (y=0.40-0.49) were synthesized on GaN templates by plasma-assisted molecular beam epitaxy. High-resolution X-ray diffraction was used to correlate the strain accommodation of the films to composition. Room temperature ultraviolet B (280nm-320nm) photoluminescence intensity increased with increasing In composition, while the Stokes shift remained relatively constant. The data suggest a competition between radiative and non-radiative recombination occurs for carriers, respectively, localized at centers produced by In incorporation and at dislocations produced by strain relaxation. © 2015 AIP Publishing LLC.\n
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\n \n\n \n \n \n \n \n \n UV Light Detection from CdS Nanocrystal Sensitized Graphene Photodetectors at kHz Frequencies.\n \n \n \n \n\n\n \n Spirito, D.; Kudera, S.; Miseikis, V.; Giansante, C.; Coletti, C.; and Krahne, R.\n\n\n \n\n\n\n Journal of Physical Chemistry C, 119(42): 23859-23864. 2015.\n cited By 21\n\n\n\n
\n\n\n\n \n \n \"UVPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Spirito201523859,\nauthor={Spirito, D. and Kudera, S. and Miseikis, V. and Giansante, C. and Coletti, C. and Krahne, R.},\ntitle={UV Light Detection from CdS Nanocrystal Sensitized Graphene Photodetectors at kHz Frequencies},\njournal={Journal of Physical Chemistry C},\nyear={2015},\nvolume={119},\nnumber={42},\npages={23859-23864},\ndoi={10.1021/acs.jpcc.5b07895},\nnote={cited By 21},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84945256526&doi=10.1021%2facs.jpcc.5b07895&partnerID=40&md5=f87ee6393f79d88e765a4f71164ce815},\nabstract={We have fabricated UV-sensitive photodetectors based on colloidal CdS nanocrystals and graphene. The nanocrystals act as a sensitizer layer that improves light harvesting leading to high responsivity of the detector. Despite the slow relaxation of the photogenerated charges in the nanocrystal film, faster processes allowed to detect pulses up to a repetition rate of 2 kHz. We have performed time-resolved analysis of the processes occurring in our hybrid system and discuss possible photoinduced charge transfer mechanisms. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={19327447},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We have fabricated UV-sensitive photodetectors based on colloidal CdS nanocrystals and graphene. The nanocrystals act as a sensitizer layer that improves light harvesting leading to high responsivity of the detector. Despite the slow relaxation of the photogenerated charges in the nanocrystal film, faster processes allowed to detect pulses up to a repetition rate of 2 kHz. We have performed time-resolved analysis of the processes occurring in our hybrid system and discuss possible photoinduced charge transfer mechanisms. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Flexible structures based on a short pitch cholesteric liquid crystals.\n \n \n \n \n\n\n \n Palermo, G.; De Sio, L.; and Umeton, C.\n\n\n \n\n\n\n Molecular Crystals and Liquid Crystals, 619(1): 35-41. 2015.\n cited By 2\n\n\n\n
\n\n\n\n \n \n \"FlexiblePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Palermo201535,\nauthor={Palermo, G. and De Sio, L. and Umeton, C.},\ntitle={Flexible structures based on a short pitch cholesteric liquid crystals},\njournal={Molecular Crystals and Liquid Crystals},\nyear={2015},\nvolume={619},\nnumber={1},\npages={35-41},\ndoi={10.1080/15421406.2015.1087275},\nnote={cited By 2},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84945250834&doi=10.1080%2f15421406.2015.1087275&partnerID=40&md5=d8cfa391a9e2727b188ea640b4f745da},\nabstract={We report on the realization and characterization of electro-responsive and pressure sensitive polydimethylsiloxane (PDMS) conductive photonic structures combined with the reconfigurable properties of short pitch cholesteric liquid crystals (aligned in Grandjean configuration). By combining ion-implantation process and surface chemistry functionalization, we have overcome the insulating properties of PDMS and induced long range organization of cholesteric liquid crystals, thus controlling both diffraction and selective Bragg reflection of light by means of external perturbations (electric field, pressure). We have characterized our devices in terms of morphological, optical and electro-optical properties. © 2015 Copyright © Taylor & Francis Group, LLC.},\npublisher={Taylor and Francis Inc.},\nissn={15421406},\ncoden={MCLCD},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We report on the realization and characterization of electro-responsive and pressure sensitive polydimethylsiloxane (PDMS) conductive photonic structures combined with the reconfigurable properties of short pitch cholesteric liquid crystals (aligned in Grandjean configuration). By combining ion-implantation process and surface chemistry functionalization, we have overcome the insulating properties of PDMS and induced long range organization of cholesteric liquid crystals, thus controlling both diffraction and selective Bragg reflection of light by means of external perturbations (electric field, pressure). We have characterized our devices in terms of morphological, optical and electro-optical properties. © 2015 Copyright © Taylor & Francis Group, LLC.\n
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\n \n\n \n \n \n \n \n \n Exciton-Plasmon Coupling Enhancement via Metal Oxidation.\n \n \n \n \n\n\n \n Todisco, F.; D'Agostino, S.; Esposito, M.; Fernández-Domínguez, A.; De Giorgi, M.; Ballarini, D.; Dominici, L.; Tarantini, I.; Cuscuná, M.; Della Sala, F.; Gigli, G.; and Sanvitto, D.\n\n\n \n\n\n\n ACS Nano, 9(10): 9691-9699. 2015.\n cited By 34\n\n\n\n
\n\n\n\n \n \n \"Exciton-PlasmonPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Todisco20159691,\nauthor={Todisco, F. and D'Agostino, S. and Esposito, M. and Fernández-Domínguez, A.I. and De Giorgi, M. and Ballarini, D. and Dominici, L. and Tarantini, I. and Cuscuná, M. and Della Sala, F. and Gigli, G. and Sanvitto, D.},\ntitle={Exciton-Plasmon Coupling Enhancement via Metal Oxidation},\njournal={ACS Nano},\nyear={2015},\nvolume={9},\nnumber={10},\npages={9691-9699},\ndoi={10.1021/acsnano.5b04974},\nnote={cited By 34},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84945936715&doi=10.1021%2facsnano.5b04974&partnerID=40&md5=dcc27d656cd99d9ff4f61ac9f4e90f87},\nabstract={In this paper, we report on the effect of metal oxidation on strong coupling interactions between silver nanostructures and a J-aggregated cyanine dye. We show that metal oxidation can sensibly affect the plexcitonic system, inducing a change in the coupling strength. In particular, we demonstrate that the presence of oxide prevents the appearance of Rabi splitting in the extinction spectra for thick spacers. In contrast, below a threshold percentage, the oxide layer results in an higher coupling strength between the plasmon and the Frenkel exciton. Contrary to common belief, a thin oxide layer seems thus to act, under certain conditions, as a coupling mediator between an emitter and a localized surface plasmon excited in a metallic nanostructure. This suggests that metal oxidation can be exploited as a means to enhance light-matter interactions in strong coupling applications. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={19360851},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
\n
\n\n\n
\n In this paper, we report on the effect of metal oxidation on strong coupling interactions between silver nanostructures and a J-aggregated cyanine dye. We show that metal oxidation can sensibly affect the plexcitonic system, inducing a change in the coupling strength. In particular, we demonstrate that the presence of oxide prevents the appearance of Rabi splitting in the extinction spectra for thick spacers. In contrast, below a threshold percentage, the oxide layer results in an higher coupling strength between the plasmon and the Frenkel exciton. Contrary to common belief, a thin oxide layer seems thus to act, under certain conditions, as a coupling mediator between an emitter and a localized surface plasmon excited in a metallic nanostructure. This suggests that metal oxidation can be exploited as a means to enhance light-matter interactions in strong coupling applications. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Altered protein expression pattern in skin fibroblasts from parkin-mutant early-onset Parkinson's disease patients.\n \n \n \n \n\n\n \n Lippolis, R.; Siciliano, R.; Pacelli, C.; Ferretta, A.; Mazzeo, M.; Scacco, S.; Papa, F.; Gaballo, A.; Dell'Aquila, C.; De Mari, M.; Papa, S.; and Cocco, T.\n\n\n \n\n\n\n Biochimica et Biophysica Acta - Molecular Basis of Disease, 1852(9): 1960-1970. 2015.\n cited By 14\n\n\n\n
\n\n\n\n \n \n \"AlteredPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Lippolis20151960,\nauthor={Lippolis, R. and Siciliano, R.A. and Pacelli, C. and Ferretta, A. and Mazzeo, M.F. and Scacco, S. and Papa, F. and Gaballo, A. and Dell'Aquila, C. and De Mari, M. and Papa, S. and Cocco, T.},\ntitle={Altered protein expression pattern in skin fibroblasts from parkin-mutant early-onset Parkinson's disease patients},\njournal={Biochimica et Biophysica Acta - Molecular Basis of Disease},\nyear={2015},\nvolume={1852},\nnumber={9},\npages={1960-1970},\ndoi={10.1016/j.bbadis.2015.06.015},\nnote={cited By 14},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84937124849&doi=10.1016%2fj.bbadis.2015.06.015&partnerID=40&md5=9c3f7df1ace201f696f19c8c7bf9d510},\nabstract={Parkinson's disease (PD) is the most common neurodegenerative movement disorder caused primarily by selective degeneration of the dopaminergic neurons in substantia nigra. In this work the proteomes extracted from primary fibroblasts of two unrelated, hereditary cases of PD patients, with different parkin mutations, were compared with the proteomes extracted from commercial adult normal human dermal fibroblasts (NHDF) and primary fibroblasts from the healthy mother of one of the two patients. The results show that the fibroblasts from the two different cases of parkin-mutant patients display analogous alterations in the expression level of proteins involved in different cellular functions, like cytoskeleton structure-dynamics, calcium homeostasis, oxidative stress response, protein and RNA processing. © 2015.},\npublisher={Elsevier},\nissn={09254439},\ncoden={BBADE},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
\n
\n\n\n
\n Parkinson's disease (PD) is the most common neurodegenerative movement disorder caused primarily by selective degeneration of the dopaminergic neurons in substantia nigra. In this work the proteomes extracted from primary fibroblasts of two unrelated, hereditary cases of PD patients, with different parkin mutations, were compared with the proteomes extracted from commercial adult normal human dermal fibroblasts (NHDF) and primary fibroblasts from the healthy mother of one of the two patients. The results show that the fibroblasts from the two different cases of parkin-mutant patients display analogous alterations in the expression level of proteins involved in different cellular functions, like cytoskeleton structure-dynamics, calcium homeostasis, oxidative stress response, protein and RNA processing. © 2015.\n
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\n \n\n \n \n \n \n \n \n From Life to Life: through new materials and plasmonics.\n \n \n \n \n\n\n \n Strangi, G.; De Luca, A.; and Bartolino, R.\n\n\n \n\n\n\n Rendiconti Lincei, 26: 127-128. 2015.\n cited By 1\n\n\n\n
\n\n\n\n \n \n \"FromPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Strangi2015127,\nauthor={Strangi, G. and De Luca, A. and Bartolino, R.},\ntitle={From Life to Life: through new materials and plasmonics},\njournal={Rendiconti Lincei},\nyear={2015},\nvolume={26},\npages={127-128},\ndoi={10.1007/s12210-015-0434-1},\nnote={cited By 1},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84938977884&doi=10.1007%2fs12210-015-0434-1&partnerID=40&md5=13bba687339990cdb19652bda20bf8f0},\npublisher={Springer-Verlag Italia s.r.l.},\nissn={20374631},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n \n\n \n \n \n \n \n \n Exciton Fine Structure of CdSe/CdS Nanocrystals Determined by Polarization Microscopy at Room Temperature.\n \n \n \n \n\n\n \n Vezzoli, S.; Manceau, M.; Leménager, G.; Glorieux, Q.; Giacobino, E.; Carbone, L.; De Vittorio, M.; and Bramati, A.\n\n\n \n\n\n\n ACS Nano, 9(8): 7992-8003. 2015.\n cited By 44\n\n\n\n
\n\n\n\n \n \n \"ExcitonPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Vezzoli20157992,\nauthor={Vezzoli, S. and Manceau, M. and Leménager, G. and Glorieux, Q. and Giacobino, E. and Carbone, L. and De Vittorio, M. and Bramati, A.},\ntitle={Exciton Fine Structure of CdSe/CdS Nanocrystals Determined by Polarization Microscopy at Room Temperature},\njournal={ACS Nano},\nyear={2015},\nvolume={9},\nnumber={8},\npages={7992-8003},\ndoi={10.1021/acsnano.5b01354},\nnote={cited By 44},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84940032528&doi=10.1021%2facsnano.5b01354&partnerID=40&md5=99317ee397c2943ec0a48b3d10c13dbf},\nabstract={We present a method that allows determining the band-edge exciton fine structure of CdSe/CdS dot-in-rods samples based on single particle polarization measurements at room temperature. We model the measured emission polarization of such single particles considering the fine structure properties, the dielectric effect induced by the anisotropic shell, and the measurement configuration. We use this method to characterize the band-edge exciton fine structure splitting of various samples of dot-in-rods. We show that, when the diameter of the CdSe core increases, a transition from a spherical like band-edge exciton symmetry to a rod-like band edge exciton symmetry occurs. This explains the often reported large emission polarization of such particles compared to spherical CdSe/CdS emitters. (Chemical Equation Presented). © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={19360851},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We present a method that allows determining the band-edge exciton fine structure of CdSe/CdS dot-in-rods samples based on single particle polarization measurements at room temperature. We model the measured emission polarization of such single particles considering the fine structure properties, the dielectric effect induced by the anisotropic shell, and the measurement configuration. We use this method to characterize the band-edge exciton fine structure splitting of various samples of dot-in-rods. We show that, when the diameter of the CdSe core increases, a transition from a spherical like band-edge exciton symmetry to a rod-like band edge exciton symmetry occurs. This explains the often reported large emission polarization of such particles compared to spherical CdSe/CdS emitters. (Chemical Equation Presented). © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Flame retardant properties of plasma pre-treated/diamond-like carbon (DLC) coated cotton fabrics.\n \n \n \n \n\n\n \n Caschera, D.; Toro, R.; Federici, F.; Riccucci, C.; Ingo, G.; Gigli, G.; and Cortese, B.\n\n\n \n\n\n\n Cellulose, 22(4): 2797-2809. 2015.\n cited By 25\n\n\n\n
\n\n\n\n \n \n \"FlamePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Caschera20152797,\nauthor={Caschera, D. and Toro, R.G. and Federici, F. and Riccucci, C. and Ingo, G.M. and Gigli, G. and Cortese, B.},\ntitle={Flame retardant properties of plasma pre-treated/diamond-like carbon (DLC) coated cotton fabrics},\njournal={Cellulose},\nyear={2015},\nvolume={22},\nnumber={4},\npages={2797-2809},\ndoi={10.1007/s10570-015-0661-8},\nnote={cited By 25},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84937975932&doi=10.1007%2fs10570-015-0661-8&partnerID=40&md5=6cd6cb8d3ab0063f76f844851ffbb79b},\nabstract={Textiles with superior anti-flammability properties combined with minimal environmental impact are extremely necessary to reduce fire-related issues. In this regard, diamond-like carbon (DLC) coatings on cotton fabrics may represent promising candidates as potential flame-retardant (FR) materials. Herein, superhydrophobic and fire-resistant cotton fabrics were fabricated through a two-step plasma strategy by alternately exposing substrates to H<inf>2</inf> and O<inf>2</inf> plasma pre-treatments and subsequent DLC deposition. Fourier transform-infrared spectroscopy analysis has revealed that different plasma pre-treatments can impose surface modifications on the chemical structure of cotton, especially in carboxylic and hydroxyl groups, leading to a radical alteration of surface roughness and of the crystalline cellulosic external structure. These changes deeply influenced the growth of DLC thin films and the surface properties of cotton fabric because of the combination of a hierarchical structure and surface chemistry as verified using field emission gun-scanning electron microscopy and water contact angle measurements. The effects of both specific gases used in the pre-treatment step and duration of pre-treatment were analysed and compared using thermogravimetric analyses. The H<inf>2</inf>-pre-treated DLC cottons exhibited good potential as an FR material, showing improved thermal stability in respect to untreated cotton, as evidenced by increased ignition times. Moreover, vertical burning tests have demonstrated that DLC-cotton systems exhibit enhanced flammability resistance. © 2015, Springer Science+Business Media Dordrecht.},\npublisher={Kluwer Academic Publishers},\nissn={09690239},\ncoden={CELLE},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
\n
\n\n\n
\n Textiles with superior anti-flammability properties combined with minimal environmental impact are extremely necessary to reduce fire-related issues. In this regard, diamond-like carbon (DLC) coatings on cotton fabrics may represent promising candidates as potential flame-retardant (FR) materials. Herein, superhydrophobic and fire-resistant cotton fabrics were fabricated through a two-step plasma strategy by alternately exposing substrates to H2 and O2 plasma pre-treatments and subsequent DLC deposition. Fourier transform-infrared spectroscopy analysis has revealed that different plasma pre-treatments can impose surface modifications on the chemical structure of cotton, especially in carboxylic and hydroxyl groups, leading to a radical alteration of surface roughness and of the crystalline cellulosic external structure. These changes deeply influenced the growth of DLC thin films and the surface properties of cotton fabric because of the combination of a hierarchical structure and surface chemistry as verified using field emission gun-scanning electron microscopy and water contact angle measurements. The effects of both specific gases used in the pre-treatment step and duration of pre-treatment were analysed and compared using thermogravimetric analyses. The H2-pre-treated DLC cottons exhibited good potential as an FR material, showing improved thermal stability in respect to untreated cotton, as evidenced by increased ignition times. Moreover, vertical burning tests have demonstrated that DLC-cotton systems exhibit enhanced flammability resistance. © 2015, Springer Science+Business Media Dordrecht.\n
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\n \n\n \n \n \n \n \n \n Liquid crystals order in polymeric microchannels.\n \n \n \n \n\n\n \n Palermo, G.; De Sio, L.; Caputo, R.; Umeton, C.; and Bartolino, R.\n\n\n \n\n\n\n Volume 2 Springer International Publishing, 2015.\n cited By 0\n\n\n\n
\n\n\n\n \n \n \"LiquidPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@BOOK{Palermo20151,\nauthor={Palermo, G. and De Sio, L. and Caputo, R. and Umeton, C. and Bartolino, R.},\ntitle={Liquid crystals order in polymeric microchannels},\njournal={Liquid Crystalline Polymers},\nyear={2015},\nvolume={2},\npages={1-14},\ndoi={10.1007/978-3-319-20270-9_1},\nnote={cited By 0},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84955697358&doi=10.1007%2f978-3-319-20270-9_1&partnerID=40&md5=d635a11e0a706754a4743fd110931c32},\npublisher={Springer International Publishing},\nisbn={9783319202709; 9783319202693},\ndocument_type={Book Chapter},\nsource={Scopus},\n}\n\n
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\n \n\n \n \n \n \n \n \n Electrically controllable multicolor cholesteric laser.\n \n \n \n \n\n\n \n Saadaoui, L.; Petriashvili, G.; De Santo, M.; Hamdi, R.; Othman, T.; and Barberi, R.\n\n\n \n\n\n\n Optics Express, 23(17): 22922-22927. 2015.\n cited By 4\n\n\n\n
\n\n\n\n \n \n \"ElectricallyPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Saadaoui201522922,\nauthor={Saadaoui, L. and Petriashvili, G. and De Santo, M.P. and Hamdi, R. and Othman, T. and Barberi, R.},\ntitle={Electrically controllable multicolor cholesteric laser},\njournal={Optics Express},\nyear={2015},\nvolume={23},\nnumber={17},\npages={22922-22927},\ndoi={10.1364/OE.23.022922},\nnote={cited By 4},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84957599823&doi=10.1364%2fOE.23.022922&partnerID=40&md5=e2b13da17c1fc87c270ba39cebb3ff4a},\nabstract={A new strategy to obtain multicolor lasing from cholesteric liquid crystals is presented. A four layer cell is prepared with three different cholesteric layers and a layer containing a photoluminescent dye. The three cholesteric mixtures are prepared so that their photonic band gaps are partially overlapped. Through this combination, two laser lines are obtained in the same spot under the pumping beam irradiation. Eventually, one of the laser lines can be switched off if an electric field is applied to the first or the last cholesteric layer. © 2015 Optical Society of America.},\npublisher={OSA - The Optical Society},\nissn={10944087},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n A new strategy to obtain multicolor lasing from cholesteric liquid crystals is presented. A four layer cell is prepared with three different cholesteric layers and a layer containing a photoluminescent dye. The three cholesteric mixtures are prepared so that their photonic band gaps are partially overlapped. Through this combination, two laser lines are obtained in the same spot under the pumping beam irradiation. Eventually, one of the laser lines can be switched off if an electric field is applied to the first or the last cholesteric layer. © 2015 Optical Society of America.\n
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\n \n\n \n \n \n \n \n \n Comment on \"linear Wave Dynamics Explains Observations Attributed to Dark Solitons in a Polariton Quantum Fluid\".\n \n \n \n \n\n\n \n Amo, A.; Bloch, J.; Bramati, A.; Carusotto, I.; Ciuti, C.; Deveaud, B.; Giacobino, E.; Grosso, G.; Kamchatnov, A.; Malpuech, G.; Pavloff, N.; Pigeon, S.; Sanvitto, D.; and Solnyshkov, D.\n\n\n \n\n\n\n Physical Review Letters, 115(8). 2015.\n cited By 8\n\n\n\n
\n\n\n\n \n \n \"CommentPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Amo2015,\nauthor={Amo, A. and Bloch, J. and Bramati, A. and Carusotto, I. and Ciuti, C. and Deveaud, B. and Giacobino, E. and Grosso, G. and Kamchatnov, A. and Malpuech, G. and Pavloff, N. and Pigeon, S. and Sanvitto, D. and Solnyshkov, D.D.},\ntitle={Comment on "linear Wave Dynamics Explains Observations Attributed to Dark Solitons in a Polariton Quantum Fluid"},\njournal={Physical Review Letters},\nyear={2015},\nvolume={115},\nnumber={8},\ndoi={10.1103/PhysRevLett.115.089401},\nart_number={089401},\nnote={cited By 8},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84940688692&doi=10.1103%2fPhysRevLett.115.089401&partnerID=40&md5=69b3d57f26ee4699814fadcc1adf4ac9},\npublisher={American Physical Society},\nissn={00319007},\ncoden={PRLTA},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n \n\n \n \n \n \n \n \n Confined H(1s) and H(2p) under different geometries.\n \n \n \n \n\n\n \n Longo, G.; Longo, S.; and Giordano, D.\n\n\n \n\n\n\n Physica Scripta, 90(8). 2015.\n cited By 2\n\n\n\n
