Combined HREM and HAADF scanning transmission electron microscopy: A powerful tool for investigating structural changes in thermally aged Ceria-Zirconia mixed oxides. Pérez-Omil, A, J., Bernal, S., Calvino, J, J., Herńandez, C, J., Mira, C., Rodríguez-Luque, P, M., Erni, R., Browning, & D, N. Chemistry of Materials, 17(17):4282--4285, Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Ćadiz, Spain, 2005.
Paper abstract bibtex The technique of combined high-resolution transmission electron microscopy (HRTEM) and high-angle annular dark field (HAADF) scanning electron microscopy for structural changes in thermally aged Ceria-Zirconia mixed oxides is investigated. The combined application of HRTEM and HAADF technique has allowed to interpret the superstructure contrasts observed in the HRTEM images of a cycled ceria-zirconia mixed oxide. It was found that the approach offers a powerful tool for characterizing structural rearrangements occurring in the cationic sublattice of these materials. It was also found that the approach allows to detect these structural effects at a nanoscale and earlier stages than those required by macroscopic techniques.
@article{ Perez-Omil2005,
abstract = {The technique of combined high-resolution transmission electron microscopy (HRTEM) and high-angle annular dark field (HAADF) scanning electron microscopy for structural changes in thermally aged Ceria-Zirconia mixed oxides is investigated. The combined application of HRTEM and HAADF technique has allowed to interpret the superstructure contrasts observed in the HRTEM images of a cycled ceria-zirconia mixed oxide. It was found that the approach offers a powerful tool for characterizing structural rearrangements occurring in the cationic sublattice of these materials. It was also found that the approach allows to detect these structural effects at a nanoscale and earlier stages than those required by macroscopic techniques.},
address = {Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Ć{a}diz, Spain},
annote = {Cited By (since 1996): 20
Export Date: 15 January 2013
Source: Scopus
CODEN: CMATE
doi: 10.1021/cm050976g
Language of Original Document: English
Correspondence Address: Calvino, J.J.; Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Ć{a}diz, Spain; email: jose.calvino@uca.es
References: Shelef, M., Graham, G.W., McCabe, R.W., (2002) Catalysis by Ceria and Related Materials, pp. 343-375. , Trovarelli, A., Ed.; Imperial College Press: London; Chapter 10;
Izu, N., Omata, T., Otsuka-Yao-Matsuo, S., (1998) J. Alloys Compd., 270, p. 107;
Baker, R.T., Bernal, S., Blanco, G., Cordon, A.M., Pintado, J.M., Rodríguez-Izquierdo, J.M., Fally, F., Perrichon, V., (1999) Chem. Commun., p. 149;
Fornasiero, P., Moniti, T., Graziani, M., Kaspar, J., Hungria, A.B., Martínez-Arias, A., Conesa, J.C., (2002) Phys. Chem. Chem. Phys., 4, p. 149;
Montini, T., Bañares, M.A., Hickey, N., Di Monte, R., Fornasiero, P., Kaspar, J., Graziani, M., (2004) Phys. Chem. Chem. Phys., 6, p. 1;
Montini, T., Hickey, N., Fornasiero, P., Graziani, M., Bañares, M.A., Martínez-Huerta, M.V., Alessandri, I., Depero, L.E., (2005) Chem. Mater., 17, p. 1157;
Kishimoto, H., Omata, T., Otsuka-Yao-Matsuo, S., Ueda, K., Hosono, H., Kawazoe, H., (2000) J. Alloys Compd., 312, p. 94;
Bernal, S., Botana, F.J., Calvino, J.J., Ĺ{o}pez Cartes, C., Pérez-Omil, J.A., Rodríguez-Izquierdo, J.M., (1998) Ultramicroscopy, 72, p. 135;