\n\n\n\n \n \n \"ConfinedPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Longo2015,\nauthor={Longo, G.M. and Longo, S. and Giordano, D.},\ntitle={Confined H(1s) and H(2p) under different geometries},\njournal={Physica Scripta},\nyear={2015},\nvolume={90},\nnumber={8},\ndoi={10.1088/0031-8949/90/8/085402},\nart_number={085402},\nnote={cited By 2},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84937943490&doi=10.1088%2f0031-8949%2f90%2f8%2f085402&partnerID=40&md5=b72b90bbb4f71b6553168bdd784b1bb9},\nabstract={In this paper the diffusion Monte Carlo method is applied to the confined hydrogen atom with different confinement geometries. This approach is validated using the much studied spherical and cylindrical confinements and then applied to cubical and squared ones, for which data are not available, as new applications of the method relevant to solid state physics. The energy eigenvalues of the ground state and one low-lying excited state are reported as a function of the characteristic confinement length. © 2015 The Royal Swedish Academy of Sciences.},\npublisher={Institute of Physics Publishing},\nissn={00318949},\ncoden={PHSTB},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n In this paper the diffusion Monte Carlo method is applied to the confined hydrogen atom with different confinement geometries. This approach is validated using the much studied spherical and cylindrical confinements and then applied to cubical and squared ones, for which data are not available, as new applications of the method relevant to solid state physics. The energy eigenvalues of the ground state and one low-lying excited state are reported as a function of the characteristic confinement length. © 2015 The Royal Swedish Academy of Sciences.\n
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\n \n\n \n \n \n \n \n \n Micromotors with asymmetric shape that efficiently convert light into work by thermocapillary effects.\n \n \n \n \n\n\n \n Maggi, C.; Saglimbeni, F.; Dipalo, M.; De Angelis, F.; and Di Leonardo, R.\n\n\n \n\n\n\n Nature Communications, 6. 2015.\n cited By 109\n\n\n\n
\n\n\n\n \n \n \"MicromotorsPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Maggi2015,\nauthor={Maggi, C. and Saglimbeni, F. and Dipalo, M. and De Angelis, F. and Di Leonardo, R.},\ntitle={Micromotors with asymmetric shape that efficiently convert light into work by thermocapillary effects},\njournal={Nature Communications},\nyear={2015},\nvolume={6},\ndoi={10.1038/ncomms8855},\nart_number={7855},\nnote={cited By 109},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84938223652&doi=10.1038%2fncomms8855&partnerID=40&md5=5841978bad543b209e948125050ec095},\nabstract={The direct conversion of light into work allows the driving of micron-sized motors in a contactless, controllable and continuous way. Light-to-work conversion can involve either direct transfer of optical momentum or indirect opto-thermal effects. Both strategies have been implemented using different coupling mechanisms. However, the resulting efficiencies are always very low, and high power densities, generally obtained by focused laser beams, are required. Here we show that microfabricated gears, sitting on a liquid-air interface, can efficiently convert absorbed light into rotational motion through a thermocapillary effect. We demonstrate rotation rates up to 300r.p.m. under wide-field illumination with incoherent light. Our analysis shows that thermocapillary propulsion is one of the strongest mechanisms for light actuation at the micron- and nanoscale.},\npublisher={Nature Publishing Group},\nissn={20411723},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The direct conversion of light into work allows the driving of micron-sized motors in a contactless, controllable and continuous way. Light-to-work conversion can involve either direct transfer of optical momentum or indirect opto-thermal effects. Both strategies have been implemented using different coupling mechanisms. However, the resulting efficiencies are always very low, and high power densities, generally obtained by focused laser beams, are required. Here we show that microfabricated gears, sitting on a liquid-air interface, can efficiently convert absorbed light into rotational motion through a thermocapillary effect. We demonstrate rotation rates up to 300r.p.m. under wide-field illumination with incoherent light. Our analysis shows that thermocapillary propulsion is one of the strongest mechanisms for light actuation at the micron- and nanoscale.\n
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\n \n\n \n \n \n \n \n \n Dielectric relaxation in non-polar nematic liquid crystal devices.\n \n \n \n \n\n\n \n Carbone, F.; Mazzulla, A.; Ciuchi, F.; and Scaramuzza, N.\n\n\n \n\n\n\n European Physical Journal Plus, 130(7). 2015.\n cited By 5\n\n\n\n
\n\n\n\n \n \n \"DielectricPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Carbone2015,\nauthor={Carbone, F. and Mazzulla, A. and Ciuchi, F. and Scaramuzza, N.},\ntitle={Dielectric relaxation in non-polar nematic liquid crystal devices},\njournal={European Physical Journal Plus},\nyear={2015},\nvolume={130},\nnumber={7},\npage_count={7},\ndoi={10.1140/epjp/i2015-15151-0},\nart_number={151},\nnote={cited By 5},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84938253962&doi=10.1140%2fepjp%2fi2015-15151-0&partnerID=40&md5=0430abf417b7f43051dccbff547270e7},\nabstract={We investigate the dielectric relaxation in non-polar nematic planar aligned liquid crystal samples by means of both dielectric spectroscopy and a transient current method. The dielectric functions, obtained by the impedance data, are modeled by the modified Havriliak-Negami method, which allows to determine spectra in terms of permittivity, conductivity and dielectric relaxation. Further information on the involved electric charge and the ion mobility is achieved by means of current measurements. The outcomes demonstrate that the effective relaxation times originate from ionic polarization and depend on the interfaces properties, pointing out the influence of the layered structure. © 2015, Società Italiana di Fisica and Springer-Verlag Berlin Heidelberg.},\npublisher={Springer Verlag},\nissn={21905444},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We investigate the dielectric relaxation in non-polar nematic planar aligned liquid crystal samples by means of both dielectric spectroscopy and a transient current method. The dielectric functions, obtained by the impedance data, are modeled by the modified Havriliak-Negami method, which allows to determine spectra in terms of permittivity, conductivity and dielectric relaxation. Further information on the involved electric charge and the ion mobility is achieved by means of current measurements. The outcomes demonstrate that the effective relaxation times originate from ionic polarization and depend on the interfaces properties, pointing out the influence of the layered structure. © 2015, Società Italiana di Fisica and Springer-Verlag Berlin Heidelberg.\n
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\n \n\n \n \n \n \n \n \n Multicomponent polariton superfluidity in the optical parametric oscillator regime.\n \n \n \n \n\n\n \n Berceanu, A.; Dominici, L.; Carusotto, I.; Ballarini, D.; Cancellieri, E.; Gigli, G.; Szymańska, M.; Sanvitto, D.; and Marchetti, F.\n\n\n \n\n\n\n Physical Review B - Condensed Matter and Materials Physics, 92(3). 2015.\n cited By 8\n\n\n\n
\n\n\n\n \n \n \"MulticomponentPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Berceanu2015,\nauthor={Berceanu, A.C. and Dominici, L. and Carusotto, I. and Ballarini, D. and Cancellieri, E. and Gigli, G. and Szymańska, M.H. and Sanvitto, D. and Marchetti, F.M.},\ntitle={Multicomponent polariton superfluidity in the optical parametric oscillator regime},\njournal={Physical Review B - Condensed Matter and Materials Physics},\nyear={2015},\nvolume={92},\nnumber={3},\ndoi={10.1103/PhysRevB.92.035307},\nart_number={035307},\nnote={cited By 8},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84938929402&doi=10.1103%2fPhysRevB.92.035307&partnerID=40&md5=3d392af983d973acf53a1d98523599f5},\nabstract={Superfluidity, which is the ability of a liquid or gas to flow with zero viscosity, is one of the most remarkable implications of collective quantum coherence. In equilibrium systems such as liquid 4He and ultracold atomic gases, superfluid behavior conjugates diverse yet related phenomena, such as a persistent metastable flow in multiply connected geometries and the existence of a critical velocity for frictionless flow when hitting a static defect. The link between these different aspects of superfluid behavior is far less clear in driven-dissipative systems displaying collective coherence, such as microcavity polaritons, which raises important questions about their concurrency. With a joint theoretical and experimental study, we show that the scenario is particularly rich for polaritons driven in a three-fluid collective coherent regime, i.e., a so-called optical parametric oscillator. On the one hand, the spontaneous macroscopic coherence following the phase locking of the signal and idler fluids has been shown to be responsible for their simultaneous quantized flow metastability. On the other hand, we show here that the pump, signal, and idler have distinct responses when hitting a static defect; while the signal displays modulations that are barely perceptible, the ones appearing in the pump and idler are determined by their mutual coupling due to nonlinear and parametric processes. © 2015 American Physical Society. ©2015 American Physical Society.},\npublisher={American Physical Society},\nissn={10980121},\ncoden={PRBMD},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
\n
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\n Superfluidity, which is the ability of a liquid or gas to flow with zero viscosity, is one of the most remarkable implications of collective quantum coherence. In equilibrium systems such as liquid 4He and ultracold atomic gases, superfluid behavior conjugates diverse yet related phenomena, such as a persistent metastable flow in multiply connected geometries and the existence of a critical velocity for frictionless flow when hitting a static defect. The link between these different aspects of superfluid behavior is far less clear in driven-dissipative systems displaying collective coherence, such as microcavity polaritons, which raises important questions about their concurrency. With a joint theoretical and experimental study, we show that the scenario is particularly rich for polaritons driven in a three-fluid collective coherent regime, i.e., a so-called optical parametric oscillator. On the one hand, the spontaneous macroscopic coherence following the phase locking of the signal and idler fluids has been shown to be responsible for their simultaneous quantized flow metastability. On the other hand, we show here that the pump, signal, and idler have distinct responses when hitting a static defect; while the signal displays modulations that are barely perceptible, the ones appearing in the pump and idler are determined by their mutual coupling due to nonlinear and parametric processes. © 2015 American Physical Society. ©2015 American Physical Society.\n
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\n \n\n \n \n \n \n \n \n Subdiffraction Light Concentration by J-Aggregate Nanostructures.\n \n \n \n \n\n\n \n Cacciola, A.; Triolo, C.; Di Stefano, O.; Genco, A.; Mazzeo, M.; Saija, R.; Patanè, S.; and Savasta, S.\n\n\n \n\n\n\n ACS Photonics, 2(7): 971-979. 2015.\n cited By 28\n\n\n\n
\n\n\n\n \n \n \"SubdiffractionPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Cacciola2015971,\nauthor={Cacciola, A. and Triolo, C. and Di Stefano, O. and Genco, A. and Mazzeo, M. and Saija, R. and Patanè, S. and Savasta, S.},\ntitle={Subdiffraction Light Concentration by J-Aggregate Nanostructures},\njournal={ACS Photonics},\nyear={2015},\nvolume={2},\nnumber={7},\npages={971-979},\ndoi={10.1021/acsphotonics.5b00197},\nnote={cited By 28},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84937042110&doi=10.1021%2facsphotonics.5b00197&partnerID=40&md5=fc7a1ab42ef6c907e5db9ebd54ddd536},\nabstract={We show, by accurate scattering calculations, that nanostructures obtained from thin films of J-aggregate dyes, despite their insulating behavior, are able to concentrate the electromagnetic field at optical frequencies like metallic nanoparticles. These results promise to widely enlarge the range of plasmonic materials, thus opening new perspectives in nanophotonics. Specifically we investigate ultrathin nanodisks and nanodisk dimers that can be obtained by standard nanolithography and nanopatterning techniques. These molecular aggregates display highly attractive nonlinear optical properties, which can be exploited for the realization of ultracompact devices for switching by light on the nanoscale without the need of additional nonlinear materials. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={23304022},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We show, by accurate scattering calculations, that nanostructures obtained from thin films of J-aggregate dyes, despite their insulating behavior, are able to concentrate the electromagnetic field at optical frequencies like metallic nanoparticles. These results promise to widely enlarge the range of plasmonic materials, thus opening new perspectives in nanophotonics. Specifically we investigate ultrathin nanodisks and nanodisk dimers that can be obtained by standard nanolithography and nanopatterning techniques. These molecular aggregates display highly attractive nonlinear optical properties, which can be exploited for the realization of ultracompact devices for switching by light on the nanoscale without the need of additional nonlinear materials. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Advances in Use of Capsule-Based Fluorescent Sensors for Measuring Acidification of Endocytic Compartments in Cells with Altered Expression of V-ATPase Subunit V1G1.\n \n \n \n \n\n\n \n De Luca, M.; Ferraro, M.; Hartmann, R.; Rivera-Gil, P.; Klingl, A.; Nazarenus, M.; Ramirez, A.; Parak, W.; Bucci, C.; Rinaldi, R.; and Del Mercato, L.\n\n\n \n\n\n\n ACS Applied Materials and Interfaces, 7(27): 15052-15060. 2015.\n cited By 13\n\n\n\n
\n\n\n\n \n \n \"AdvancesPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{DeLuca201515052,\nauthor={De Luca, M. and Ferraro, M.M. and Hartmann, R. and Rivera-Gil, P. and Klingl, A. and Nazarenus, M. and Ramirez, A. and Parak, W.J. and Bucci, C. and Rinaldi, R. and Del Mercato, L.L.},\ntitle={Advances in Use of Capsule-Based Fluorescent Sensors for Measuring Acidification of Endocytic Compartments in Cells with Altered Expression of V-ATPase Subunit V1G1},\njournal={ACS Applied Materials and Interfaces},\nyear={2015},\nvolume={7},\nnumber={27},\npages={15052-15060},\ndoi={10.1021/acsami.5b04375},\nnote={cited By 13},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84937053893&doi=10.1021%2facsami.5b04375&partnerID=40&md5=50d478d7bc611402551e53a3d136ef51},\nabstract={Acidification of eukaryotic cell compartments is accomplished by vacuolar H+-ATPases (V-ATPases), large multisubunit complexes able to pump protons into the lumen of organelles or in the extracellular medium. V-ATPases are involved in a number of physiological cellular processes, and thus regulation of V-ATPase activity is of crucial importance for the cell. Indeed, dysfunction of V-ATPase or alterations of acidification have been recently recognized as key factors in a variety of human diseases. In this study, we applied capsule-based pH sensors and a real-time tracking method for investigating the role of the V1G1 subunit of V-ATPases in regulating the activity of the proton pump. We first constructed stable cell lines overexpressing or silencing the subunit V1G1. Second, we used fluorescent capsule-based pH sensors to monitor acidification before and during internalization by modified and control living cells. By using a simple real-time method for tracking capsule internalization, we were able to identify different capsule acidification levels with respect to each analyzed cell and to establish the kinetics for each. The intracellular pH measurements indicate a delay in acidification in either V1G1-overexpressing or V1G1-silenced cells compared to controls. Finally, in an independent set of experiments, we applied transmission electron microscopy and confocal fluorescence microscopy to further investigate the internalization of the capsules. Both analyses confirm that capsules are engulfed in acidic vesicular structures in modified and control cell lines. The use of capsule-based pH sensors allowed demonstration of the importance of the V1G1 subunit in V-ATPase activity concerning intravesicular acidification. We believe that the combined use of these pH-sensor system and such a real-time method for tracking their internalization path would contribute to systematically measure the proton concentration changes inside the endocytic compartments in various cell systems. This approach would provide fundamental information regarding molecular mechanisms and factors that regulate intracellular acidification, vesicular trafficking, and cytoskeletal reorganizations. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={19448244},\npubmed_id={26086317},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Acidification of eukaryotic cell compartments is accomplished by vacuolar H+-ATPases (V-ATPases), large multisubunit complexes able to pump protons into the lumen of organelles or in the extracellular medium. V-ATPases are involved in a number of physiological cellular processes, and thus regulation of V-ATPase activity is of crucial importance for the cell. Indeed, dysfunction of V-ATPase or alterations of acidification have been recently recognized as key factors in a variety of human diseases. In this study, we applied capsule-based pH sensors and a real-time tracking method for investigating the role of the V1G1 subunit of V-ATPases in regulating the activity of the proton pump. We first constructed stable cell lines overexpressing or silencing the subunit V1G1. Second, we used fluorescent capsule-based pH sensors to monitor acidification before and during internalization by modified and control living cells. By using a simple real-time method for tracking capsule internalization, we were able to identify different capsule acidification levels with respect to each analyzed cell and to establish the kinetics for each. The intracellular pH measurements indicate a delay in acidification in either V1G1-overexpressing or V1G1-silenced cells compared to controls. Finally, in an independent set of experiments, we applied transmission electron microscopy and confocal fluorescence microscopy to further investigate the internalization of the capsules. Both analyses confirm that capsules are engulfed in acidic vesicular structures in modified and control cell lines. The use of capsule-based pH sensors allowed demonstration of the importance of the V1G1 subunit in V-ATPase activity concerning intravesicular acidification. We believe that the combined use of these pH-sensor system and such a real-time method for tracking their internalization path would contribute to systematically measure the proton concentration changes inside the endocytic compartments in various cell systems. This approach would provide fundamental information regarding molecular mechanisms and factors that regulate intracellular acidification, vesicular trafficking, and cytoskeletal reorganizations. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Statistical physics of nonlinear wave interaction.\n \n \n \n \n\n\n \n Antenucci, F.; Ibáñez Berganza, M.; and Leuzzi, L.\n\n\n \n\n\n\n Physical Review B - Condensed Matter and Materials Physics, 92(1). 2015.\n cited By 10\n\n\n\n
\n\n\n\n \n \n \"StatisticalPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Antenucci2015,\nauthor={Antenucci, F. and Ibáñez Berganza, M. and Leuzzi, L.},\ntitle={Statistical physics of nonlinear wave interaction},\njournal={Physical Review B - Condensed Matter and Materials Physics},\nyear={2015},\nvolume={92},\nnumber={1},\ndoi={10.1103/PhysRevB.92.014204},\nart_number={014204},\nnote={cited By 10},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84937880220&doi=10.1103%2fPhysRevB.92.014204&partnerID=40&md5=7ae18ee2c728016b97078ac4e385be20},\nabstract={The thermodynamic properties of vector [O(2) and complex spherical] models with four-body interactions are analyzed. When defined in dense topologies, these are effective models for the nonlinear interaction of scalar fields in the presence of a stochastic noise, as has been well established for the case of the mode-locking laser formation in a closed cavity. With the help of an efficient Monte Carlo algorithm we show how, beyond the fully connected case, rich phenomenology emerges. Below a certain dilution threshold, the spherical model condenses in a nonequipartite way, while in the XY model the transition becomes continuous and the O(2) symmetry remains unbroken. We attribute this fact to the invariance under gauge transformations. The introduction of topological inhomogeneities in the network of quadruplets induces some features: again symmetry conservation; the vanishing of two-point correlators; and a dynamical correlation function presenting two time scales, the large one being related to the transition between different degenerated configurations, connected by particular gauge transformations. We discuss possible experimental implications of these results in the context of nonlinear optics. © 2015 American Physical Society.},\npublisher={American Physical Society},\nissn={10980121},\ncoden={PRBMD},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The thermodynamic properties of vector [O(2) and complex spherical] models with four-body interactions are analyzed. When defined in dense topologies, these are effective models for the nonlinear interaction of scalar fields in the presence of a stochastic noise, as has been well established for the case of the mode-locking laser formation in a closed cavity. With the help of an efficient Monte Carlo algorithm we show how, beyond the fully connected case, rich phenomenology emerges. Below a certain dilution threshold, the spherical model condenses in a nonequipartite way, while in the XY model the transition becomes continuous and the O(2) symmetry remains unbroken. We attribute this fact to the invariance under gauge transformations. The introduction of topological inhomogeneities in the network of quadruplets induces some features: again symmetry conservation; the vanishing of two-point correlators; and a dynamical correlation function presenting two time scales, the large one being related to the transition between different degenerated configurations, connected by particular gauge transformations. We discuss possible experimental implications of these results in the context of nonlinear optics. © 2015 American Physical Society.\n
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\n \n\n \n \n \n \n \n \n Role of Polymer in Hybrid Polymer/PbS Quantum Dot Solar Cells.\n \n \n \n \n\n\n \n Mastria, R.; Rizzo, A.; Giansante, C.; Ballarini, D.; Dominici, L.; Inganäs, O.; and Gigli, G.\n\n\n \n\n\n\n Journal of Physical Chemistry C, 119(27): 14972-14979. 2015.\n cited By 35\n\n\n\n
\n\n\n\n \n \n \"RolePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Mastria201514972,\nauthor={Mastria, R. and Rizzo, A. and Giansante, C. and Ballarini, D. and Dominici, L. and Inganäs, O. and Gigli, G.},\ntitle={Role of Polymer in Hybrid Polymer/PbS Quantum Dot Solar Cells},\njournal={Journal of Physical Chemistry C},\nyear={2015},\nvolume={119},\nnumber={27},\npages={14972-14979},\ndoi={10.1021/acs.jpcc.5b03761},\nnote={cited By 35},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84936867775&doi=10.1021%2facs.jpcc.5b03761&partnerID=40&md5=34db10da860db42312846de66ddf1b30},\nabstract={Hybrid nanocomposites (HCs) obtained by blend solutions of conjugated polymers and colloidal semiconductor nanocrystals are among the most promising materials to be exploited in solution-processed photovoltaic applications. The comprehension of the operating principles of solar cells based on HCs thus represents a crucial step toward the rational engineering of high performing photovoltaic devices. Here we investigate the effect of conjugated polymers on hybrid solar cell performances by taking advantage from an optimized morphology of the HCs comprising lead sulfide quantum dots (PbS QDs). Uncommonly, we find that larger photocurrent densities are achieved by HCs incorporating wide-bandgap polymers. A combination of spectroscopic and electro-optical measurements suggests that wide-bandgap polymers promote efficient charge/exciton transfer processes and hinder the population of midgap states on PbS QDs. Our findings underline the key role of the polymer in HC-based solar cells in the activation/deactivation of charge transfer/loss pathways. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={19327447},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Hybrid nanocomposites (HCs) obtained by blend solutions of conjugated polymers and colloidal semiconductor nanocrystals are among the most promising materials to be exploited in solution-processed photovoltaic applications. The comprehension of the operating principles of solar cells based on HCs thus represents a crucial step toward the rational engineering of high performing photovoltaic devices. Here we investigate the effect of conjugated polymers on hybrid solar cell performances by taking advantage from an optimized morphology of the HCs comprising lead sulfide quantum dots (PbS QDs). Uncommonly, we find that larger photocurrent densities are achieved by HCs incorporating wide-bandgap polymers. A combination of spectroscopic and electro-optical measurements suggests that wide-bandgap polymers promote efficient charge/exciton transfer processes and hinder the population of midgap states on PbS QDs. Our findings underline the key role of the polymer in HC-based solar cells in the activation/deactivation of charge transfer/loss pathways. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Quantitative constraint-based computational model of tumor-to-stroma coupling via lactate shuttle.\n \n \n \n \n\n\n \n Capuani, F.; De Martino, D.; Marinari, E.; and De Martino, A.\n\n\n \n\n\n\n Scientific Reports, 5. 2015.\n cited By 9\n\n\n\n
\n\n\n\n \n \n \"QuantitativePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Capuani2015,\nauthor={Capuani, F. and De Martino, D. and Marinari, E. and De Martino, A.},\ntitle={Quantitative constraint-based computational model of tumor-to-stroma coupling via lactate shuttle},\njournal={Scientific Reports},\nyear={2015},\nvolume={5},\ndoi={10.1038/srep11880},\nart_number={11880},\nnote={cited By 9},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84936854728&doi=10.1038%2fsrep11880&partnerID=40&md5=5fac26c922099a5f77c42f7023620774},\nabstract={Cancer cells utilize large amounts of ATP to sustain growth, relying primarily on non-oxidative, fermentative pathways for its production. In many types of cancers this leads, even in the presence of oxygen, to the secretion of carbon equivalents (usually in the form of lactate) in the cell's surroundings, a feature known as the Warburg effect. While the molecular basis of this phenomenon are still to be elucidated, it is clear that the spilling of energy resources contributes to creating a peculiar microenvironment for tumors, possibly characterized by a degree of toxicity. This suggests that mechanisms for recycling the fermentation products (e.g. a lactate shuttle) may be active, effectively inducing a mutually beneficial metabolic coupling between aberrant and non-aberrant cells. Here we analyze this scenario through a large-scale in silico metabolic model of interacting human cells. By going beyond the cell-autonomous description, we show that elementary physico-chemical constraints indeed favor the establishment of such a coupling under very broad conditions. The characterization we obtained by tuning the aberrant cell's demand for ATP, amino-acids and fatty acids and/or the imbalance in nutrient partitioning provides quantitative support to the idea that synergistic multi-cell effects play a central role in cancer sustainment. © 2015, Nature Publishing Group. All rights reserved.},\npublisher={Nature Publishing Group},\nissn={20452322},\npubmed_id={26149467},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Cancer cells utilize large amounts of ATP to sustain growth, relying primarily on non-oxidative, fermentative pathways for its production. In many types of cancers this leads, even in the presence of oxygen, to the secretion of carbon equivalents (usually in the form of lactate) in the cell's surroundings, a feature known as the Warburg effect. While the molecular basis of this phenomenon are still to be elucidated, it is clear that the spilling of energy resources contributes to creating a peculiar microenvironment for tumors, possibly characterized by a degree of toxicity. This suggests that mechanisms for recycling the fermentation products (e.g. a lactate shuttle) may be active, effectively inducing a mutually beneficial metabolic coupling between aberrant and non-aberrant cells. Here we analyze this scenario through a large-scale in silico metabolic model of interacting human cells. By going beyond the cell-autonomous description, we show that elementary physico-chemical constraints indeed favor the establishment of such a coupling under very broad conditions. The characterization we obtained by tuning the aberrant cell's demand for ATP, amino-acids and fatty acids and/or the imbalance in nutrient partitioning provides quantitative support to the idea that synergistic multi-cell effects play a central role in cancer sustainment. © 2015, Nature Publishing Group. All rights reserved.\n
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\n \n\n \n \n \n \n \n \n SELF-CONSISTENT CASTAING DISTRIBUTION OF SOLAR WIND TURBULENT FLUCTUATIONS.\n \n \n \n \n\n\n \n Sorriso-Valvo, L.; Marino, R.; Lijoi, L.; Perri, S.; and Carbone, V.\n\n\n \n\n\n\n Astrophysical Journal, 807(1). 2015.\n cited By 16\n\n\n\n
\n\n\n\n \n \n \"SELF-CONSISTENTPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Sorriso-Valvo2015,\nauthor={Sorriso-Valvo, L. and Marino, R. and Lijoi, L. and Perri, S. and Carbone, V.},\ntitle={SELF-CONSISTENT CASTAING DISTRIBUTION OF SOLAR WIND TURBULENT FLUCTUATIONS},\njournal={Astrophysical Journal},\nyear={2015},\nvolume={807},\nnumber={1},\ndoi={10.1088/0004-637X/807/1/86},\nart_number={86},\nnote={cited By 16},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84936792207&doi=10.1088%2f0004-637X%2f807%2f1%2f86&partnerID=40&md5=ed4fddced85dc276d5b9698f8bf74af0},\nabstract={The intermittent behavior of solar wind turbulent fluctuations has often been investigated through the modeling of their probability distribution functions (PDFs). Among others, the Castaing model has successfully been used in the past. In this paper, the energy dissipation field of solar wind turbulence has been studied for fast, slow, and polar wind samples recorded by Helios 2 and Ulysses spacecraft. The statistical description of the dissipation rate has then been used to remove intermittency through conditioning of the PDFs. Based on such observation, a self-consistent, parameter-free Castaing model is presented. The self-consistent model is tested against experimental PDFs, showing good agreement and supporting the picture of a multifractal energy cascade at the origin of solar wind intermittency. © 2015. The American Astronomical Society. All rights reserved.},\npublisher={Institute of Physics Publishing},\nissn={0004637X},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The intermittent behavior of solar wind turbulent fluctuations has often been investigated through the modeling of their probability distribution functions (PDFs). Among others, the Castaing model has successfully been used in the past. In this paper, the energy dissipation field of solar wind turbulence has been studied for fast, slow, and polar wind samples recorded by Helios 2 and Ulysses spacecraft. The statistical description of the dissipation rate has then been used to remove intermittency through conditioning of the PDFs. Based on such observation, a self-consistent, parameter-free Castaing model is presented. The self-consistent model is tested against experimental PDFs, showing good agreement and supporting the picture of a multifractal energy cascade at the origin of solar wind intermittency. © 2015. The American Astronomical Society. All rights reserved.\n
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\n \n\n \n \n \n \n \n \n The beginnings of plasmomechanics: towards plasmonic strain sensors.\n \n \n \n \n\n\n \n Maurer, T.; Marae-Djouda, J.; Cataldi, U.; Gontier, A.; Montay, G.; Madi, Y.; Panicaud, B.; Macias, D.; Adam, P.; Lévêque, G.; Bürgi, T.; and Caputo, R.\n\n\n \n\n\n\n Frontiers of Materials Science, 9(2): 170-177. 2015.\n cited By 31\n\n\n\n
\n\n\n\n \n \n \"ThePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Maurer2015170,\nauthor={Maurer, T. and Marae-Djouda, J. and Cataldi, U. and Gontier, A. and Montay, G. and Madi, Y. and Panicaud, B. and Macias, D. and Adam, P.-M. and Lévêque, G. and Bürgi, T. and Caputo, R.},\ntitle={The beginnings of plasmomechanics: towards plasmonic strain sensors},\njournal={Frontiers of Materials Science},\nyear={2015},\nvolume={9},\nnumber={2},\npages={170-177},\ndoi={10.1007/s11706-015-0290-z},\nnote={cited By 31},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84929836589&doi=10.1007%2fs11706-015-0290-z&partnerID=40&md5=974a05266c657d1f8ea1621af7c4cf55},\nabstract={This article exposes the beginnings of a new field which could be named as “plasmomechanics”. Plasmomechanics comes from the convergence between mechanics and plasmonics. Here we discuss a relatively recent topic whose technological aim is the development of plasmonic strain sensors. The idea is based on the ability to deduce Au nanoparticles (NPs) distance distributions from polarized optical extinction spectroscopy which could thus give access to material strains. Variations of interparticle distances distributions can indeed lead to variations of plasmonic coupling and thus to material color change as shown here experimentally and numerically for random Au NP assemblies deposited onto elastomer films. © 2015, Higher Education Press and Springer-Verlag Berlin Heidelberg.},\npublisher={Higher Education Press},\nissn={2095025X},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n\n\n
\n This article exposes the beginnings of a new field which could be named as “plasmomechanics”. Plasmomechanics comes from the convergence between mechanics and plasmonics. Here we discuss a relatively recent topic whose technological aim is the development of plasmonic strain sensors. The idea is based on the ability to deduce Au nanoparticles (NPs) distance distributions from polarized optical extinction spectroscopy which could thus give access to material strains. Variations of interparticle distances distributions can indeed lead to variations of plasmonic coupling and thus to material color change as shown here experimentally and numerically for random Au NP assemblies deposited onto elastomer films. © 2015, Higher Education Press and Springer-Verlag Berlin Heidelberg.\n
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\n \n\n \n \n \n \n \n \n Hydrodynamic Trapping of Swimming Bacteria by Convex Walls.\n \n \n \n \n\n\n \n Sipos, O.; Nagy, K.; Di Leonardo, R.; and Galajda, P.\n\n\n \n\n\n\n Physical Review Letters, 114(25). 2015.\n cited By 58\n\n\n\n
\n\n\n\n \n \n \"HydrodynamicPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Sipos2015,\nauthor={Sipos, O. and Nagy, K. and Di Leonardo, R. and Galajda, P.},\ntitle={Hydrodynamic Trapping of Swimming Bacteria by Convex Walls},\njournal={Physical Review Letters},\nyear={2015},\nvolume={114},\nnumber={25},\ndoi={10.1103/PhysRevLett.114.258104},\nart_number={258104},\nnote={cited By 58},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84936972397&doi=10.1103%2fPhysRevLett.114.258104&partnerID=40&md5=e1f2db2760aeae355f3f806d9dc7050d},\nabstract={Swimming bacteria display a remarkable tendency to move along flat surfaces for prolonged times. This behavior may have a biological importance but can also be exploited by using microfabricated structures to manipulate bacteria. The main physical mechanism behind the surface entrapment of swimming bacteria is, however, still an open question. By studying the swimming motion of Escherichia coli cells near microfabricated pillars of variable size, we show that cell entrapment is also present for convex walls of sufficiently low curvature. Entrapment is, however, markedly reduced below a characteristic radius. Using a simple hydrodynamic model, we predict that trapped cells swim at a finite angle with the wall and a precise relation exists between the swimming angle at a flat wall and the critical radius of curvature for entrapment. Both predictions are quantitatively verified by experimental data. Our results demonstrate that the main mechanism for wall entrapment is hydrodynamic in nature and show the possibility of inhibiting cell adhesion, and thus biofilm formation, using convex features of appropriate curvature. © 2015 American Physical Society.},\npublisher={American Physical Society},\nissn={00319007},\ncoden={PRLTA},\npubmed_id={26197146},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Swimming bacteria display a remarkable tendency to move along flat surfaces for prolonged times. This behavior may have a biological importance but can also be exploited by using microfabricated structures to manipulate bacteria. The main physical mechanism behind the surface entrapment of swimming bacteria is, however, still an open question. By studying the swimming motion of Escherichia coli cells near microfabricated pillars of variable size, we show that cell entrapment is also present for convex walls of sufficiently low curvature. Entrapment is, however, markedly reduced below a characteristic radius. Using a simple hydrodynamic model, we predict that trapped cells swim at a finite angle with the wall and a precise relation exists between the swimming angle at a flat wall and the critical radius of curvature for entrapment. Both predictions are quantitatively verified by experimental data. Our results demonstrate that the main mechanism for wall entrapment is hydrodynamic in nature and show the possibility of inhibiting cell adhesion, and thus biofilm formation, using convex features of appropriate curvature. © 2015 American Physical Society.\n
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\n \n\n \n \n \n \n \n \n X-ray photoelectron spectroscopy of reduced graphene oxide prepared by a novel green method.\n \n \n \n \n\n\n \n Rella, S.; Giuri, A.; Corcione, C.; Acocella, M.; Colella, S.; Guerra, G.; Listorti, A.; Rizzo, A.; and Malitesta, C.\n\n\n \n\n\n\n Vacuum, 119: 159-162. 2015.\n cited By 28\n\n\n\n
\n\n\n\n \n \n \"X-rayPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Rella2015159,\nauthor={Rella, S. and Giuri, A. and Corcione, C.E. and Acocella, M.R. and Colella, S. and Guerra, G. and Listorti, A. and Rizzo, A. and Malitesta, C.},\ntitle={X-ray photoelectron spectroscopy of reduced graphene oxide prepared by a novel green method},\njournal={Vacuum},\nyear={2015},\nvolume={119},\npages={159-162},\ndoi={10.1016/j.vacuum.2015.05.008},\nart_number={6670},\nnote={cited By 28},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84930649407&doi=10.1016%2fj.vacuum.2015.05.008&partnerID=40&md5=b2b7d4e3b10d11ed814671752256a05d},\nabstract={Abstract This work is focused on the surface characterization of reduced graphene oxide (rGO) obtained through reduction of graphite oxide. The reduction was performed using a green method (based on UV irradiation under N<inf>2</inf>) with low environmental impact, free of additional functionalization reagents, simple and low-cost. X-ray photoelectron spectroscopy (XPS) was applied for chemical characterization of surface C species showing a significant reduction of oxygen-containing functional groups from the surface of rGO. © 2015 Elsevier Ltd.},\npublisher={Elsevier Ltd},\nissn={0042207X},\ncoden={VACUA},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Abstract This work is focused on the surface characterization of reduced graphene oxide (rGO) obtained through reduction of graphite oxide. The reduction was performed using a green method (based on UV irradiation under N2) with low environmental impact, free of additional functionalization reagents, simple and low-cost. X-ray photoelectron spectroscopy (XPS) was applied for chemical characterization of surface C species showing a significant reduction of oxygen-containing functional groups from the surface of rGO. © 2015 Elsevier Ltd.\n
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\n \n\n \n \n \n \n \n \n Polar features in the flagellar propulsion of E. coli bacteria.\n \n \n \n \n\n\n \n Bianchi, S.; Saglimbeni, F.; Lepore, A.; and Di Leonardo, R.\n\n\n \n\n\n\n Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, 91(6). 2015.\n cited By 14\n\n\n\n
\n\n\n\n \n \n \"PolarPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Bianchi2015,\nauthor={Bianchi, S. and Saglimbeni, F. and Lepore, A. and Di Leonardo, R.},\ntitle={Polar features in the flagellar propulsion of E. coli bacteria},\njournal={Physical Review E - Statistical, Nonlinear, and Soft Matter Physics},\nyear={2015},\nvolume={91},\nnumber={6},\ndoi={10.1103/PhysRevE.91.062705},\nart_number={062705},\nnote={cited By 14},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84930959075&doi=10.1103%2fPhysRevE.91.062705&partnerID=40&md5=958aae978e62234c8c7076e0e7099dd3},\nabstract={E. coli bacteria swim following a run and tumble pattern. In the run state all flagella join in a single helical bundle that propels the cell body along approximately straight paths. When one or more flagellar motors reverse direction the bundle unwinds and the cell randomizes its orientation. This basic picture represents an idealization of a much more complex dynamical problem. Although it has been shown that bundle formation can occur at either pole of the cell, it is still unclear whether these two run states correspond to asymmetric propulsion features. Using holographic microscopy we record the 3D motions of individual bacteria swimming in optical traps. We find that most cells possess two run states characterized by different propulsion forces, total torque, and bundle conformations. We analyze the statistical properties of bundle reversal and compare the hydrodynamic features of forward and backward running states. Our method is naturally multi-particle and opens up the way towards controlled hydrodynamic studies of interacting swimming cells. © 2015 American Physical Society.},\npublisher={American Physical Society},\nissn={15393755},\ncoden={PLEEE},\npubmed_id={26172734},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n E. coli bacteria swim following a run and tumble pattern. In the run state all flagella join in a single helical bundle that propels the cell body along approximately straight paths. When one or more flagellar motors reverse direction the bundle unwinds and the cell randomizes its orientation. This basic picture represents an idealization of a much more complex dynamical problem. Although it has been shown that bundle formation can occur at either pole of the cell, it is still unclear whether these two run states correspond to asymmetric propulsion features. Using holographic microscopy we record the 3D motions of individual bacteria swimming in optical traps. We find that most cells possess two run states characterized by different propulsion forces, total torque, and bundle conformations. We analyze the statistical properties of bundle reversal and compare the hydrodynamic features of forward and backward running states. Our method is naturally multi-particle and opens up the way towards controlled hydrodynamic studies of interacting swimming cells. © 2015 American Physical Society.\n
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\n \n\n \n \n \n \n \n \n Plasmonics meets biology through optics.\n \n \n \n \n\n\n \n De Sio, L.; Caracciolo, G.; Annesi, F.; Placido, T.; Pozzi, D.; Comparelli, R.; Pane, A.; Curri, M.; Agostiano, A.; and Bartolino, R.\n\n\n \n\n\n\n Nanomaterials, 5(2): 1022-1033. 2015.\n cited By 1\n\n\n\n
\n\n\n\n \n \n \"PlasmonicsPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{DeSio20151022,\nauthor={De Sio, L. and Caracciolo, G. and Annesi, F. and Placido, T. and Pozzi, D. and Comparelli, R. and Pane, A. and Curri, M.L. and Agostiano, A. and Bartolino, R.},\ntitle={Plasmonics meets biology through optics},\njournal={Nanomaterials},\nyear={2015},\nvolume={5},\nnumber={2},\npages={1022-1033},\ndoi={10.3390/nano5021022},\nnote={cited By 1},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84937604797&doi=10.3390%2fnano5021022&partnerID=40&md5=bc28fc315546dfe3afba3eba73e09111},\nabstract={Plasmonic metallic nanoparticles (NPs) represent a relevant class of nanomaterials, which is able to achieve light localization down to nanoscale by exploiting a phenomenon called Localized Plasmon Resonance. In the last few years, NPs have been proposed to trigger DNA release or enhance ablation of diseased tissues, while minimizing damage to healthy tissues. In view of the therapeutic relevance of such plasmonic NPs, a detailed characterization of the electrostatic interaction between positively charged gold nanorods (GNRs) and a negatively charged whole-genome DNA solution is reported. The preparation of the hybrid biosystem has been investigated as a function of DNA concentration by means of ζ-potential, hydrodynamic diameter and gel electrophoresis analysis. The results have pointed out the specific conditions to achieve the most promising GNRs/DNA complex and its photo-thermal properties have been investigated. The overall study allows to envisage the possibility to ingeniously combine plasmonic and biological materials and, thus, enable design and development of an original non invasive all-optical methodology for monitoring photo-induced temperature variation with high sensitivity. © 2015 by the authors.},\npublisher={MDPI AG},\nissn={20794991},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Plasmonic metallic nanoparticles (NPs) represent a relevant class of nanomaterials, which is able to achieve light localization down to nanoscale by exploiting a phenomenon called Localized Plasmon Resonance. In the last few years, NPs have been proposed to trigger DNA release or enhance ablation of diseased tissues, while minimizing damage to healthy tissues. In view of the therapeutic relevance of such plasmonic NPs, a detailed characterization of the electrostatic interaction between positively charged gold nanorods (GNRs) and a negatively charged whole-genome DNA solution is reported. The preparation of the hybrid biosystem has been investigated as a function of DNA concentration by means of ζ-potential, hydrodynamic diameter and gel electrophoresis analysis. The results have pointed out the specific conditions to achieve the most promising GNRs/DNA complex and its photo-thermal properties have been investigated. The overall study allows to envisage the possibility to ingeniously combine plasmonic and biological materials and, thus, enable design and development of an original non invasive all-optical methodology for monitoring photo-induced temperature variation with high sensitivity. © 2015 by the authors.\n