Stadelmann, P., (1987) Ultramicroscopy, 21, p. 131;
Kirkland, E.J., (1998) Advanced Computing in Electron Microscopy, , Plenum Press: New York;
Coĺ{o}n, G., Pijolat, M., Valdivieso, F., Vidal, H., Kaspar, J., Fonochio, E., Daturi, M., Bernal, S., (1998) J. Chem. Soc., Faraday Trans., 94, p. 3717;
Vidal, H., Bernal, S., Kaspar, J., Pijolat, M., Perrichon, V., Blanco, G., Pintado, J.M., Fally, F., (1999) Catal. Today, 54, p. 93;
Torng, S., Miyazawa, K., Suzuki, K., Sakuma, T., (1994) Philos. Mag. A, 70, p. 505;
Masui, T., Ozaki, T., Adachi, G., Kang, Z., Eyring, L., (2000) Chem. Lett., 7, p. 240;
Pennycook, S.J., Boatner, A., (1988) Nature, 336, p. 565;
Browning, N.D., Arslan, I., Moeck, P., Topuria, T., (2001) Phys. Status Solidi b, 227, p. 229;
Zhao, H., Guillet, N., Valdivieso, F., Pijolat, M., (2003) Solid State Ionics, 160, p. 317;
Mamontov, E., Brezny, R., Koranne, M., Egami, T., (2003) J. Phys. Chem. B, 107, p. 13007},
author = {Pérez-Omil, J A and Bernal, S and Calvino, J J and Herń{a}ndez, J C and Mira, C and Rodríguez-Luque, M P and Erni, R and Browning, N D},
issn = {08974756 (ISSN)},
journal = {Chemistry of Materials},
keywords = {Age hardening,Ceria-Zirconia mixed oxides,Crystal lattices,Heat treatment,High resolution electron microscopy,High-angle annular dark field (HAADF) scanning ele,Positive ions,Scanning electron microscopy,Sublattices,Thermal ageign,Zirconia},
number = {17},
pages = {4282--4285},
title = {{Combined HREM and HAADF scanning transmission electron microscopy: A powerful tool for investigating structural changes in thermally aged Ceria-Zirconia mixed oxides}},
url = {https://www.scopus.com/inward/record.url?eid=2-s2.0-24944496885\&partnerID=40\&md5=b0a8ec860259046c6e39ce4a7f28040e},
volume = {17},
year = {2005}
}
Downloads: 0
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The combined application of HRTEM and HAADF technique has allowed to interpret the superstructure contrasts observed in the HRTEM images of a cycled ceria-zirconia mixed oxide. It was found that the approach offers a powerful tool for characterizing structural rearrangements occurring in the cationic sublattice of these materials. It was also found that the approach allows to detect these structural effects at a nanoscale and earlier stages than those required by macroscopic techniques.},\n address = {Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Ć{a}diz, Spain},\n annote = {Cited By (since 1996): 20\n\n \nExport Date: 15 January 2013\n\n \nSource: Scopus\n\n \nCODEN: CMATE\n\n \ndoi: 10.1021/cm050976g\n\n \nLanguage of Original Document: English\n\n \nCorrespondence Address: Calvino, J.J.; Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Ć{a}diz, Spain; email: jose.calvino@uca.es\n\n \nReferences: Shelef, M., Graham, G.W., McCabe, R.W., (2002) Catalysis by Ceria and Related Materials, pp. 343-375. , Trovarelli, A., Ed.; Imperial College Press: London; Chapter 10; \nIzu, N., Omata, T., Otsuka-Yao-Matsuo, S., (1998) J. Alloys Compd., 270, p. 107; \nBaker, R.T., Bernal, S., Blanco, G., Cordon, A.M., Pintado, J.M., Rodríguez-Izquierdo, J.M., Fally, F., Perrichon, V., (1999) Chem. Commun., p. 149; \nFornasiero, P., Moniti, T., Graziani, M., Kaspar, J., Hungria, A.B., Martínez-Arias, A., Conesa, J.C., (2002) Phys. Chem. Chem. Phys., 4, p. 149; \nMontini, T., Bañares, M.A., Hickey, N., Di