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\n \n\n \n \n \n \n \n \n Ferric ions inhibit the amyloid fibrillation of β-lactoglobulin at high temperature.\n \n \n \n \n\n\n \n Guzzi, R.; Rizzuti, B.; Labate, C.; Zappone, B.; and De Santo, M.\n\n\n \n\n\n\n Biomacromolecules, 16(6): 1794-1801. 2015.\n cited By 12\n\n\n\n
\n\n\n\n \n \n \"FerricPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Guzzi20151794,\nauthor={Guzzi, R. and Rizzuti, B. and Labate, C. and Zappone, B. and De Santo, M.P.},\ntitle={Ferric ions inhibit the amyloid fibrillation of β-lactoglobulin at high temperature},\njournal={Biomacromolecules},\nyear={2015},\nvolume={16},\nnumber={6},\npages={1794-1801},\ndoi={10.1021/acs.biomac.5b00371},\nnote={cited By 12},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84930959825&doi=10.1021%2facs.biomac.5b00371&partnerID=40&md5=067891566c3096c24ea16b26d28a683a},\nabstract={The energetics of amyloid fibrillar aggregation of β-lactoglobulin (βLG) following incubation at high temperature and acid pH was studied by differential scanning calorimetry in the presence of Cu2+ or Fe3+ cations, and without any metal. Cu2+ and metal-free protein solutions showed a distinct exothermic response that disappeared almost completely when the Fe3+ molar concentration was ten times greater than the βLG concentration. Thioflavin T fluorescence studies in solution and atomic force microscopy analysis of the deposit left on flat mica substrates by heat-incubated βLG solutions correlated the absence of exothermic response of Fe3+-βLG solutions with a lack of fibril production. In contrast, abundant fibril deposits were observed for Cu2+-βLG solutions, with a rich polymorphism of multistrand fibrillar structures. Electron paramagnetic resonance revealed that Fe3+ permanently binds to βLG in the aggregate state whereas Cu2+ plays a catalytic role without binding to the protein. We propose that Fe3+ inhibits fibril production after binding to a key region of the protein sequence, possibly interfering with the nucleation step of the fibrillation process and opening a nonfibrillar aggregation pathway. These findings suggest that transition metal ions can be utilized to effectively modulate protein self-assembly into a variety of structures with distinct morphologies at the nanoscale level. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={15257797},\ncoden={BOMAF},\npubmed_id={25989053},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The energetics of amyloid fibrillar aggregation of β-lactoglobulin (βLG) following incubation at high temperature and acid pH was studied by differential scanning calorimetry in the presence of Cu2+ or Fe3+ cations, and without any metal. Cu2+ and metal-free protein solutions showed a distinct exothermic response that disappeared almost completely when the Fe3+ molar concentration was ten times greater than the βLG concentration. Thioflavin T fluorescence studies in solution and atomic force microscopy analysis of the deposit left on flat mica substrates by heat-incubated βLG solutions correlated the absence of exothermic response of Fe3+-βLG solutions with a lack of fibril production. In contrast, abundant fibril deposits were observed for Cu2+-βLG solutions, with a rich polymorphism of multistrand fibrillar structures. Electron paramagnetic resonance revealed that Fe3+ permanently binds to βLG in the aggregate state whereas Cu2+ plays a catalytic role without binding to the protein. We propose that Fe3+ inhibits fibril production after binding to a key region of the protein sequence, possibly interfering with the nucleation step of the fibrillation process and opening a nonfibrillar aggregation pathway. These findings suggest that transition metal ions can be utilized to effectively modulate protein self-assembly into a variety of structures with distinct morphologies at the nanoscale level. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Inference for interacting linear waves in ordered and random media.\n \n \n \n \n\n\n \n Tyagi, P.; Pagnani, A.; Antenucci, F.; Ibánez Berganza, M.; and Leuzzi, L.\n\n\n \n\n\n\n Journal of Statistical Mechanics: Theory and Experiment, 2015(5). 2015.\n cited By 3\n\n\n\n
\n\n\n\n \n \n \"InferencePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Tyagi2015,\nauthor={Tyagi, P. and Pagnani, A. and Antenucci, F. and Ibánez Berganza, M. and Leuzzi, L.},\ntitle={Inference for interacting linear waves in ordered and random media},\njournal={Journal of Statistical Mechanics: Theory and Experiment},\nyear={2015},\nvolume={2015},\nnumber={5},\ndoi={10.1088/1742-5468/2015/05/P05031},\nart_number={P05031},\nnote={cited By 3},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84934881063&doi=10.1088%2f1742-5468%2f2015%2f05%2fP05031&partnerID=40&md5=c2275be92fdd159e6d028b407059982a},\nabstract={A statistical inference method is developed and tested for pairwise interacting systems whose degrees of freedom are continuous angular variables, such as planar spins in magnetic systems or wave phases in optics and acoustics. We investigate systems with both deterministic and quenched disordered couplings on two extreme topologies: complete and sparse graphs. To match further applications in optics also complex couplings and external fields are considered and general inference formulas are derived for real and imaginary parts of Hermitian coupling matrices from real and imaginary parts of complex correlation functions. The whole procedure is, eventually, tested on numerically generated correlation functions and local magnetizations by means of Monte Carlo simulations. © 2015 IOP Publishing Ltd and SISSA Medialab srl.},\npublisher={Institute of Physics Publishing},\nissn={17425468},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n A statistical inference method is developed and tested for pairwise interacting systems whose degrees of freedom are continuous angular variables, such as planar spins in magnetic systems or wave phases in optics and acoustics. We investigate systems with both deterministic and quenched disordered couplings on two extreme topologies: complete and sparse graphs. To match further applications in optics also complex couplings and external fields are considered and general inference formulas are derived for real and imaginary parts of Hermitian coupling matrices from real and imaginary parts of complex correlation functions. The whole procedure is, eventually, tested on numerically generated correlation functions and local magnetizations by means of Monte Carlo simulations. © 2015 IOP Publishing Ltd and SISSA Medialab srl.\n
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\n \n\n \n \n \n \n \n \n Complex spherical 2+4 spin glass: A model for nonlinear optics in random media.\n \n \n \n \n\n\n \n Antenucci, F.; Crisanti, A.; and Leuzzi, L.\n\n\n \n\n\n\n Physical Review A - Atomic, Molecular, and Optical Physics, 91(5). 2015.\n cited By 19\n\n\n\n
\n\n\n\n \n \n \"ComplexPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Antenucci2015,\nauthor={Antenucci, F. and Crisanti, A. and Leuzzi, L.},\ntitle={Complex spherical 2+4 spin glass: A model for nonlinear optics in random media},\njournal={Physical Review A - Atomic, Molecular, and Optical Physics},\nyear={2015},\nvolume={91},\nnumber={5},\ndoi={10.1103/PhysRevA.91.053816},\nart_number={053816},\nnote={cited By 19},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84929339958&doi=10.1103%2fPhysRevA.91.053816&partnerID=40&md5=1591842c2d1aa4a17132dd8c0371b6bc},\nabstract={A disordered mean-field model for multimode laser in open and irregular cavities is proposed and discussed within the replica analysis. The model includes the dynamics of the mode intensity and accounts also for the possible presence of a linear coupling between the modes, due, e.g., to the leakages from an open cavity. The complete phase diagram, in terms of disorder strength, source pumping, and nonlinearity, consists of four different optical regimes: incoherent fluorescence, standard mode locking, random lasing, and the spontaneous phase locking. A replica symmetry-breaking phase transition is predicted at the random lasing threshold. For a high enough strength of nonlinearity, a whole region with nonvanishing complexity anticipates the transition, and the light modes in the disordered medium display typical discontinuous glassy behavior, i.e., the photonic glass has a multitude of metastable states that correspond to different mode-locking processes in random lasers. The lasing regime is still present for very open cavities, although the transition becomes continuous at the lasing threshold. © 2015 American Physical Society.},\npublisher={American Physical Society},\nissn={10502947},\ncoden={PLRAA},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n A disordered mean-field model for multimode laser in open and irregular cavities is proposed and discussed within the replica analysis. The model includes the dynamics of the mode intensity and accounts also for the possible presence of a linear coupling between the modes, due, e.g., to the leakages from an open cavity. The complete phase diagram, in terms of disorder strength, source pumping, and nonlinearity, consists of four different optical regimes: incoherent fluorescence, standard mode locking, random lasing, and the spontaneous phase locking. A replica symmetry-breaking phase transition is predicted at the random lasing threshold. For a high enough strength of nonlinearity, a whole region with nonvanishing complexity anticipates the transition, and the light modes in the disordered medium display typical discontinuous glassy behavior, i.e., the photonic glass has a multitude of metastable states that correspond to different mode-locking processes in random lasers. The lasing regime is still present for very open cavities, although the transition becomes continuous at the lasing threshold. © 2015 American Physical Society.\n
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\n \n\n \n \n \n \n \n \n Effect of mesostructured layer upon crystalline properties and device performance on perovskite solar cells.\n \n \n \n \n\n\n \n Listorti, A.; Juarez-Perez, E.; Frontera, C.; Roiati, V.; Garcia-Andrade, L.; Colella, S.; Rizzo, A.; Ortiz, P.; and Mora-Sero, I.\n\n\n \n\n\n\n Journal of Physical Chemistry Letters, 6(9): 1628-1637. 2015.\n cited By 67\n\n\n\n
\n\n\n\n \n \n \"EffectPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Listorti20151628,\nauthor={Listorti, A. and Juarez-Perez, E.J. and Frontera, C. and Roiati, V. and Garcia-Andrade, L. and Colella, S. and Rizzo, A. and Ortiz, P. and Mora-Sero, I.},\ntitle={Effect of mesostructured layer upon crystalline properties and device performance on perovskite solar cells},\njournal={Journal of Physical Chemistry Letters},\nyear={2015},\nvolume={6},\nnumber={9},\npages={1628-1637},\ndoi={10.1021/acs.jpclett.5b00483},\nnote={cited By 67},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84928987819&doi=10.1021%2facs.jpclett.5b00483&partnerID=40&md5=69a85292c27ca277d41feaba6a14420e},\nabstract={One of the most fascinating characteristics of perovskite solar cells (PSCs) is the retrieved obtainment of outstanding photovoltaic (PV) performances withstanding important device configuration variations. Here we have analyzed CHNH3PbI 3-xClx in planar or in mesostructured (MS) configurations, employing both titania and alumina scaffolds, fully infiltrated with perovskite material or presenting an overstanding layer. The use of the MS scaffold induces to the perovskite different structural properties, in terms of grain size, preferential orientation, and unit cell volume, in comparison to the ones of the material grown with no constraints, as we have found out by X-ray diffraction analyses. We have studied the effect of the PSC configuration on photoinduced absorption and time-resolved photoluminescence, complementary techniques that allow studying charge photogeneration and recombination. We have estimated electron diffusion length in the considered configurations observing a decrease when the material is confined in the MS scaffold with respect to a planar architecture. However, the presence of perovskite overlayer allows an overall recovering of long diffusion lengths explaining the record PV performances obtained with a device configuration bearing both the mesostructure and a perovskite overlayer. Our results suggest that performance in devices with perovskite overlayer is mainly ruled by the overlayer, whereas the mesoporous layer influences the contact properties. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={19487185},\npubmed_id={26263326},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n One of the most fascinating characteristics of perovskite solar cells (PSCs) is the retrieved obtainment of outstanding photovoltaic (PV) performances withstanding important device configuration variations. Here we have analyzed CHNH3PbI 3-xClx in planar or in mesostructured (MS) configurations, employing both titania and alumina scaffolds, fully infiltrated with perovskite material or presenting an overstanding layer. The use of the MS scaffold induces to the perovskite different structural properties, in terms of grain size, preferential orientation, and unit cell volume, in comparison to the ones of the material grown with no constraints, as we have found out by X-ray diffraction analyses. We have studied the effect of the PSC configuration on photoinduced absorption and time-resolved photoluminescence, complementary techniques that allow studying charge photogeneration and recombination. We have estimated electron diffusion length in the considered configurations observing a decrease when the material is confined in the MS scaffold with respect to a planar architecture. However, the presence of perovskite overlayer allows an overall recovering of long diffusion lengths explaining the record PV performances obtained with a device configuration bearing both the mesostructure and a perovskite overlayer. Our results suggest that performance in devices with perovskite overlayer is mainly ruled by the overlayer, whereas the mesoporous layer influences the contact properties. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Molecular structure and equilibrium forces of bovine submaxillary mucin adsorbed at a solid-liquid interface.\n \n \n \n \n\n\n \n Zappone, B.; Patil, N.; Madsen, J.; Pakkanen, K.; and Lee, S.\n\n\n \n\n\n\n Langmuir, 31(15): 4524-4533. 2015.\n cited By 15\n\n\n\n
\n\n\n\n \n \n \"MolecularPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Zappone20154524,\nauthor={Zappone, B. and Patil, N.J. and Madsen, J.B. and Pakkanen, K.I. and Lee, S.},\ntitle={Molecular structure and equilibrium forces of bovine submaxillary mucin adsorbed at a solid-liquid interface},\njournal={Langmuir},\nyear={2015},\nvolume={31},\nnumber={15},\npages={4524-4533},\ndoi={10.1021/acs.langmuir.5b00548},\nnote={cited By 15},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84928485415&doi=10.1021%2facs.langmuir.5b00548&partnerID=40&md5=02221016ce24537d5b51e6b999d3ba3b},\nabstract={By combining dynamic light scattering, circular dichroism spectroscopy, atomic force microscopy, and surface force apparatus, the conformation of bovine submaxillary mucin in dilute solution and nanomechanical properties of mucin layers adsorbed on mica have been investigated. The samples were prepared by additional chromatographic purification of commercially available products. The mucin molecule was found to have a z-average hydrodynamic diameter of ca. 35 nm in phosphate buffered solution, without any particular secondary or tertiary structure. The contour length of the mucin is larger than, yet of the same order of magnitude as the diameter, indicating that the molecule can be modeled as a relatively rigid polymeric chain due to the large persistence length of the central glycosylated domain. Mucin molecules adsorbed abundantly onto mica from saline buffer, generating polymer-like, long-ranged, repulsive, and nonhysteretic forces upon compression of the adsorbed layers. Detailed analysis of such forces suggests that adsorbed mucins had an elongated conformation favored by the stiffness of the central domain. Acidification of aqueous media was chosen as means to reduce mucin-mucin and mucin-substrate electrostatic interactions. The hydrodynamic diameter in solution did not significantly change when the pH was lowered, showing that the large persistence length of the mucin molecule is due to steric hindrance between sugar chains, rather than electrostatic interactions. Remarkably, the force generated by an adsorbed layer with a fixed surface coverage also remained unaltered upon acidification. This observation can be linked to the surface-protective, pH-resistant role of bovine submaxillary mucin in the variable environmental conditions of the oral cavity. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={07437463},\ncoden={LANGD},\npubmed_id={25806669},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n By combining dynamic light scattering, circular dichroism spectroscopy, atomic force microscopy, and surface force apparatus, the conformation of bovine submaxillary mucin in dilute solution and nanomechanical properties of mucin layers adsorbed on mica have been investigated. The samples were prepared by additional chromatographic purification of commercially available products. The mucin molecule was found to have a z-average hydrodynamic diameter of ca. 35 nm in phosphate buffered solution, without any particular secondary or tertiary structure. The contour length of the mucin is larger than, yet of the same order of magnitude as the diameter, indicating that the molecule can be modeled as a relatively rigid polymeric chain due to the large persistence length of the central glycosylated domain. Mucin molecules adsorbed abundantly onto mica from saline buffer, generating polymer-like, long-ranged, repulsive, and nonhysteretic forces upon compression of the adsorbed layers. Detailed analysis of such forces suggests that adsorbed mucins had an elongated conformation favored by the stiffness of the central domain. Acidification of aqueous media was chosen as means to reduce mucin-mucin and mucin-substrate electrostatic interactions. The hydrodynamic diameter in solution did not significantly change when the pH was lowered, showing that the large persistence length of the mucin molecule is due to steric hindrance between sugar chains, rather than electrostatic interactions. Remarkably, the force generated by an adsorbed layer with a fixed surface coverage also remained unaltered upon acidification. This observation can be linked to the surface-protective, pH-resistant role of bovine submaxillary mucin in the variable environmental conditions of the oral cavity. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n Statistical physical theory of mode-locking laser generation with a frequency comb.\n \n \n \n \n\n\n \n Antenucci, F.; Berganza, M.; and Leuzzi, L.\n\n\n \n\n\n\n Physical Review A - Atomic, Molecular, and Optical Physics, 91(4). 2015.\n cited By 11\n\n\n\n
\n\n\n\n \n \n \"StatisticalPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Antenucci2015,\nauthor={Antenucci, F. and Berganza, M.I. and Leuzzi, L.},\ntitle={Statistical physical theory of mode-locking laser generation with a frequency comb},\njournal={Physical Review A - Atomic, Molecular, and Optical Physics},\nyear={2015},\nvolume={91},\nnumber={4},\ndoi={10.1103/PhysRevA.91.043811},\nart_number={043811},\nnote={cited By 11},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84929359941&doi=10.1103%2fPhysRevA.91.043811&partnerID=40&md5=80af2571fbebea6390deac1cbb2b37e1},\nabstract={A study of the mode-locking lasing pulse formation in closed cavities is presented within a statistical-mechanical framework where the onset of laser coincides with a thermodynamic phase transition driven by the optical power pumped into the system. Electromagnetic modes are represented by classical degrees of freedom of a Hamiltonian model at equilibrium in an effective ensemble corresponding to the stationary laser regime. By means of optimized Monte Carlo numerical simulations, the system properties are analyzed while varying mode interaction dilution, gain profile, and number of modes. Properties of the resulting mode-locking laser phase are presented that were not observed in previous approaches based on mean-field approximations. For strong dilution of the nonlinear interaction network, power condensation occurs as the total optical intensity is taken by a few electromagnetic modes, whose number does not depend on the size of the system. For all reported cases, laser thresholds, intensity spectra, phase waves, and ultrafast electromagnetic pulses are computed. © 2015 American Physical Society.},\npublisher={American Physical Society},\nissn={10502947},\ncoden={PLRAA},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n A study of the mode-locking lasing pulse formation in closed cavities is presented within a statistical-mechanical framework where the onset of laser coincides with a thermodynamic phase transition driven by the optical power pumped into the system. Electromagnetic modes are represented by classical degrees of freedom of a Hamiltonian model at equilibrium in an effective ensemble corresponding to the stationary laser regime. By means of optimized Monte Carlo numerical simulations, the system properties are analyzed while varying mode interaction dilution, gain profile, and number of modes. Properties of the resulting mode-locking laser phase are presented that were not observed in previous approaches based on mean-field approximations. For strong dilution of the nonlinear interaction network, power condensation occurs as the total optical intensity is taken by a few electromagnetic modes, whose number does not depend on the size of the system. For all reported cases, laser thresholds, intensity spectra, phase waves, and ultrafast electromagnetic pulses are computed. © 2015 American Physical Society.\n
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\n \n\n \n \n \n \n \n \n Multipoint observation of anisotropy and intermittency in solar-wind turbulence.\n \n \n \n \n\n\n \n Yordanova, E.; Perri, S.; Sorriso-Valvo, L.; and Carbone, V.\n\n\n \n\n\n\n EPL, 110(1). 2015.\n cited By 7\n\n\n\n
\n\n\n\n \n \n \"MultipointPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Yordanova2015,\nauthor={Yordanova, E. and Perri, S. and Sorriso-Valvo, L. and Carbone, V.},\ntitle={Multipoint observation of anisotropy and intermittency in solar-wind turbulence},\njournal={EPL},\nyear={2015},\nvolume={110},\nnumber={1},\ndoi={10.1209/0295-5075/110/19001},\nart_number={19001},\nnote={cited By 7},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84928686203&doi=10.1209%2f0295-5075%2f110%2f19001&partnerID=40&md5=2596a887152400ad66c767a637da99b1},\nabstract={Using high-resolution magnetic-field Cluster observations, we have investigated the magnetic-field anisotropy via the second- and fourth-order structure functions over a wide range of scales reaching below the subproton scale. The magnetic-field increments have been computed from single- and two-spacecraft measurements. The two-satellite technique allows us to study the increments as a function of an actual space lag. Both single- and two-point analyses show that the magnetic field is anisotropic even at small time/spatial scales. The single-spacecraft data also shows that the degree of anisotropy does not change with the scale at proton and subproton scales. It is also pointed out that the degree of magnetic-field anisotropy tends to be overestimated in the single-spacecraft data analysis. This is particularly evident at small scales and it depends on the angle between the spacecraft separation and the flow direction. From the fourth-order moment of the probability density function of the magnetic-field increments we have also investigated the presence of intermittency in the fluctuations. Even though to a different degree, intermittency was present over the entire range of scales, with an indication of scale invariance at subproton scales. © Copyright EPLA, 2015.},\npublisher={Institute of Physics Publishing},\nissn={02955075},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Using high-resolution magnetic-field Cluster observations, we have investigated the magnetic-field anisotropy via the second- and fourth-order structure functions over a wide range of scales reaching below the subproton scale. The magnetic-field increments have been computed from single- and two-spacecraft measurements. The two-satellite technique allows us to study the increments as a function of an actual space lag. Both single- and two-point analyses show that the magnetic field is anisotropic even at small time/spatial scales. The single-spacecraft data also shows that the degree of anisotropy does not change with the scale at proton and subproton scales. It is also pointed out that the degree of magnetic-field anisotropy tends to be overestimated in the single-spacecraft data analysis. This is particularly evident at small scales and it depends on the angle between the spacecraft separation and the flow direction. From the fourth-order moment of the probability density function of the magnetic-field increments we have also investigated the presence of intermittency in the fluctuations. Even though to a different degree, intermittency was present over the entire range of scales, with an indication of scale invariance at subproton scales. © Copyright EPLA, 2015.\n
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\n \n\n \n \n \n \n \n \n Optically transparent graphene-based Salisbury screen microwave absorber.\n \n \n \n \n\n\n \n Grande, M.; D'Orazio, A.; Bianco, G.; Bruno, G.; Vincenti, M.; De Ceglia, D.; and Scalora, M.\n\n\n \n\n\n\n 2015.\n cited By 5\n\n\n\n
\n\n\n\n \n \n \"OpticallyPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@CONFERENCE{Grande2015,\nauthor={Grande, M. and D'Orazio, A. and Bianco, G.V. and Bruno, G. and Vincenti, M.A. and De Ceglia, D. and Scalora, M.},\ntitle={Optically transparent graphene-based Salisbury screen microwave absorber},\njournal={Mediterranean Microwave Symposium},\nyear={2015},\nvolume={2015-January},\ndoi={10.1109/MMS.2015.7375386},\nart_number={7375386},\nnote={cited By 5},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84962716067&doi=10.1109%2fMMS.2015.7375386&partnerID=40&md5=e48f9a914f465b60af067f95b84a70e1},\nabstract={We propose an analytical model to study the absorption of a graphene sheet in the microwave range when its sheet resistance is varied. We demonstrate that the maximum achievable for a suspended structure is 50% and it is independent of the frequency in the range of interest. Finally, we propose a microwave absorber based on a Salisbury screen configuration consisting of two opportunely doped graphene sheets separated by a quarter-wavelength dielectric lossless spacer. In particular, we show how it is possible to achieve near-perfect absorption over a wide frequency bandwidth and how this graphene-based absorber is less sensitive to the variation of the graphene sheet resistance. The realization of the microwave absorber with few-layer graphene leads to a fully transparent device in the visible-near infrared range. © 2015 IEEE.},\npublisher={IEEE Computer Society},\nissn={21579822},\nisbn={9781467376020},\ndocument_type={Conference Paper},\nsource={Scopus},\n}\n\n
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\n We propose an analytical model to study the absorption of a graphene sheet in the microwave range when its sheet resistance is varied. We demonstrate that the maximum achievable for a suspended structure is 50% and it is independent of the frequency in the range of interest. Finally, we propose a microwave absorber based on a Salisbury screen configuration consisting of two opportunely doped graphene sheets separated by a quarter-wavelength dielectric lossless spacer. In particular, we show how it is possible to achieve near-perfect absorption over a wide frequency bandwidth and how this graphene-based absorber is less sensitive to the variation of the graphene sheet resistance. The realization of the microwave absorber with few-layer graphene leads to a fully transparent device in the visible-near infrared range. © 2015 IEEE.\n
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\n \n\n \n \n \n \n \n \n Matrix-assisted pulsed laser evaporation deposition of Pd nanoparticles: The role of solvent.\n \n \n \n \n\n\n \n Cesaria, M.; Caricato, A.; Taurino, A.; Resta, V.; Belviso, M.; Cozzoli, P.; and Martino, M.\n\n\n \n\n\n\n Science of Advanced Materials, 7(11): 2388-2400. 2015.\n cited By 0\n\n\n\n
\n\n\n\n \n \n \"Matrix-assistedPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Cesaria20152388,\nauthor={Cesaria, M. and Caricato, A.P. and Taurino, A. and Resta, V. and Belviso, M.R. and Cozzoli, P.D. and Martino, M.},\ntitle={Matrix-assisted pulsed laser evaporation deposition of Pd nanoparticles: The role of solvent},\njournal={Science of Advanced Materials},\nyear={2015},\nvolume={7},\nnumber={11},\npages={2388-2400},\ndoi={10.1166/sam.2015.2661},\nnote={cited By 0},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947323175&doi=10.1166%2fsam.2015.2661&partnerID=40&md5=c0dcedd735a27ce4b1784c6aa8b53b5a},\nabstract={The formation of Pd nanoparticles (NPs) by matrix-assisted pulsed laser evaporation (MAPLE) of a palladium acetate solution has been studied as a function of the carrier solvent, laser-pulse number, metal precursor concentration and post-deposition thermal heating. Structural and compositional analyses demonstrate that: (i) the conventional MAPLE process can induce self-reduction of the metal salt precursor, thereby leading to the formation of metallic Pd(0) NPs; (ii) the solvent critically determines the size, morphology, and size distribution of the resulting NPs; and (iii) the cumulative effects of laser-pulse number and solute concentration are less influential than the type of solvent used. For diethyl ether-derived samples, a bimodal distribution of NP sizes spanning from ~1 nm up to 20 nm was obtained. Conversely, by using acetone, a mono-modal distribution of sizes in the ~1 nm-6 nm range (mean diameter of 1.5±0.7 nm) and a more uniform and densepacked surface coverage (NP coverage was twice as dense as the one obtained with diethyl ether) resulted in. These observations point out that solvents with low dynamical viscosity coefficients and high volatility favor the formation of larger and more broadly dispersed NPs. A general theoretical picture has been proposed to describe the NP formation pathways on account of the solvent properties and the mechanisms underlying the MAPLE process enabled by the technique. © 2015 by American Scientific Publishers.},\npublisher={American Scientific Publishers},\nissn={19472935},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The formation of Pd nanoparticles (NPs) by matrix-assisted pulsed laser evaporation (MAPLE) of a palladium acetate solution has been studied as a function of the carrier solvent, laser-pulse number, metal precursor concentration and post-deposition thermal heating. Structural and compositional analyses demonstrate that: (i) the conventional MAPLE process can induce self-reduction of the metal salt precursor, thereby leading to the formation of metallic Pd(0) NPs; (ii) the solvent critically determines the size, morphology, and size distribution of the resulting NPs; and (iii) the cumulative effects of laser-pulse number and solute concentration are less influential than the type of solvent used. For diethyl ether-derived samples, a bimodal distribution of NP sizes spanning from  1 nm up to 20 nm was obtained. Conversely, by using acetone, a mono-modal distribution of sizes in the  1 nm-6 nm range (mean diameter of 1.5±0.7 nm) and a more uniform and densepacked surface coverage (NP coverage was twice as dense as the one obtained with diethyl ether) resulted in. These observations point out that solvents with low dynamical viscosity coefficients and high volatility favor the formation of larger and more broadly dispersed NPs. A general theoretical picture has been proposed to describe the NP formation pathways on account of the solvent properties and the mechanisms underlying the MAPLE process enabled by the technique. © 2015 by American Scientific Publishers.\n
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\n \n\n \n \n \n \n \n \n Tailoring chiro-optical effects by helical nanowire arrangement.\n \n \n \n \n\n\n \n Esposito, M.; Tasco, V.; Todisco, F.; Benedetti, A.; Tarantini, I.; Cuscunà, M.; Dominici, L.; De Giorgi, M.; and Passaseo, A.\n\n\n \n\n\n\n Nanoscale, 7(43): 18081-18088. 2015.\n cited By 29\n\n\n\n
\n\n\n\n \n \n \"TailoringPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Esposito201518081,\nauthor={Esposito, M. and Tasco, V. and Todisco, F. and Benedetti, A. and Tarantini, I. and Cuscunà, M. and Dominici, L. and De Giorgi, M. and Passaseo, A.},\ntitle={Tailoring chiro-optical effects by helical nanowire arrangement},\njournal={Nanoscale},\nyear={2015},\nvolume={7},\nnumber={43},\npages={18081-18088},\ndoi={10.1039/c5nr04674b},\nnote={cited By 29},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84946134472&doi=10.1039%2fc5nr04674b&partnerID=40&md5=0f470b0ba540855e7ad165aefab38daa},\nabstract={In this work, we experimentally investigate the chiro-optical properties of 3D metallic helical systems at optical frequencies. Both single and triple-nanowire geometries have been studied. In particular, we found that in single-helical nanostructures, the enhancement of chiro-optical effects achievable by geometrical design is limited, especially with respect to the operation wavelength and the circular polarization conversion purity. Conversely, in the triple-helical nanowire configuration, the dominant interaction is the coupling among the intertwined coaxial helices which is driven by a symmetric spatial arrangement. Consequently, a general improvement in the g-factor, extinction ratio and signal-to-noise-ratio is achieved in a broad spectral range. Moreover, while in single-helical nanowires a mixed linear and circular birefringence results in an optical activity strongly dependent on the sample orientation and wavelength, in the triple-helical nanowire configuration, the obtained purely circular birefringence leads to a large optical activity up to 8°, independent of the sample angle, and extending in a broad band of 500 nm in the visible range. These results demonstrate a strong correlation between the configurational internal interactions and the chiral feature designation, which can be effectively exploited for nanoscale chiral device engineering. © 2015 The Royal Society of Chemistry.},\npublisher={Royal Society of Chemistry},\nissn={20403364},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n In this work, we experimentally investigate the chiro-optical properties of 3D metallic helical systems at optical frequencies. Both single and triple-nanowire geometries have been studied. In particular, we found that in single-helical nanostructures, the enhancement of chiro-optical effects achievable by geometrical design is limited, especially with respect to the operation wavelength and the circular polarization conversion purity. Conversely, in the triple-helical nanowire configuration, the dominant interaction is the coupling among the intertwined coaxial helices which is driven by a symmetric spatial arrangement. Consequently, a general improvement in the g-factor, extinction ratio and signal-to-noise-ratio is achieved in a broad spectral range. Moreover, while in single-helical nanowires a mixed linear and circular birefringence results in an optical activity strongly dependent on the sample orientation and wavelength, in the triple-helical nanowire configuration, the obtained purely circular birefringence leads to a large optical activity up to 8°, independent of the sample angle, and extending in a broad band of 500 nm in the visible range. These results demonstrate a strong correlation between the configurational internal interactions and the chiral feature designation, which can be effectively exploited for nanoscale chiral device engineering. © 2015 The Royal Society of Chemistry.\n
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\n \n\n \n \n \n \n \n \n Insights into the effects of metal nanostructuring and oxidation on the work function and charge transfer of metal/graphene hybrids.\n \n \n \n \n\n\n \n Giangregorio, M.; Jiao, W.; Bianco, G.; Capezzuto, P.; Brown, A.; Bruno, G.; and Losurdo, M.\n\n\n \n\n\n\n Nanoscale, 7(30): 12868-12877. 2015.\n cited By 28\n\n\n\n
\n\n\n\n \n \n \"InsightsPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Giangregorio201512868,\nauthor={Giangregorio, M.M. and Jiao, W. and Bianco, G.V. and Capezzuto, P. and Brown, A.S. and Bruno, G. and Losurdo, M.},\ntitle={Insights into the effects of metal nanostructuring and oxidation on the work function and charge transfer of metal/graphene hybrids},\njournal={Nanoscale},\nyear={2015},\nvolume={7},\nnumber={30},\npages={12868-12877},\ndoi={10.1039/c5nr02610e},\nnote={cited By 28},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84937878954&doi=10.1039%2fc5nr02610e&partnerID=40&md5=d1b59c4b178e88e778b3bc9f2f031576},\nabstract={Graphene/metal heterojunctions are ubiquitous in graphene-based devices and, therefore, have attracted increasing interest of researchers. Indeed, the literature on the field reports apparently contradictory results about the effect of a metal on graphene doping. Here, we elucidate the effect of metal nanostructuring and oxidation on the metal work function (WF) and, consequently, on the charge transfer and doping of graphene/metal hybrids. We show that nanostructuring and oxidation of metals provide a valid support to frame WF and doping variation in metal/graphene hybrids. Chemical vapour-deposited monolayer graphene has been transferred onto a variety of metal surfaces, including d-metals, such as Ag, Au, and Cu, and sp-metals, such as Al and Ga, configured as thin films or nanoparticle (NP) ensembles of various average sizes. The metal-induced charge transfer and the doping of graphene have been investigated using Kelvin probe force microscopy (KPFM), and corroborated by Raman spectroscopy and plasmonic ellipsometric spectroscopy. We show that when the appropriate WF of the metal is considered, without any assumption, taking into account WF variations by nanostructure and/or oxidation, a linear relationship between the metal WF and the doping of graphene is found. Specifically, for all metals, nanostructuring lowers the metal WF. In addition, using gold as an example, a critical metal nanoparticle size is found at which the direction of charge transfer, and consequently graphene doping, is inverted. © The Royal Society of Chemistry.},\npublisher={Royal Society of Chemistry},\nissn={20403364},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Graphene/metal heterojunctions are ubiquitous in graphene-based devices and, therefore, have attracted increasing interest of researchers. Indeed, the literature on the field reports apparently contradictory results about the effect of a metal on graphene doping. Here, we elucidate the effect of metal nanostructuring and oxidation on the metal work function (WF) and, consequently, on the charge transfer and doping of graphene/metal hybrids. We show that nanostructuring and oxidation of metals provide a valid support to frame WF and doping variation in metal/graphene hybrids. Chemical vapour-deposited monolayer graphene has been transferred onto a variety of metal surfaces, including d-metals, such as Ag, Au, and Cu, and sp-metals, such as Al and Ga, configured as thin films or nanoparticle (NP) ensembles of various average sizes. The metal-induced charge transfer and the doping of graphene have been investigated using Kelvin probe force microscopy (KPFM), and corroborated by Raman spectroscopy and plasmonic ellipsometric spectroscopy. We show that when the appropriate WF of the metal is considered, without any assumption, taking into account WF variations by nanostructure and/or oxidation, a linear relationship between the metal WF and the doping of graphene is found. Specifically, for all metals, nanostructuring lowers the metal WF. In addition, using gold as an example, a critical metal nanoparticle size is found at which the direction of charge transfer, and consequently graphene doping, is inverted. © The Royal Society of Chemistry.\n
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\n \n\n \n \n \n \n \n \n Ultrastrong light-matter coupling in electroluminescent organic microcavities.\n \n \n \n \n\n\n \n Gambino, S.; Genco, A.; Accorsi, G.; Di Stefano, O.; Savasta, S.; Patanè, S.; Gigli, G.; and Mazzeo, M.\n\n\n \n\n\n\n Applied Materials Today, 1(1): 33-36. 2015.\n cited By 13\n\n\n\n
\n\n\n\n \n \n \"UltrastrongPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Gambino201533,\nauthor={Gambino, S. and Genco, A. and Accorsi, G. and Di Stefano, O. and Savasta, S. and Patanè, S. and Gigli, G. and Mazzeo, M.},\ntitle={Ultrastrong light-matter coupling in electroluminescent organic microcavities},\njournal={Applied Materials Today},\nyear={2015},\nvolume={1},\nnumber={1},\npages={33-36},\ndoi={10.1016/j.apmt.2015.08.003},\nnote={cited By 13},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84976487054&doi=10.1016%2fj.apmt.2015.08.003&partnerID=40&md5=a656d8833e2a9998b72033f993509f28},\nabstract={In this work, we explore the effects of the ultrastrong coupling regime between light and molecular excitons on the electrical and optical properties of microcavity-OLEDs. We studied two different samples having a coupling value of 31% and 48%. The main effect of the ultrastrong interaction is on the electroluminescent emission linewidth which was only 28 meV, that is about 12-fold narrower than that of the corresponding photoluminescence of the uncoupled material and even half the linewidth of photonic (weak-coupled) microcavity working at the same wavelength. © 2015 Elsevier Ltd. All rights reserved.},\npublisher={Elsevier Ltd},\nissn={23529407},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n In this work, we explore the effects of the ultrastrong coupling regime between light and molecular excitons on the electrical and optical properties of microcavity-OLEDs. We studied two different samples having a coupling value of 31% and 48%. The main effect of the ultrastrong interaction is on the electroluminescent emission linewidth which was only 28 meV, that is about 12-fold narrower than that of the corresponding photoluminescence of the uncoupled material and even half the linewidth of photonic (weak-coupled) microcavity working at the same wavelength. © 2015 Elsevier Ltd. All rights reserved.\n
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\n \n\n \n \n \n \n \n \n Perovskite photovoltachromic cells for building integration.\n \n \n \n \n\n\n \n Cannavale, A.; Eperon, G.; Cossari, P.; Abate, A.; Snaith, H.; and Gigli, G.\n\n\n \n\n\n\n Energy and Environmental Science, 8(5): 1578-1584. 2015.\n cited By 79\n\n\n\n
\n\n\n\n \n \n \"PerovskitePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Cannavale20151578,\nauthor={Cannavale, A. and Eperon, G.E. and Cossari, P. and Abate, A. and Snaith, H.J. and Gigli, G.},\ntitle={Perovskite photovoltachromic cells for building integration},\njournal={Energy and Environmental Science},\nyear={2015},\nvolume={8},\nnumber={5},\npages={1578-1584},\ndoi={10.1039/c5ee00896d},\nnote={cited By 79},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84928963616&doi=10.1039%2fc5ee00896d&partnerID=40&md5=34e69a590086723bd7637d85d8bd85c1},\nabstract={Photovoltachromic devices combine photovoltaic and electrochromic behaviours to enable adjustable transparency glazing, where the photovoltaic component supplies the power to drive the coloration. Such stand-alone, self-powered devices are of commercial interest for integration into windows and surfaces of buildings and vehicles. Here, we report for the first time a perovskite-based photovoltachromic device with self-adaptive transparency. This multifunctional device is capable of producing electrical power by solar energy conversion as well as undergoing a chromic transition from neutral-color semi-transparent to dark blue-tinted when irradiated with solar light, without any additional external bias. The combination of semi-transparent perovskite photovoltaic and solid-state electrochromic cells enables fully solid-state photovoltachromic devices with 26% (or 16%) average visible transmittance and 3.7% (or 5.5%) maximum light power conversion efficiency. Upon activating the self-tinting, the average visible transmittance drops to 8.4% (or 5.5%). These results represent a significant step towards the commercialization of photovoltachromic building envelopes. © 2015 The Royal Society of Chemistry.},\npublisher={Royal Society of Chemistry},\nissn={17545692},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Photovoltachromic devices combine photovoltaic and electrochromic behaviours to enable adjustable transparency glazing, where the photovoltaic component supplies the power to drive the coloration. Such stand-alone, self-powered devices are of commercial interest for integration into windows and surfaces of buildings and vehicles. Here, we report for the first time a perovskite-based photovoltachromic device with self-adaptive transparency. This multifunctional device is capable of producing electrical power by solar energy conversion as well as undergoing a chromic transition from neutral-color semi-transparent to dark blue-tinted when irradiated with solar light, without any additional external bias. The combination of semi-transparent perovskite photovoltaic and solid-state electrochromic cells enables fully solid-state photovoltachromic devices with 26% (or 16%) average visible transmittance and 3.7% (or 5.5%) maximum light power conversion efficiency. Upon activating the self-tinting, the average visible transmittance drops to 8.4% (or 5.5%). These results represent a significant step towards the commercialization of photovoltachromic building envelopes. © 2015 The Royal Society of Chemistry.\n