Monte, R., Fornasiero, P., Kaspar, J., Graziani, M., (2004) Phys. Chem. Chem. Phys., 6, p. 1; \nMontini, T., Hickey, N., Fornasiero, P., Graziani, M., Bañares, M.A., Martínez-Huerta, M.V., Alessandri, I., Depero, L.E., (2005) Chem. Mater., 17, p. 1157; \nKishimoto, H., Omata, T., Otsuka-Yao-Matsuo, S., Ueda, K., Hosono, H., Kawazoe, H., (2000) J. Alloys Compd., 312, p. 94; \nBernal, S., Botana, F.J., Calvino, J.J., Ĺ{o}pez Cartes, C., Pérez-Omil, J.A., Rodríguez-Izquierdo, J.M., (1998) Ultramicroscopy, 72, p. 135; \nStadelmann, P., (1987) Ultramicroscopy, 21, p. 131; \nKirkland, E.J., (1998) Advanced Computing in Electron Microscopy, , Plenum Press: New York; \nCoĺ{o}n, G., Pijolat, M., Valdivieso, F., Vidal, H., Kaspar, J., Fonochio, E., Daturi, M., Bernal, S., (1998) J. Chem. Soc., Faraday Trans., 94, p. 3717; \nVidal, H., Bernal, S., Kaspar, J., Pijolat, M., Perrichon, V., Blanco, G., Pintado, J.M., Fally, F., (1999) Catal. Today, 54, p. 93; \nTorng, S., Miyazawa, K., Suzuki, K., Sakuma, T., (1994) Philos. Mag. A, 70, p. 505; \nMasui, T., Ozaki, T., Adachi, G., Kang, Z., Eyring, L., (2000) Chem. Lett., 7, p. 240; \nPennycook, S.J., Boatner, A., (1988) Nature, 336, p. 565; \nBrowning, N.D., Arslan, I., Moeck, P., Topuria, T., (2001) Phys. Status Solidi b, 227, p. 229; \nZhao, H., Guillet, N., Valdivieso, F., Pijolat, M., (2003) Solid State Ionics, 160, p. 317; \nMamontov, E., Brezny, R., Koranne, M., Egami, T., (2003) J. Phys. Chem. B, 107, p. 13007},\n author = {Pérez-Omil, J A and Bernal, S and Calvino, J J and Herń{a}ndez, J C and Mira, C and Rodríguez-Luque, M P and Erni, R and Browning, N D},\n issn = {08974756 (ISSN)},\n journal = {Chemistry of Materials},\n keywords = {Age hardening,Ceria-Zirconia mixed oxides,Crystal lattices,Heat treatment,High resolution electron microscopy,High-angle annular dark field (HAADF) scanning ele,Positive ions,Scanning electron microscopy,Sublattices,Thermal ageign,Zirconia},\n number = {17},\n pages = {4282--4285},\n title = {{Combined HREM and HAADF scanning transmission electron microscopy: A powerful tool for investigating structural changes in thermally aged Ceria-Zirconia mixed oxides}},\n url = {https://www.scopus.com/inward/record.url?eid=2-s2.0-24944496885\\&partnerID=40\\&md5=b0a8ec860259046c6e39ce4a7f28040e},\n volume = {17},\n year = {2005}\n}</pre>\n</div>\n\n\n<div class=\"well well-small bibbase\" id=\"abstract_Perez_Omil2005\"\n style=\"display:none\">\n The technique of combined high-resolution transmission electron microscopy (HRTEM) and high-angle annular dark field (HAADF) scanning electron microscopy for structural changes in thermally aged Ceria-Zirconia mixed oxides is investigated. The combined application of HRTEM and HAADF technique has allowed to interpret the superstructure contrasts observed in the HRTEM images of a cycled ceria-zirconia mixed oxide. It was found that the approach offers a powerful tool for characterizing structural rearrangements occurring in the cationic sublattice of these materials. It was also found that the approach allows to detect these structural effects at a nanoscale and earlier stages than those required by macroscopic techniques.\n</div>\n\n\n</div>\n","downloads":0,"keyword":["Age hardening","Ceria-Zirconia mixed oxides","Crystal lattices","Heat treatment","High resolution electron microscopy","High-angle annular dark field (HAADF) scanning ele","Positive ions","Scanning electron microscopy","Sublattices","Thermal ageign","Zirconia"],"abstract":"The technique of combined high-resolution transmission electron microscopy (HRTEM) and high-angle annular dark field (HAADF) scanning electron microscopy for structural changes in thermally aged Ceria-Zirconia mixed oxides is investigated. The combined application of HRTEM and HAADF technique has allowed to interpret the superstructure contrasts observed in the HRTEM images of a cycled ceria-zirconia mixed oxide. It was found that the approach offers a powerful tool for characterizing structural rearrangements occurring in the cationic sublattice of these materials. It was also found that the approach allows to detect these structural effects at a nanoscale and earlier stages than those required by macroscopic techniques.","address":"Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Ćadiz, Spain","annote":"Cited By (since 1996): 20 Export Date: 15 January 2013 Source: Scopus CODEN: CMATE doi: 10.1021/cm050976g Language of Original Document: English Correspondence Address: Calvino, J.J.; Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Ćadiz, Spain; email: jose.calvino@uca.es References: Shelef, M., Graham, G.W., McCabe, R.W., (2002) Catalysis by Ceria and Related Materials, pp. 343-375. , Trovarelli, A., Ed.; Imperial College Press: London; Chapter 10; Izu, N., Omata, T., Otsuka-Yao-Matsuo, S., (1998) J. Alloys Compd., 270, p. 107; Baker, R.T., Bernal, S., Blanco, G., Cordon, A.M., Pintado, J.M., Rodríguez-Izquierdo, J.M., Fally, F., Perrichon, V., (1999) Chem. Commun., p. 149; Fornasiero, P., Moniti, T., Graziani, M., Kaspar, J., Hungria, A.B., Martínez-Arias, A., Conesa, J.C., (2002) Phys. Chem. Chem. Phys., 4, p. 149; Montini, T., Bañares, M.A., Hickey, N., Di Monte, R., Fornasiero, P., Kaspar, J., Graziani, M., (2004) Phys. Chem. Chem. Phys., 6, p. 1; Montini, T., Hickey, N., Fornasiero, P., Graziani, M., Bañares, M.A., Martínez-Huerta, M.V., Alessandri, I., Depero, L.E., (2005) Chem. Mater., 17, p. 1157; Kishimoto, H., Omata, T., Otsuka-Yao-Matsuo, S., Ueda, K., Hosono, H., Kawazoe, H., (2000) J. Alloys Compd., 312, p. 94; Bernal, S., Botana, F.J., Calvino, J.J., Ĺopez Cartes, C., Pérez-Omil, J.A., Rodríguez-Izquierdo, J.M., (1998) Ultramicroscopy, 72, p. 135; Stadelmann, P., (1987) Ultramicroscopy, 21, p. 131; Kirkland, E.J., (1998) Advanced Computing in Electron Microscopy, , Plenum Press: New York; Coĺon, G., Pijolat, M., Valdivieso, F., Vidal, H., Kaspar, J., Fonochio, E., Daturi, M., Bernal, S., (1998) J. Chem. Soc., Faraday Trans., 94, p. 3717; Vidal, H., Bernal, S., Kaspar, J., Pijolat, M., Perrichon, V., Blanco, G., Pintado, J.M., Fally, F., (1999) Catal. Today, 54, p. 93; Torng, S., Miyazawa, K., Suzuki, K., Sakuma, T., (1994) Philos. Mag. A, 70, p. 505; Masui, T., Ozaki, T., Adachi, G., Kang, Z., Eyring, L., (2000) Chem. Lett., 7, p. 240; Pennycook, S.J., Boatner, A., (1988) Nature, 336, p. 565; Browning, N.D., Arslan, I., Moeck, P., Topuria, T., (2001) Phys. Status Solidi b, 227, p. 229; Zhao, H., Guillet, N., Valdivieso, F., Pijolat, M., (2003) Solid State Ionics, 160, p. 317; Mamontov, E., Brezny, R., Koranne, M., Egami, T., (2003) J. Phys. Chem. B, 107, p. 