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\n \n\n \n \n \n \n \n \n Multiscale morphology design of hybrid halide perovskites through a polymeric template.\n \n \n \n \n\n\n \n Masi, S.; Rizzo, A.; Aiello, F.; Balzano, F.; Uccello-Barretta, G.; Listorti, A.; Gigli, G.; and Colella, S.\n\n\n \n\n\n\n Nanoscale, 7(45): 18956-18963. 2015.\n cited By 50\n\n\n\n
\n\n\n\n \n \n \"MultiscalePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Masi201518956,\nauthor={Masi, S. and Rizzo, A. and Aiello, F. and Balzano, F. and Uccello-Barretta, G. and Listorti, A. and Gigli, G. and Colella, S.},\ntitle={Multiscale morphology design of hybrid halide perovskites through a polymeric template},\njournal={Nanoscale},\nyear={2015},\nvolume={7},\nnumber={45},\npages={18956-18963},\ndoi={10.1039/c5nr04715c},\nnote={cited By 50},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947290936&doi=10.1039%2fc5nr04715c&partnerID=40&md5=8e7118965bf9aabd8ca61fa0d6fc5e95},\nabstract={Hybrid halide perovskites have emerged as promising active constituents of next generation solution processable optoelectronic devices. During their assembling process, perovskite components undergo very complex dynamic equilibria starting in solution and progressing throughout film formation. Finding a methodology to control and affect these equilibria, responsible for the unique morphological diversity observed in perovskite films, constitutes a fundamental step towards a reproducible material processability. Here we propose the exploitation of polymer matrices as cooperative assembling components of novel perovskite CH3NH3PbI3 : polymer composites, in which the control of the chemical interactions in solution allows a predictable tuning of the final film morphology. We reveal that the nature of the interactions between perovskite precursors and polymer functional groups, probed by Nuclear Magnetic Resonance (NMR) spectroscopy and Dynamic Light Scattering (DLS) techniques, allows the control of aggregates in solution whose characteristics are strictly maintained in the solid film, and permits the formation of nanostructures that are inaccessible to conventional perovskite depositions. These results demonstrate how the fundamental chemistry of perovskite precursors in solution has a paramount influence on controlling and monitoring the final morphology of CH3NH3PbI3 (MAPbI3) thin films, foreseeing the possibility of designing perovskite : polymer composites targeting diverse optoelectronic applications. © 2015 The Royal Society of Chemistry.},\npublisher={Royal Society of Chemistry},\nissn={20403364},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
\n
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\n Hybrid halide perovskites have emerged as promising active constituents of next generation solution processable optoelectronic devices. During their assembling process, perovskite components undergo very complex dynamic equilibria starting in solution and progressing throughout film formation. Finding a methodology to control and affect these equilibria, responsible for the unique morphological diversity observed in perovskite films, constitutes a fundamental step towards a reproducible material processability. Here we propose the exploitation of polymer matrices as cooperative assembling components of novel perovskite CH3NH3PbI3 : polymer composites, in which the control of the chemical interactions in solution allows a predictable tuning of the final film morphology. We reveal that the nature of the interactions between perovskite precursors and polymer functional groups, probed by Nuclear Magnetic Resonance (NMR) spectroscopy and Dynamic Light Scattering (DLS) techniques, allows the control of aggregates in solution whose characteristics are strictly maintained in the solid film, and permits the formation of nanostructures that are inaccessible to conventional perovskite depositions. These results demonstrate how the fundamental chemistry of perovskite precursors in solution has a paramount influence on controlling and monitoring the final morphology of CH3NH3PbI3 (MAPbI3) thin films, foreseeing the possibility of designing perovskite : polymer composites targeting diverse optoelectronic applications. © 2015 The Royal Society of Chemistry.\n
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\n \n\n \n \n \n \n \n \n Nucleation and growth of nanoparticles in a plasma by laser ablation in liquid.\n \n \n \n \n\n\n \n Taccogna, F.\n\n\n \n\n\n\n Journal of Plasma Physics, 81(5). 2015.\n cited By 10\n\n\n\n
\n\n\n\n \n \n \"NucleationPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Taccogna2015,\nauthor={Taccogna, F.},\ntitle={Nucleation and growth of nanoparticles in a plasma by laser ablation in liquid},\njournal={Journal of Plasma Physics},\nyear={2015},\nvolume={81},\nnumber={5},\ndoi={10.1017/S0022377815000793},\nart_number={495810509},\nnote={cited By 10},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84945206675&doi=10.1017%2fS0022377815000793&partnerID=40&md5=27efb8d63715a7b9f6841f74d55effcd},\nabstract={Modelling the nucleation and growth of nanoparticles in liquid-phase laser ablation is very important to optimize and control thesize and the structure of nanoparticles. However, the detailed formation process of nanoparticles after laser ablation is still unclear. In the present study we investigated for the first time the kinetic growth of nanoparticles synthesized by laser ablation in water, emphasizing the leading role of the plasma medium and in particular the electrostatic agglomeration due to the charging of the nanoparticle in the plasma plume. The importance of the confining role of the liquid medium on the plasma plume is revealed, showing how anisothermal expansion is able to produce smaller nanoparticles compared to an adiabatic cooling. © 2015 Cambridge University Press.},\npublisher={Cambridge University Press},\nissn={00223778},\ncoden={JPLPB},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Modelling the nucleation and growth of nanoparticles in liquid-phase laser ablation is very important to optimize and control thesize and the structure of nanoparticles. However, the detailed formation process of nanoparticles after laser ablation is still unclear. In the present study we investigated for the first time the kinetic growth of nanoparticles synthesized by laser ablation in water, emphasizing the leading role of the plasma medium and in particular the electrostatic agglomeration due to the charging of the nanoparticle in the plasma plume. The importance of the confining role of the liquid medium on the plasma plume is revealed, showing how anisothermal expansion is able to produce smaller nanoparticles compared to an adiabatic cooling. © 2015 Cambridge University Press.\n
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\n \n\n \n \n \n \n \n \n Implications of TiO2 surface functionalization on polycrystalline mixed halide perovskite films and photovoltaic devices.\n \n \n \n \n\n\n \n Guerra, V.; Altamura, D.; Trifiletti, V.; Colella, S.; Listorti, A.; Giannuzzi, R.; Pellegrino, G.; Condorelli, G.; Giannini, C.; Gigli, G.; and Rizzo, A.\n\n\n \n\n\n\n Journal of Materials Chemistry A, 3(41): 20811-20818. 2015.\n cited By 26\n\n\n\n
\n\n\n\n \n \n \"ImplicationsPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Guerra201520811,\nauthor={Guerra, V.L.P. and Altamura, D. and Trifiletti, V. and Colella, S. and Listorti, A. and Giannuzzi, R. and Pellegrino, G. and Condorelli, G.G. and Giannini, C. and Gigli, G. and Rizzo, A.},\ntitle={Implications of TiO2 surface functionalization on polycrystalline mixed halide perovskite films and photovoltaic devices},\njournal={Journal of Materials Chemistry A},\nyear={2015},\nvolume={3},\nnumber={41},\npages={20811-20818},\ndoi={10.1039/c5ta05220c},\nnote={cited By 26},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84944244642&doi=10.1039%2fc5ta05220c&partnerID=40&md5=af3e6689e4cfe51cabd5b641fc64cd7d},\nabstract={We exploit TiO2 surface functionalization as a tool to induce the crystallization process of CH3NH3PbI3-xClx perovskite thin films resulting in a reduction of the degree of orientation of the (110) crystallographic planes. Notably, the variation of the film crystalline orientational order does not affect the photovoltaic performances of the perovskite-based devices, whose efficiency remains mostly unchanged. Our findings suggest that other factors are more significant in determining the device efficiency, such as the non-homogenous coverage of the TiO2 surface causing charge recombination at the organic/TiO2 interface, defect distribution on the perovskite bulk and at the interfaces, and transport in the organic or TiO2 layer. This observation represents a step towards the comprehension of the perovskite film peculiarities influencing the photovoltaic efficiency for high performance devices. © The Royal Society of Chemistry 2015.},\npublisher={Royal Society of Chemistry},\nissn={20507488},\ncoden={JMCAE},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We exploit TiO2 surface functionalization as a tool to induce the crystallization process of CH3NH3PbI3-xClx perovskite thin films resulting in a reduction of the degree of orientation of the (110) crystallographic planes. Notably, the variation of the film crystalline orientational order does not affect the photovoltaic performances of the perovskite-based devices, whose efficiency remains mostly unchanged. Our findings suggest that other factors are more significant in determining the device efficiency, such as the non-homogenous coverage of the TiO2 surface causing charge recombination at the organic/TiO2 interface, defect distribution on the perovskite bulk and at the interfaces, and transport in the organic or TiO2 layer. This observation represents a step towards the comprehension of the perovskite film peculiarities influencing the photovoltaic efficiency for high performance devices. © The Royal Society of Chemistry 2015.\n
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\n \n\n \n \n \n \n \n \n Synthesis of reduced graphite oxide by a novel green process based on UV light irradiation.\n \n \n \n \n\n\n \n Giuri, A.; Rella, S.; Malitesta, C.; Colella, S.; Listorti, A.; Gigli, G.; Rizzo, A.; Davide Cozzoli, P.; Acocella, M.; Guerra, G.; and Corcione, C.\n\n\n \n\n\n\n Science of Advanced Materials, 7(11): 2445-2451. 2015.\n cited By 8\n\n\n\n
\n\n\n\n \n \n \"SynthesisPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Giuri20152445,\nauthor={Giuri, A. and Rella, S. and Malitesta, C. and Colella, S. and Listorti, A. and Gigli, G. and Rizzo, A. and Davide Cozzoli, P. and Acocella, M.R. and Guerra, G. and Corcione, C.E.},\ntitle={Synthesis of reduced graphite oxide by a novel green process based on UV light irradiation},\njournal={Science of Advanced Materials},\nyear={2015},\nvolume={7},\nnumber={11},\npages={2445-2451},\ndoi={10.1166/sam.2015.2472},\nnote={cited By 8},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947333679&doi=10.1166%2fsam.2015.2472&partnerID=40&md5=ff45740123f959e8c69febaad6a8299c},\nabstract={We have developed a novel and straightforward approach for the green synthesis of reduced graphite oxide (rGO). First, graphite oxide (GO) was prepared by the Hummers' oxidation method, starting from high-surfacearea graphite. Then, rGO was generated from GO in aqueous suspension through a UV-irradiation treatment. The influence of different process parameters (including type of UV source, irradiation time and atmosphere) on the GO reduction efficiency was explored and evaluated on the basis of the data acquired by several experimental techniques, such as infrared spectroscopy in attenuated total reflectance mode, X-ray diffraction, UV-vis absorption spectrophotometry, X-ray photoelectron spectroscopy and thermogravimetry. The acquired results allowed identifying appropriate sets of reaction conditions under which GO reduction yield could be maximized. In particular, the highest reduction degree was obtained by exposing GO to UV light in a UV oven for 48 h under inert atmosphere. The reduction strategy developed by us represents an innovative low-cost and easy route to graphene-based nanomaterials, which does not require any stabilizer, photocatalyst or reducing agent. For this reason, our method represents an attractive environmentally friendly alternative approach for the preparation of stable rGO dispersions in large-scale amounts, to be utilizable in disparate engineering applications. © 2015 by American Scientific Publishers.},\npublisher={American Scientific Publishers},\nissn={19472935},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We have developed a novel and straightforward approach for the green synthesis of reduced graphite oxide (rGO). First, graphite oxide (GO) was prepared by the Hummers' oxidation method, starting from high-surfacearea graphite. Then, rGO was generated from GO in aqueous suspension through a UV-irradiation treatment. The influence of different process parameters (including type of UV source, irradiation time and atmosphere) on the GO reduction efficiency was explored and evaluated on the basis of the data acquired by several experimental techniques, such as infrared spectroscopy in attenuated total reflectance mode, X-ray diffraction, UV-vis absorption spectrophotometry, X-ray photoelectron spectroscopy and thermogravimetry. The acquired results allowed identifying appropriate sets of reaction conditions under which GO reduction yield could be maximized. In particular, the highest reduction degree was obtained by exposing GO to UV light in a UV oven for 48 h under inert atmosphere. The reduction strategy developed by us represents an innovative low-cost and easy route to graphene-based nanomaterials, which does not require any stabilizer, photocatalyst or reducing agent. For this reason, our method represents an attractive environmentally friendly alternative approach for the preparation of stable rGO dispersions in large-scale amounts, to be utilizable in disparate engineering applications. © 2015 by American Scientific Publishers.\n
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\n \n\n \n \n \n \n \n \n Sustainability of organic dye-sensitized solar cells: The role of chemical synthesis.\n \n \n \n \n\n\n \n Grisorio, R.; De Marco, L.; Baldisserri, C.; Martina, F.; Serantoni, M.; Gigli, G.; and Suranna, G.\n\n\n \n\n\n\n ACS Sustainable Chemistry and Engineering, 3(4): 770-777. 2015.\n cited By 36\n\n\n\n
\n\n\n\n \n \n \"SustainabilityPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Grisorio2015770,\nauthor={Grisorio, R. and De Marco, L. and Baldisserri, C. and Martina, F. and Serantoni, M. and Gigli, G. and Suranna, G.P.},\ntitle={Sustainability of organic dye-sensitized solar cells: The role of chemical synthesis},\njournal={ACS Sustainable Chemistry and Engineering},\nyear={2015},\nvolume={3},\nnumber={4},\npages={770-777},\ndoi={10.1021/acssuschemeng.5b00108},\nnote={cited By 36},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84926484870&doi=10.1021%2facssuschemeng.5b00108&partnerID=40&md5=71454c93a00add7ade96a6b998fa011f},\nabstract={The synthesis of a novel and efficient π-extended D-A-π-A organic sensitizer (G3, φ = 8.64%) for dye-sensitized solar cells has been accomplished by applying the green chemistry pillars, aiming at overriding traditional routes involving organometallic intermediates with innovative synthetic strategies for reducing the waste burden and dye production costs. It has been demonstrated that the obtainment of a complex target sensitizer can be exclusively pursued via direct arylation reactions. Green metrics comparison with those of a traditional synthetic pathway clearly indicates that the new approach has a lower environmental impact in terms of chemical procedures and generated wastes, stressing the importance of the synergy between the molecular design and the synthetic plan in the framework of environmentally friendly routes to back up sustainable development of third-generation photovoltaics. Additionally, the stability of the G3-based photovoltaic devices was also investigated in aging tests on large area devices, evidencing the excellent potentialities of the proposed structure for all practical applications involving inorganic semiconductor/organic dye interfaces. © 2015 American Chemical Society.},\npublisher={American Chemical Society},\nissn={21680485},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The synthesis of a novel and efficient π-extended D-A-π-A organic sensitizer (G3, φ = 8.64%) for dye-sensitized solar cells has been accomplished by applying the green chemistry pillars, aiming at overriding traditional routes involving organometallic intermediates with innovative synthetic strategies for reducing the waste burden and dye production costs. It has been demonstrated that the obtainment of a complex target sensitizer can be exclusively pursued via direct arylation reactions. Green metrics comparison with those of a traditional synthetic pathway clearly indicates that the new approach has a lower environmental impact in terms of chemical procedures and generated wastes, stressing the importance of the synergy between the molecular design and the synthetic plan in the framework of environmentally friendly routes to back up sustainable development of third-generation photovoltaics. Additionally, the stability of the G3-based photovoltaic devices was also investigated in aging tests on large area devices, evidencing the excellent potentialities of the proposed structure for all practical applications involving inorganic semiconductor/organic dye interfaces. © 2015 American Chemical Society.\n
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\n \n\n \n \n \n \n \n \n New biocompatible polymeric micelles designed for efficient intracellular uptake and delivery.\n \n \n \n \n\n\n \n Di Maria, F.; Blasi, L.; Quarta, A.; Bergamini, G.; Barbarella, G.; Giorgini, L.; and Benaglia, M.\n\n\n \n\n\n\n Journal of Materials Chemistry B, 3(46): 8963-8972. 2015.\n cited By 3\n\n\n\n
\n\n\n\n \n \n \"NewPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{DiMaria20158963,\nauthor={Di Maria, F. and Blasi, L. and Quarta, A. and Bergamini, G. and Barbarella, G. and Giorgini, L. and Benaglia, M.},\ntitle={New biocompatible polymeric micelles designed for efficient intracellular uptake and delivery},\njournal={Journal of Materials Chemistry B},\nyear={2015},\nvolume={3},\nnumber={46},\npages={8963-8972},\ndoi={10.1039/c5tb01631b},\nnote={cited By 3},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947801789&doi=10.1039%2fc5tb01631b&partnerID=40&md5=8555be2c23e36589cd1c0b9619b18327},\nabstract={New amphiphilic block copolymers are easily synthesised by post-polymerisation modifications of poly(glycidyl methacrylate) chain derivatives. The obtained material, upon dispersion in water, is capable of self-assembling into robust micelles. These nanoparticles, which are also characterised by adaptable stability, were loaded with different thiophene based fluorophores. The photoluminescent micelles were administered to cultured cells revealing a high and rapid internalisation of structurally different fluorescent molecules by the same internalisation pathway. Appropriate pairs of chromophores were selected and loaded into the micelles to induce Förster resonance energy transfer (FRET). The disappearing of the FRET phenomenon, after cell uptaking, demonstrated the intracellular release of the nanoparticle contents. The studied nanomaterial and the loaded chromophores have also shown to be biocompatible and non toxic towards the tested cells. © The Royal Society of Chemistry 2015.},\npublisher={Royal Society of Chemistry},\nissn={20507518},\ncoden={JMCBD},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n New amphiphilic block copolymers are easily synthesised by post-polymerisation modifications of poly(glycidyl methacrylate) chain derivatives. The obtained material, upon dispersion in water, is capable of self-assembling into robust micelles. These nanoparticles, which are also characterised by adaptable stability, were loaded with different thiophene based fluorophores. The photoluminescent micelles were administered to cultured cells revealing a high and rapid internalisation of structurally different fluorescent molecules by the same internalisation pathway. Appropriate pairs of chromophores were selected and loaded into the micelles to induce Förster resonance energy transfer (FRET). The disappearing of the FRET phenomenon, after cell uptaking, demonstrated the intracellular release of the nanoparticle contents. The studied nanomaterial and the loaded chromophores have also shown to be biocompatible and non toxic towards the tested cells. © The Royal Society of Chemistry 2015.\n
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\n \n\n \n \n \n \n \n \n Fatty acid binding into the highest affinity site of human serum albumin observed in molecular dynamics simulation.\n \n \n \n \n\n\n \n Rizzuti, B.; Bartucci, R.; Sportelli, L.; and Guzzi, R.\n\n\n \n\n\n\n Archives of Biochemistry and Biophysics, 579(1): 18-25. 2015.\n cited By 21\n\n\n\n
\n\n\n\n \n \n \"FattyPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Rizzuti201518,\nauthor={Rizzuti, B. and Bartucci, R. and Sportelli, L. and Guzzi, R.},\ntitle={Fatty acid binding into the highest affinity site of human serum albumin observed in molecular dynamics simulation},\njournal={Archives of Biochemistry and Biophysics},\nyear={2015},\nvolume={579},\nnumber={1},\npages={18-25},\ndoi={10.1016/j.abb.2015.05.018},\nnote={cited By 21},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84934941822&doi=10.1016%2fj.abb.2015.05.018&partnerID=40&md5=9ceaa5965d8faedc6a445ef7c91b8081},\nabstract={Multiple molecular dynamics simulations were performed to investigate the association of stearic acid into the highest affinity binding site of human serum albumin. All binding events ended with a rapid (&lt;10 ps) lock-in of the fatty acid due to formation of a hydrogen bond with Tyr401. The kinetics and energetics of the penetration process both depended linearly on the positional shift of the fatty acid, with an average insertion time and free energy reduction of, respectively, 32 ± 20 ps and 0.70 ± 0.15 kcal/mol per methylene group absorbed. Binding events of longer duration (tbind &gt; 1 ns) were characterized by a slow exploration of the pocket entry and, frequently, of a nearby protein crevice corresponding to a metastable state along the route to the binding site. Taken all together, these findings reconstruct the following pathway for the binding process of stearic acid: (i) contact with the protein surface, possibly facilitated by the presence of an intermediate location, (ii) probing of the site entry, (iii) insertion into the protein, and (iv) lock-in at the final position. This general description may also apply to other long-chain fatty acids binding into any of the high-affinity sites of albumin, or to specific sites of other lipid-binding proteins. © 2015 Elsevier Inc. All rights reserved.},\npublisher={Academic Press Inc.},\nissn={00039861},\ncoden={ABBIA},\npubmed_id={26048999},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
\n
\n\n\n
\n Multiple molecular dynamics simulations were performed to investigate the association of stearic acid into the highest affinity binding site of human serum albumin. All binding events ended with a rapid (<10 ps) lock-in of the fatty acid due to formation of a hydrogen bond with Tyr401. The kinetics and energetics of the penetration process both depended linearly on the positional shift of the fatty acid, with an average insertion time and free energy reduction of, respectively, 32 ± 20 ps and 0.70 ± 0.15 kcal/mol per methylene group absorbed. Binding events of longer duration (tbind > 1 ns) were characterized by a slow exploration of the pocket entry and, frequently, of a nearby protein crevice corresponding to a metastable state along the route to the binding site. Taken all together, these findings reconstruct the following pathway for the binding process of stearic acid: (i) contact with the protein surface, possibly facilitated by the presence of an intermediate location, (ii) probing of the site entry, (iii) insertion into the protein, and (iv) lock-in at the final position. This general description may also apply to other long-chain fatty acids binding into any of the high-affinity sites of albumin, or to specific sites of other lipid-binding proteins. © 2015 Elsevier Inc. All rights reserved.\n
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\n \n\n \n \n \n \n \n \n One step preparation of quantum dot-embedded lipid nanovesicles by a microfluidic device.\n \n \n \n \n\n\n \n Zacheo, A.; Quarta, A.; Zizzari, A.; Monteduro, A.; Maruccio, G.; Arima, V.; and Gigli, G.\n\n\n \n\n\n\n RSC Advances, 5(119): 98576-98582. 2015.\n cited By 4\n\n\n\n
\n\n\n\n \n \n \"OnePaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Zacheo201598576,\nauthor={Zacheo, A. and Quarta, A. and Zizzari, A. and Monteduro, A.G. and Maruccio, G. and Arima, V. and Gigli, G.},\ntitle={One step preparation of quantum dot-embedded lipid nanovesicles by a microfluidic device},\njournal={RSC Advances},\nyear={2015},\nvolume={5},\nnumber={119},\npages={98576-98582},\ndoi={10.1039/c5ra18862h},\nnote={cited By 4},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84948424853&doi=10.1039%2fc5ra18862h&partnerID=40&md5=319b14b31746ba3cd878853479bda5c1},\nabstract={Synthetic carriers that mimic "natural lipid-based vesicles" (such as micro/nanovesicles, exosomes) have found broad applications in biomedicine for the delivery of biomolecules and drugs. Remarkable advantages of using synthetic carriers include control over the lipid composition, structure and size, together with the possibility to add tracer molecules to monitor their in situ distribution via fluorescence microscopy. Over the past few years, new methods of vesicles production have been developed and optimized, such as those based on microfluidic techniques. These innovative approaches allow us to overcome the limitations faced in conventional methods of liposome preparation, such as size distribution and polydispersity. Herein, a Microfluidic Hydrodynamic Focusing (MHF) device has been used for the production of lipid-based vesicles with different lipid combinations that resemble natural exosomes, such as phosphatidylcholines (PC), cholesterol (Chol), dicetyl phosphate (DCP) and ceramide (Cer). Thanks to a fine control on fluid manipulation, the MHF device allows preparation of vesicles with controlled size, a relevant feature in the emerging field of carrier-assisted cell-delivery. Interestingly, PC/Chol/Cer vesicles exhibit low polydispersity and high stability up to 45 days. Later, quantum dots (QDs) were successfully embedded in these vesicles through the same preparation process. The development of QD-embedded lipid nanovesicles by MHF devices has never been described previously.},\npublisher={Royal Society of Chemistry},\nissn={20462069},\ncoden={RSCAC},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
\n
\n\n\n
\n Synthetic carriers that mimic \"natural lipid-based vesicles\" (such as micro/nanovesicles, exosomes) have found broad applications in biomedicine for the delivery of biomolecules and drugs. Remarkable advantages of using synthetic carriers include control over the lipid composition, structure and size, together with the possibility to add tracer molecules to monitor their in situ distribution via fluorescence microscopy. Over the past few years, new methods of vesicles production have been developed and optimized, such as those based on microfluidic techniques. These innovative approaches allow us to overcome the limitations faced in conventional methods of liposome preparation, such as size distribution and polydispersity. Herein, a Microfluidic Hydrodynamic Focusing (MHF) device has been used for the production of lipid-based vesicles with different lipid combinations that resemble natural exosomes, such as phosphatidylcholines (PC), cholesterol (Chol), dicetyl phosphate (DCP) and ceramide (Cer). Thanks to a fine control on fluid manipulation, the MHF device allows preparation of vesicles with controlled size, a relevant feature in the emerging field of carrier-assisted cell-delivery. Interestingly, PC/Chol/Cer vesicles exhibit low polydispersity and high stability up to 45 days. Later, quantum dots (QDs) were successfully embedded in these vesicles through the same preparation process. The development of QD-embedded lipid nanovesicles by MHF devices has never been described previously.\n
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\n \n\n \n \n \n \n \n \n Hyperbolic metamaterials: Design, fabrication, and applications of ultra-anisotropic nanomaterials.\n \n \n \n \n\n\n \n Sreekanth, K.; Luca, A.; and Strangi, G.\n\n\n \n\n\n\n NanoScience and Technology, 100: 447-467. 2015.\n cited By 2\n\n\n\n
\n\n\n\n \n \n \"HyperbolicPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Sreekanth2015447,\nauthor={Sreekanth, K.V. and Luca, A.D. and Strangi, G.},\ntitle={Hyperbolic metamaterials: Design, fabrication, and applications of ultra-anisotropic nanomaterials},\njournal={NanoScience and Technology},\nyear={2015},\nvolume={100},\npages={447-467},\ndoi={10.1007/978-3-319-18293-3_12},\nnote={cited By 2},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84931268762&doi=10.1007%2f978-3-319-18293-3_12&partnerID=40&md5=64af1e9f2fc08c2decc2912a21fe6c2a},\nabstract={Hyperbolic metamaterial (HMM) is a non-magnetic extremely anisotropic nanostructure that cannot be found in nature at optical frequencies having an open hyperboloid iso-frequency surface. Interestingly, these anisotropic media support highly confined wavevector modes (high-k modes) in addition to surface plasmon modes within the structure due to hyperbolic dispersion. The high-k modes in an anisotropic hyperbolic metamaterials are conventionally refereed to as volume plasmon polaritons (VPPs) or bulk Bloch plasmon polaritons (BPPs). Since BPPs are highly confined within the entire structure, the excitation, collection and control those modes at optical frequencies are very challenging. Here, the focus will be on the excitation and collection of bulk plasmon polaritons from anisotropic hyperbolic metamaterials at optical frequencies using the grating coupling principle. In this chapter, the basic properties of hyperbolic metamaterials are first introduced. Then we give a comprehensive overview, describing on design, fabrication and characterization of grating coupled anisotropic hyperbolic metamaterials (GCAHMs) in a wide wavelength range, from visible to near infrared. Numerical simulation results supporting the obtained experimental data are also presented. Finally, we describe potential applications of GCAHMs in photonics and biomedical research with concluding remarks. © Springer International Publishing Switzerland 2015.},\npublisher={Springer Verlag},\nissn={14344904},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n Hyperbolic metamaterial (HMM) is a non-magnetic extremely anisotropic nanostructure that cannot be found in nature at optical frequencies having an open hyperboloid iso-frequency surface. Interestingly, these anisotropic media support highly confined wavevector modes (high-k modes) in addition to surface plasmon modes within the structure due to hyperbolic dispersion. The high-k modes in an anisotropic hyperbolic metamaterials are conventionally refereed to as volume plasmon polaritons (VPPs) or bulk Bloch plasmon polaritons (BPPs). Since BPPs are highly confined within the entire structure, the excitation, collection and control those modes at optical frequencies are very challenging. Here, the focus will be on the excitation and collection of bulk plasmon polaritons from anisotropic hyperbolic metamaterials at optical frequencies using the grating coupling principle. In this chapter, the basic properties of hyperbolic metamaterials are first introduced. Then we give a comprehensive overview, describing on design, fabrication and characterization of grating coupled anisotropic hyperbolic metamaterials (GCAHMs) in a wide wavelength range, from visible to near infrared. Numerical simulation results supporting the obtained experimental data are also presented. Finally, we describe potential applications of GCAHMs in photonics and biomedical research with concluding remarks. © Springer International Publishing Switzerland 2015.\n
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\n \n\n \n \n \n \n \n \n Direct epitaxial CVD synthesis of tungsten disulfide on epitaxial and CVD graphene.\n \n \n \n \n\n\n \n Bianco, G.; Losurdo, M.; Giangregorio, M.; Sacchetti, A.; Prete, P.; Lovergine, N.; Capezzuto, P.; and Bruno, G.\n\n\n \n\n\n\n RSC Advances, 5(119): 98700-98708. 2015.\n cited By 24\n\n\n\n
\n\n\n\n \n \n \"DirectPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Bianco201598700,\nauthor={Bianco, G.V. and Losurdo, M. and Giangregorio, M.M. and Sacchetti, A. and Prete, P. and Lovergine, N. and Capezzuto, P. and Bruno, G.},\ntitle={Direct epitaxial CVD synthesis of tungsten disulfide on epitaxial and CVD graphene},\njournal={RSC Advances},\nyear={2015},\nvolume={5},\nnumber={119},\npages={98700-98708},\ndoi={10.1039/c5ra19698a},\nnote={cited By 24},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84948389654&doi=10.1039%2fc5ra19698a&partnerID=40&md5=7e743286e9ea1bb768b1cabc7ce58631},\nabstract={The direct chemical vapor deposition of WS2 by W(CO)6 and elemental sulfur as precursors onto epitaxial-graphene on SiC and CVD-graphene transferred on SiO2/Si substrate is presented. This methodology allows the epitaxial growth of continuous WS2 films with a homogeneous and narrow photoluminescence peak without inducing stress or structural defects in the graphene substrates. The control of the WS2 growth dynamics for providing the localized sulfide deposition by tuning the surface energy of the graphene substrates is also demonstrated. This growth methodology opens the way towards the direct bottom up fabrication of devices based on TMDCs/graphene van der Waals heterostructures. © 2015 The Royal Society of Chemistry.},\npublisher={Royal Society of Chemistry},\nissn={20462069},\ncoden={RSCAC},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The direct chemical vapor deposition of WS2 by W(CO)6 and elemental sulfur as precursors onto epitaxial-graphene on SiC and CVD-graphene transferred on SiO2/Si substrate is presented. This methodology allows the epitaxial growth of continuous WS2 films with a homogeneous and narrow photoluminescence peak without inducing stress or structural defects in the graphene substrates. The control of the WS2 growth dynamics for providing the localized sulfide deposition by tuning the surface energy of the graphene substrates is also demonstrated. This growth methodology opens the way towards the direct bottom up fabrication of devices based on TMDCs/graphene van der Waals heterostructures. © 2015 The Royal Society of Chemistry.\n
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\n \n\n \n \n \n \n \n \n Graphene-based optical absorbers.\n \n \n \n \n\n\n \n Grande, M.; Vincenti, M.; Stomeo, T.; Bianco, G.; De Ceglia, D.; Akozbek, N.; Petruzzelli, V.; Bruno, G.; De Vittorio, M.; Scalora, M.; and D'Orazio, A.\n\n\n \n\n\n\n 2015.\n cited By 1\n\n\n\n
\n\n\n\n \n \n \"Graphene-basedPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@CONFERENCE{Grande2015,\nauthor={Grande, M. and Vincenti, M.A. and Stomeo, T. and Bianco, G.V. and De Ceglia, D. and Akozbek, N. and Petruzzelli, V. and Bruno, G. and De Vittorio, M. and Scalora, M. and D'Orazio, A.},\ntitle={Graphene-based optical absorbers},\njournal={International Conference on Transparent Optical Networks},\nyear={2015},\nvolume={2015-August},\ndoi={10.1109/ICTON.2015.7193344},\nart_number={7193344},\nnote={cited By 1},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84940926917&doi=10.1109%2fICTON.2015.7193344&partnerID=40&md5=20f1600cfd363b23b62a07c4b24c6676},\nabstract={The absorption of electromagnetic waves has always attracted a large interest because of its cross-the-board nature that spans from microwave to optical frequencies in both linear and nonlinear regimes. At the same time, the experimental isolation of bi-dimensional (2D) materials has recently unveiled how single layers might also be very attractive because of their unprecedented optical and absorption properties. In particular, graphene, a 2D version of graphite, exhibits a remarkably high absorption value (∼2.3%) in the visible range [1] when compared to metals or dielectric materials. In this paper, we will review and illustrate the quest for the enhanced absorption in photonic nanostructures that incorporate monolayer and multilayer graphene sheets emphasizing the difference in terms of configurations and strategies proposed in literature. Then, we will detail the optical performance of graphene-based one-dimensional (1D) gratings that support guided mode resonances showing how it is possible to tune theoretically and experimentally their total absorption ranging from 2.3% to perfect absorption by means of metallic and dielectric reflectors or engineered super cells. © 2015 IEEE.},\neditor={Jaworski M., Marciniak M.},\npublisher={IEEE Computer Society},\nissn={21627339},\nisbn={9781467378802},\ndocument_type={Conference Paper},\nsource={Scopus},\n}\n\n
\n
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\n The absorption of electromagnetic waves has always attracted a large interest because of its cross-the-board nature that spans from microwave to optical frequencies in both linear and nonlinear regimes. At the same time, the experimental isolation of bi-dimensional (2D) materials has recently unveiled how single layers might also be very attractive because of their unprecedented optical and absorption properties. In particular, graphene, a 2D version of graphite, exhibits a remarkably high absorption value (∼2.3%) in the visible range [1] when compared to metals or dielectric materials. In this paper, we will review and illustrate the quest for the enhanced absorption in photonic nanostructures that incorporate monolayer and multilayer graphene sheets emphasizing the difference in terms of configurations and strategies proposed in literature. Then, we will detail the optical performance of graphene-based one-dimensional (1D) gratings that support guided mode resonances showing how it is possible to tune theoretically and experimentally their total absorption ranging from 2.3% to perfect absorption by means of metallic and dielectric reflectors or engineered super cells. © 2015 IEEE.\n
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\n \n\n \n \n \n \n \n \n Properties of nanocrystals-formulated aluminosilicate bricks.\n \n \n \n \n\n\n \n Conciauro, F.; Filippo, E.; Carlucci, C.; Vergaro, V.; Baldassarre, F.; D'Amato, R.; Terranova, G.; Lorusso, C.; Congedo, P.; Scremin, B.; and Ciccarella, G.\n\n\n \n\n\n\n Nanomaterials and Nanotechnology, 5(1). 2015.\n cited By 3\n\n\n\n
\n\n\n\n \n \n \"PropertiesPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Conciauro2015,\nauthor={Conciauro, F. and Filippo, E. and Carlucci, C. and Vergaro, V. and Baldassarre, F. and D'Amato, R. and Terranova, G. and Lorusso, C. and Congedo, P.M. and Scremin, B.F. and Ciccarella, G.},\ntitle={Properties of nanocrystals-formulated aluminosilicate bricks},\njournal={Nanomaterials and Nanotechnology},\nyear={2015},\nvolume={5},\nnumber={1},\ndoi={10.5772/61068},\nart_number={28},\nnote={cited By 3},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947915389&doi=10.5772%2f61068&partnerID=40&md5=3420d3e26888dd5b1791bd869b18a9a8},\nabstract={In the present work, seven different types of nanocrystals were studied as additives in the formulation of aluminosilicate bricks. The considered nanocrystals consisted of anatase titanium dioxide (two differently shaped types), boron modified anatase, calcium carbonate (in calcite phase), aluminium hydroxide and silicon carbide (of two diverse sizes), which were prepared using different methods. Syntheses aim to give a good control over a particle's size and shape. Anatase titania nanocrystals, together with the nano-aluminium hydroxide ones, were synthesized via microwave-assisted procedures, with the use of different additives and without the final calcination steps. The silicon carbide nanoparticles were prepared via laser pyrolysis. The nano-calcium carbonate was prepared via a spray drying technique. All of the nanocrystals were tested as fillers (in 0.5, 1 and 2 wt. % amounts) in a commercial aluminosilicate refractory (55 % Al2O3, 42 % SiO2). They were used to prepare bricks that were thermally treated at 1300 °C for 24 hours, according to the international norms. The differently synthesized nanocrystals were added for the preparation of the bricks, with the aim to improve their heatinsulating and/or mechanical properties. The nanocrystalsmodified refractories showed variations in properties, with respect to the untreated aluminosilicate reference in heatinsulating performances (thermal diffusivities were measured by the "hot disk" technique). In general, they also showed improvements in mechanical compression resistance for all of the samples at 2 wt. %. The best heat insulation was obtained with the addition of nano-aluminium hydroxide at 2 wt. %, while the highest mechanical compression breaking resistance was found with nano-CaCO3 at 2 wt. %. These outcomes were investigated with complementary techniques, like mercury porosimetry for porosity, and Archimedes methods to measure physical properties like the bulk and apparent densities, apparent porosities and water absorption. The results show that the nano-aluminium hydroxide modified bricks were the most porous, which could explain the best heat-insulating performances. There is a less straightforward explanation for the mechanical resistance results, as they may have relations with the characteristics of the pores. Furthermore, the nanoparticles may have possible reactions with the matrix during the heat treatments. © 2015 Author(s).},\npublisher={InTech Europe},\nissn={18479804},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n In the present work, seven different types of nanocrystals were studied as additives in the formulation of aluminosilicate bricks. The considered nanocrystals consisted of anatase titanium dioxide (two differently shaped types), boron modified anatase, calcium carbonate (in calcite phase), aluminium hydroxide and silicon carbide (of two diverse sizes), which were prepared using different methods. Syntheses aim to give a good control over a particle's size and shape. Anatase titania nanocrystals, together with the nano-aluminium hydroxide ones, were synthesized via microwave-assisted procedures, with the use of different additives and without the final calcination steps. The silicon carbide nanoparticles were prepared via laser pyrolysis. The nano-calcium carbonate was prepared via a spray drying technique. All of the nanocrystals were tested as fillers (in 0.5, 1 and 2 wt. % amounts) in a commercial aluminosilicate refractory (55 % Al2O3, 42 % SiO2). They were used to prepare bricks that were thermally treated at 1300 °C for 24 hours, according to the international norms. The differently synthesized nanocrystals were added for the preparation of the bricks, with the aim to improve their heatinsulating and/or mechanical properties. The nanocrystalsmodified refractories showed variations in properties, with respect to the untreated aluminosilicate reference in heatinsulating performances (thermal diffusivities were measured by the \"hot disk\" technique). In general, they also showed improvements in mechanical compression resistance for all of the samples at 2 wt. %. The best heat insulation was obtained with the addition of nano-aluminium hydroxide at 2 wt. %, while the highest mechanical compression breaking resistance was found with nano-CaCO3 at 2 wt. %. These outcomes were investigated with complementary techniques, like mercury porosimetry for porosity, and Archimedes methods to measure physical properties like the bulk and apparent densities, apparent porosities and water absorption. The results show that the nano-aluminium hydroxide modified bricks were the most porous, which could explain the best heat-insulating performances. There is a less straightforward explanation for the mechanical resistance results, as they may have relations with the characteristics of the pores. Furthermore, the nanoparticles may have possible reactions with the matrix during the heat treatments. © 2015 Author(s).\n
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\n \n\n \n \n \n \n \n \n Graphene-based perfect optical absorbers harnessing guided mode resonances.\n \n \n \n \n\n\n \n Grande, M.; Vincenti, M.; Stomeo, T.; Bianco, G.; De Ceglia, D.; Aközbek, N.; Petruzzelli, V.; Bruno, G.; De Vittorio, M.; Scalora, M.; and D'Orazio, A.\n\n\n \n\n\n\n Optics Express, 23(16). 2015.\n cited By 70\n\n\n\n
\n\n\n\n \n \n \"Graphene-basedPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Grande2015,\nauthor={Grande, M. and Vincenti, M.A. and Stomeo, T. and Bianco, G.V. and De Ceglia, D. and Aközbek, N. and Petruzzelli, V. and Bruno, G. and De Vittorio, M. and Scalora, M. and D'Orazio, A.},\ntitle={Graphene-based perfect optical absorbers harnessing guided mode resonances},\njournal={Optics Express},\nyear={2015},\nvolume={23},\nnumber={16},\ndoi={10.1364/OE.23.021032},\nart_number={21032},\nnote={cited By 70},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84954285380&doi=10.1364%2fOE.23.021032&partnerID=40&md5=4c4b004d7e51f784fa3cbbfdbdcc7b1e},\nabstract={We investigate graphene-based optical absorbers that exploit guided mode resonances (GMRs) attaining theoretically perfect absorption over a bandwidth of few nanometers (over the visible and near-infrared ranges) with a 40-fold increase of the monolayer graphene absorption. We analyze the influence of the geometrical parameters on the absorption rate and the angular response for oblique incidence. Finally, we experimentally verify the theoretical predictions in a one-dimensional, dielectric grating by placing it near either a metallic or a dielectric mirror, thus achieving very good agreement between numerical predictions and experimental results. © 2015 Optical Society of America.},\npublisher={OSA - The Optical Society},\nissn={10944087},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n We investigate graphene-based optical absorbers that exploit guided mode resonances (GMRs) attaining theoretically perfect absorption over a bandwidth of few nanometers (over the visible and near-infrared ranges) with a 40-fold increase of the monolayer graphene absorption. We analyze the influence of the geometrical parameters on the absorption rate and the angular response for oblique incidence. Finally, we experimentally verify the theoretical predictions in a one-dimensional, dielectric grating by placing it near either a metallic or a dielectric mirror, thus achieving very good agreement between numerical predictions and experimental results. © 2015 Optical Society of America.\n
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\n \n\n \n \n \n \n \n \n Efficient, green non-aqueous microwave-assisted synthesis of anatase TiO2 and Pt loaded TiO2 nanorods with high photocatalytic performance.\n \n \n \n \n\n\n \n Filippo, E.; Capodilupo, A.; Carlucci, C.; Perulli, P.; Conciauro, F.; Corrente, G.; Scremin, B.; Gigli, G.; and Ciccarella, G.\n\n\n \n\n\n\n Nanomaterials and Nanotechnology, 5(1). 2015.\n cited By 6\n\n\n\n
\n\n\n\n \n \n \"Efficient,Paper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{Filippo2015,\nauthor={Filippo, E. and Capodilupo, A.L. and Carlucci, C. and Perulli, P. and Conciauro, F. and Corrente, G.A. and Scremin, B.F. and Gigli, G. and Ciccarella, G.},\ntitle={Efficient, green non-aqueous microwave-assisted synthesis of anatase TiO2 and Pt loaded TiO2 nanorods with high photocatalytic performance},\njournal={Nanomaterials and Nanotechnology},\nyear={2015},\nvolume={5},\nnumber={1},\ndoi={10.5772/61147},\nart_number={61147},\nnote={cited By 6},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84982718983&doi=10.5772%2f61147&partnerID=40&md5=216485d41f45d3590e632f65413f6c33},\nabstract={A high-yield synthesis of pure anatase titania nanorods has been achieved through a nonaqueous microwave-based approach. The residual organics on nanoparticles surfaces were completely removed under ozone flow at room temperature in air. The TiO2 nanorods, with average lengths of 27.6 ± 5.8 nm and average diameters of 3.2 ± 0.4 nm, were characterized by powder X-Ray diffraction, transmission electron microscopy, selected area diffraction, BET surface area analysis and FT-IR spectroscopy. The photocatalytic performances of the as-synthesized TiO2 nanorods and platinum loaded TiO2 nanorods were implemented with respect to both commercial P25 and platinum loaded P25. Performance enhancements should be attributed to effects like differences in the adsorption capacity and in the separation efficiency of the photogenerated electrons-holes. © 2015 Author(s).},\npublisher={SAGE Publications Inc.},\nissn={18479804},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n A high-yield synthesis of pure anatase titania nanorods has been achieved through a nonaqueous microwave-based approach. The residual organics on nanoparticles surfaces were completely removed under ozone flow at room temperature in air. The TiO2 nanorods, with average lengths of 27.6 ± 5.8 nm and average diameters of 3.2 ± 0.4 nm, were characterized by powder X-Ray diffraction, transmission electron microscopy, selected area diffraction, BET surface area analysis and FT-IR spectroscopy. The photocatalytic performances of the as-synthesized TiO2 nanorods and platinum loaded TiO2 nanorods were implemented with respect to both commercial P25 and platinum loaded P25. Performance enhancements should be attributed to effects like differences in the adsorption capacity and in the separation efficiency of the photogenerated electrons-holes. © 2015 Author(s).\n
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\n \n\n \n \n \n \n \n \n Interaction between human serum albumin and different anatase TiO2 nanoparticles: A nano-bio interface study.\n \n \n \n \n\n\n \n Vergaro, V.; Carlucci, C.; Cascione, M.; Lorusso, C.; Conciauro, F.; Scremin, B.; Congedo, P.; Cannazza, G.; Citti, C.; and Ciccarella, G.\n\n\n \n\n\n\n Nanomaterials and Nanotechnology, 5(1). 2015.\n cited By 10\n\n\n\n
\n\n\n\n \n \n \"InteractionPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
\n
@ARTICLE{Vergaro2015,\nauthor={Vergaro, V. and Carlucci, C. and Cascione, M. and Lorusso, C. and Conciauro, F. and Scremin, B.F. and Congedo, P.M. and Cannazza, G. and Citti, C. and Ciccarella, G.},\ntitle={Interaction between human serum albumin and different anatase TiO2 nanoparticles: A nano-bio interface study},\njournal={Nanomaterials and Nanotechnology},\nyear={2015},\nvolume={5},\nnumber={1},\ndoi={10.5772/61092},\nart_number={30},\nnote={cited By 10},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947939754&doi=10.5772%2f61092&partnerID=40&md5=b99abe30db376a730c6922daa902db09},\nabstract={In this investigation, differently shaped and surface functionalized TiO2 anatase nanoparticles and human serum albumin (HSA) were selected to study proteinnanoparticles interaction both in a solution and on flat surfaces, thereby mimicking a medical device. Anatase nanocrystals were characterized by transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) surface analysis and dynamic light scattering (DLS). The proteinnanoparticles' interactions and their eventual reversibility were studied by pH dependent ζ- potential measurements in different media: ultra-pure water, a phosphate buffer simulating physiological conditions and in a culture medium supplemented with foetal bovine serum. The protein corona masking effect was evidenced and the interaction HSA-nanocrystals resulted irreversible. The interaction HSA-silicon supported TiO2 nanocrystals films was studied by atomic force microscopy (AFM), and resulted driven by the substrate hydrophilicity degree plus was different for the diverse range of nanocrystals tested. Surface roughness measurements showed that on some of the nanocrystals, HSA were arranged in a more globular manner. A lower protein affinity was found for nanocrystals that had a smaller primary particle size, which may correspond to their higher biocompatibility. This nano-bio interface research aimed to study the HSA protein-TiO2 anatase nanocrystals under conditions similar to those for in vitro and in vivo toxicity analyses. © 2015 Author(s). Licensee InTech.},\npublisher={InTech Europe},\nissn={18479804},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n In this investigation, differently shaped and surface functionalized TiO2 anatase nanoparticles and human serum albumin (HSA) were selected to study proteinnanoparticles interaction both in a solution and on flat surfaces, thereby mimicking a medical device. Anatase nanocrystals were characterized by transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) surface analysis and dynamic light scattering (DLS). The proteinnanoparticles' interactions and their eventual reversibility were studied by pH dependent ζ- potential measurements in different media: ultra-pure water, a phosphate buffer simulating physiological conditions and in a culture medium supplemented with foetal bovine serum. The protein corona masking effect was evidenced and the interaction HSA-nanocrystals resulted irreversible. The interaction HSA-silicon supported TiO2 nanocrystals films was studied by atomic force microscopy (AFM), and resulted driven by the substrate hydrophilicity degree plus was different for the diverse range of nanocrystals tested. Surface roughness measurements showed that on some of the nanocrystals, HSA were arranged in a more globular manner. A lower protein affinity was found for nanocrystals that had a smaller primary particle size, which may correspond to their higher biocompatibility. This nano-bio interface research aimed to study the HSA protein-TiO2 anatase nanocrystals under conditions similar to those for in vitro and in vivo toxicity analyses. © 2015 Author(s). Licensee InTech.\n
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\n \n\n \n \n \n \n \n \n Battling absorptive losses by plasmon-exciton coupling in multimeric nanostructures.\n \n \n \n \n\n\n \n Rahimi Rashed, A.; De Luca, A.; Dhama, R.; Hosseinzadeh, A.; Infusino, M.; El Kabbash, M.; Ravaine, S.; Bartolino, R.; and Strangi, G.\n\n\n \n\n\n\n RSC Advances, 5(66): 53245-53254. 2015.\n cited By 10\n\n\n\n
\n\n\n\n \n \n \"BattlingPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@ARTICLE{RahimiRashed201553245,\nauthor={Rahimi Rashed, A. and De Luca, A. and Dhama, R. and Hosseinzadeh, A. and Infusino, M. and El Kabbash, M. and Ravaine, S. and Bartolino, R. and Strangi, G.},\ntitle={Battling absorptive losses by plasmon-exciton coupling in multimeric nanostructures},\njournal={RSC Advances},\nyear={2015},\nvolume={5},\nnumber={66},\npages={53245-53254},\ndoi={10.1039/c5ra09673a},\nnote={cited By 10},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84935030852&doi=10.1039%2fc5ra09673a&partnerID=40&md5=2e937c05ab9bdd455375f2c9f1fcd19b},\nabstract={The strong inherent optical losses present in plasmonic nanostructures significantly limit their technological applications at optical frequencies. Here, we report on the interplay between plasmons and excitons as a potential approach to selectively reduce ohmic losses. Samples were prepared by functionalizing plasmonic core-shell nanostructures with excitonic molecules embedded in silica shells and interlocked by silica spacers to investigate the role played by the plasmon-exciton elements separation. Results obtained for different silica spacer thicknesses are evaluated by comparing dispersions of plasmonic multimers with respect to the corresponding monomers. We have observed fluorophore emission quenching by means of steady-state fluorescence spectroscopy, as well as a significant shortening of the corresponding fluorescence lifetime using TCSPC data. These results are accompanied by the simultaneous enhancement of Rayleigh scattering and transmittance, revealing more effective absorptive loss mitigation for multimeric systems. Moreover, upon decreasing the thickness of the intermediate silica layer between gold cores and the external gain functionalized silica shell, the efficiency of exciton-plasmon resonant energy transfer (EPRET) was significantly enhanced in both multimeric and monomeric samples. Simulation data along with experimental results confirm that the hybridized plasmon fields of multimers lead to more efficient optical loss compensation with respect to the corresponding monomers. © The Royal Society of Chemistry 2015.},\npublisher={Royal Society of Chemistry},\nissn={20462069},\ncoden={RSCAC},\ndocument_type={Article},\nsource={Scopus},\n}\n\n
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\n The strong inherent optical losses present in plasmonic nanostructures significantly limit their technological applications at optical frequencies. Here, we report on the interplay between plasmons and excitons as a potential approach to selectively reduce ohmic losses. Samples were prepared by functionalizing plasmonic core-shell nanostructures with excitonic molecules embedded in silica shells and interlocked by silica spacers to investigate the role played by the plasmon-exciton elements separation. Results obtained for different silica spacer thicknesses are evaluated by comparing dispersions of plasmonic multimers with respect to the corresponding monomers. We have observed fluorophore emission quenching by means of steady-state fluorescence spectroscopy, as well as a significant shortening of the corresponding fluorescence lifetime using TCSPC data. These results are accompanied by the simultaneous enhancement of Rayleigh scattering and transmittance, revealing more effective absorptive loss mitigation for multimeric systems. Moreover, upon decreasing the thickness of the intermediate silica layer between gold cores and the external gain functionalized silica shell, the efficiency of exciton-plasmon resonant energy transfer (EPRET) was significantly enhanced in both multimeric and monomeric samples. Simulation data along with experimental results confirm that the hybridized plasmon fields of multimers lead to more efficient optical loss compensation with respect to the corresponding monomers. © The Royal Society of Chemistry 2015.\n
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\n \n\n \n \n \n \n \n \n Statistical physics of multimode ordered and disordered lasers.\n \n \n \n \n\n\n \n Antenucci, F.; Crisanti, A.; Ibáñez Berganza, M.; and Leuzzi, L.\n\n\n \n\n\n\n 2015.\n cited By 0\n\n\n\n
\n\n\n\n \n \n \"StatisticalPaper\n  \n \n\n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@CONFERENCE{Antenucci20151981,\nauthor={Antenucci, F. and Crisanti, A. and Ibáñez Berganza, M. and Leuzzi, L.},\ntitle={Statistical physics of multimode ordered and disordered lasers},\njournal={Progress in Electromagnetics Research Symposium},\nyear={2015},\nvolume={2015-January},\npages={1981-1985},\nnote={cited By 0},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84947228235&partnerID=40&md5=cd89497326ed90b6660b0c26c389a775},\nabstract={The adoption of a statistical mechanical framework in optics provides realistic models for multimode laser systems, whose experimental implications are presented and critically analyzed. A model for passive mode locking lasers is analyzed beyond the mean-field approximation, accounting for the presence of many well-resolved frequencies of the lasing modes. The inhomogeneous structure in the nonlinear "mode locked" interaction network is shown to yield short pulses and phase waves with nontrivial slopes, corresponding to a phase delay of the pulsed laser signal. The analytic solution of a mean field-model for multimode laser in open and irregular cavities will be, afterwards, addressed. The complete phase diagram, in terms of degree of disorder, pumping rate of the source and strength of nonlinearity, consists of four different photonic regimes: incoherent fluorescence, mode locking, random lasing and the novel "phase locking wave". A replica symmetry breaking transition occurs at the random lasing threshold. For a high enough strength of nonlinearity, a whole region with nonvanishing complexity anticipates the transition and the light in the disordered medium displays typical glassy behavior.},\npublisher={Electromagnetics Academy},\nissn={15599450},\nisbn={9781934142301},\ndocument_type={Conference Paper},\nsource={Scopus},\n}\n\n
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\n The adoption of a statistical mechanical framework in optics provides realistic models for multimode laser systems, whose experimental implications are presented and critically analyzed. A model for passive mode locking lasers is analyzed beyond the mean-field approximation, accounting for the presence of many well-resolved frequencies of the lasing modes. The inhomogeneous structure in the nonlinear \"mode locked\" interaction network is shown to yield short pulses and phase waves with nontrivial slopes, corresponding to a phase delay of the pulsed laser signal. The analytic solution of a mean field-model for multimode laser in open and irregular cavities will be, afterwards, addressed. The complete phase diagram, in terms of degree of disorder, pumping rate of the source and strength of nonlinearity, consists of four different photonic regimes: incoherent fluorescence, mode locking, random lasing and the novel \"phase locking wave\". A replica symmetry breaking transition occurs at the random lasing threshold. For a high enough strength of nonlinearity, a whole region with nonvanishing complexity anticipates the transition and the light in the disordered medium displays typical glassy behavior.\n
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\n \n\n \n \n \n \n \n \n Plasma assisted flame stabilizationin a non-premixed lean burner.\n \n \n \n \n\n\n \n De Giorgi, M.; Sciolti, A.; Campilongo, S.; Pescini, E.; Ficarella, A.; Martini, L.; Tosi, P.; and Dilecce, G.\n\n\n \n\n\n\n 2015.\n cited By 11\n\n\n\n
\n\n\n\n \n \n \"PlasmaPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@CONFERENCE{DeGiorgi2015410,\nauthor={De Giorgi, M.G. and Sciolti, A. and Campilongo, S. and Pescini, E. and Ficarella, A. and Martini, L.M. and Tosi, P. and Dilecce, G.},\ntitle={Plasma assisted flame stabilizationin a non-premixed lean burner},\njournal={Energy Procedia},\nyear={2015},\nvolume={82},\npages={410-416},\ndoi={10.1016/j.egypro.2015.11.825},\nnote={cited By 11},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84960844769&doi=10.1016%2fj.egypro.2015.11.825&partnerID=40&md5=94f5226b339acd5e43b86f3891ecf3b6},\nabstract={In recent years, the application of plasma actuators in different engineering fields was considered particularly interesting. It was successfully applied for the cold flow control in aero engines and turbo-devices. One important application concerns the use of non-equilibrium plasma for plasma-assisted ignition and combustion control. The reduction of nitric oxides (NOx) in aircraft engines, gas turbines, or internal combustion engines has become a major issue in the development of combustion systems. A way to reduce the NOx emissions is to burn under homogenous lean conditions. However, in these regimes the flame becomes unstable and it leads to incomplete combustion or even extinction. Thus, the major issue becomes to stabilize the flame under lean conditions. In this context the present work aims to demonstrate the possibility to increase the combustion efficiency of a lean flame through the use of nanosecond repetitively pulsed plasma (NRPP). A NRPP produced by electric pulses with amplitude up to 40 kV, pulse rise time lower than 4 ns and repetition rate up to 3.5 kHz has been used to stabilize and improve the efficiency of a lean non premixed methane/air flame in a non-premixed Bunsen-type burner. The burner is optically accessible permitting the imaging acquisitions of the flame region. The flame behavior was acquired using a high rate CCD camera in order to capture the differences between the baseline conditions and the actuated cases. Moreover a post-processing technique showing the jagging of the flame in different conditions was applied to evaluate the changes occurring in presence of plasma actuation in term of flame area weighted respect to the luminosity intensity. It was shown that the plasma significantly allows stabilizing the flame under lean conditions where it would not exist without plasma. © 2015 The Authors. Published by Elsevier Ltd.},\neditor={Rispoli F., de Santoli L., Corsini A.},\npublisher={Elsevier Ltd},\nissn={18766102},\ndocument_type={Conference Paper},\nsource={Scopus},\n}\n\n
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\n In recent years, the application of plasma actuators in different engineering fields was considered particularly interesting. It was successfully applied for the cold flow control in aero engines and turbo-devices. One important application concerns the use of non-equilibrium plasma for plasma-assisted ignition and combustion control. The reduction of nitric oxides (NOx) in aircraft engines, gas turbines, or internal combustion engines has become a major issue in the development of combustion systems. A way to reduce the NOx emissions is to burn under homogenous lean conditions. However, in these regimes the flame becomes unstable and it leads to incomplete combustion or even extinction. Thus, the major issue becomes to stabilize the flame under lean conditions. In this context the present work aims to demonstrate the possibility to increase the combustion efficiency of a lean flame through the use of nanosecond repetitively pulsed plasma (NRPP). A NRPP produced by electric pulses with amplitude up to 40 kV, pulse rise time lower than 4 ns and repetition rate up to 3.5 kHz has been used to stabilize and improve the efficiency of a lean non premixed methane/air flame in a non-premixed Bunsen-type burner. The burner is optically accessible permitting the imaging acquisitions of the flame region. The flame behavior was acquired using a high rate CCD camera in order to capture the differences between the baseline conditions and the actuated cases. Moreover a post-processing technique showing the jagging of the flame in different conditions was applied to evaluate the changes occurring in presence of plasma actuation in term of flame area weighted respect to the luminosity intensity. It was shown that the plasma significantly allows stabilizing the flame under lean conditions where it would not exist without plasma. © 2015 The Authors. Published by Elsevier Ltd.\n
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\n \n\n \n \n \n \n \n \n Liquid crystals order in polymeric microchannels.\n \n \n \n \n\n\n \n Palermo, G.; De Sio, L.; Caputo, R.; Umeton, C.; and Bartolino, R.\n\n\n \n\n\n\n Springer International Publishing, 2015.\n cited By 0\n\n\n\n
\n\n\n\n \n \n \"LiquidPaper\n  \n \n\n \n \n doi\n  \n \n\n \n link\n  \n \n\n bibtex\n \n\n \n  \n \n abstract \n \n\n \n\n \n \n \n \n \n \n \n\n  \n \n \n\n\n\n
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@BOOK{Palermo20151,\nauthor={Palermo, G. and De Sio, L. and Caputo, R. and Umeton, C. and Bartolino, R.},\ntitle={Liquid crystals order in polymeric microchannels},\njournal={Liquid Crystalline Polymers: Volume 2-Processing and Applications},\nyear={2015},\npages={1-14},\ndoi={10.1007/978-3-319-20270-9_1},\nnote={cited By 0},\nurl={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84978194078&doi=10.1007%2f978-3-319-20270-9_1&partnerID=40&md5=22d5d23b20bd756f39016adcc0953afe},\nabstract={Liquid Crystals (LCs), combining optical nonlinearity and self-organizing properties with fluidity and being responsive to a wide variety of stimuli, have reached a key point in their development for photonic applications, for the realization of devices that can be dynamically reconfigurable, widely tunable and ultra-fast controlled. In this chapter, we overview recent advances in obtaining alignment of LCs to be used for photonics applications; in particular, we report on our recent efforts on developing a new generation of LC devices based on isotropic polymeric materials. We have realized an empty polymeric template by etching a periodic liquid crystalline composite material, called POLICRYPS (acronym of POlymer LIquid CRYstal Polymer Slices), which is a nano/micro-composite holographic grating made of slices of almost pure polymer alternated to films of well aligned Nematic Liquid Crystal (NLC). The distinctive features of the realized periodic microstructure enabled aligning several kinds of self-organizing materials, without the need of any kind of surface chemistry or functionalization. © Springer International Publishing Switzerland 2015.},\npublisher={Springer International Publishing},\nisbn={9783319202709; 9783319202693},\ndocument_type={Book Chapter},\nsource={Scopus},\n}\n
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\n Liquid Crystals (LCs), combining optical nonlinearity and self-organizing properties with fluidity and being responsive to a wide variety of stimuli, have reached a key point in their development for photonic applications, for the realization of devices that can be dynamically reconfigurable, widely tunable and ultra-fast controlled. In this chapter, we overview recent advances in obtaining alignment of LCs to be used for photonics applications; in particular, we report on our recent efforts on developing a new generation of LC devices based on isotropic polymeric materials. We have realized an empty polymeric template by etching a periodic liquid crystalline composite material, called POLICRYPS (acronym of POlymer LIquid CRYstal Polymer Slices), which is a nano/micro-composite holographic grating made of slices of almost pure polymer alternated to films of well aligned Nematic Liquid Crystal (NLC). The distinctive features of the realized periodic microstructure enabled aligning several kinds of self-organizing materials, without the need of any kind of surface chemistry or functionalization. © Springer International Publishing Switzerland 2015.\n
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