13007","author":["Pérez-Omil","A, J","Bernal, S","Calvino","J, J","Herńandez","C, J","Mira, C","Rodríguez-Luque","P, M","Erni, R","Browning","D, N"],"author_short":["Pérez-Omil","A, J.","Bernal, S.","Calvino","J, J.","Herńandez","C, J.","Mira, C.","Rodríguez-Luque","P, M.","Erni, R.","Browning","D, N."],"bibtex":"@article{ Perez-Omil2005,\n abstract = {The technique of combined high-resolution transmission electron microscopy (HRTEM) and high-angle annular dark field (HAADF) scanning electron microscopy for structural changes in thermally aged Ceria-Zirconia mixed oxides is investigated. The combined application of HRTEM and HAADF technique has allowed to interpret the superstructure contrasts observed in the HRTEM images of a cycled ceria-zirconia mixed oxide. It was found that the approach offers a powerful tool for characterizing structural rearrangements occurring in the cationic sublattice of these materials. It was also found that the approach allows to detect these structural effects at a nanoscale and earlier stages than those required by macroscopic techniques.},\n address = {Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Ć{a}diz, Spain},\n annote = {Cited By (since 1996): 20\n\n \nExport Date: 15 January 2013\n\n \nSource: Scopus\n\n \nCODEN: CMATE\n\n \ndoi: 10.1021/cm050976g\n\n \nLanguage of Original Document: English\n\n \nCorrespondence Address: Calvino, J.J.; Departamento de Ciencia de los Maienales e Ingenieria Metalurgica y Quimica Inorganica, Facultad de Ciencias, Campus Puerto Real, 11510 Ć{a}diz, Spain; email: jose.calvino@uca.es\n\n \nReferences: Shelef, M., Graham, G.W., McCabe, R.W., (2002) Catalysis by Ceria and Related Materials, pp. 343-375. , Trovarelli, A., Ed.; Imperial College Press: London; Chapter 10; \nIzu, N., Omata, T., Otsuka-Yao-Matsuo, S., (1998) J. Alloys Compd., 270, p. 107; \nBaker, R.T., Bernal, S., Blanco, G., Cordon, A.M., Pintado, J.M., Rodríguez-Izquierdo, J.M., Fally, F., Perrichon, V., (1999) Chem. Commun., p. 149; \nFornasiero, P., Moniti, T., Graziani, M., Kaspar, J., Hungria, A.B., Martínez-Arias, A., Conesa, J.C., (2002) Phys. Chem. Chem. Phys., 4, p. 149; \nMontini, T., Bañares, M.A., Hickey, N., Di Monte, R., Fornasiero, P., Kaspar, J., Graziani, M., (2004) Phys. Chem. Chem. Phys., 6, p. 1; \nMontini, T., Hickey, N., Fornasiero, P., Graziani, M., Bañares, M.A., Martínez-Huerta, M.V., Alessandri, I., Depero, L.E., (2005) Chem. Mater., 17, p. 1157; \nKishimoto, H., Omata, T., Otsuka-Yao-Matsuo, S., Ueda, K., Hosono, H., Kawazoe, H., (2000) J. Alloys Compd., 312, p. 94; \nBernal, S., Botana, F.J., Calvino, J.J., Ĺ{o}pez Cartes, C., Pérez-Omil, J.A., Rodríguez-Izquierdo, J.M., (1998) Ultramicroscopy, 72, p. 135; \nStadelmann, P., (1987) Ultramicroscopy, 21, p. 131; \nKirkland, E.J., (1998) Advanced Computing in Electron Microscopy, , Plenum Press: New York; \nCoĺ{o}n, G., Pijolat, M., Valdivieso, F., Vidal, H., Kaspar, J., Fonochio, E., Daturi, M., Bernal, S., (1998) J. Chem. Soc., Faraday Trans., 94, p. 3717; \nVidal, H., Bernal, S., Kaspar, J., Pijolat, M., Perrichon, V., Blanco, G., Pintado, J.M., Fally, F., (1999) Catal. Today, 54, p. 93; \nTorng, S., Miyazawa, K., Suzuki, K., Sakuma, T., (1994) Philos. Mag. A, 70, p. 505; \nMasui, T., Ozaki, T., Adachi, G., Kang, Z., Eyring, L., (2000) Chem. Lett., 7, p. 240; \nPennycook, S.J., Boatner, A., (1988) Nature, 336, p. 565; \nBrowning, N.D., Arslan, I., Moeck, P., Topuria, T., (2001) Phys. Status Solidi b, 227, p. 229; \nZhao, H., Guillet, N., Valdivieso, F., Pijolat, M., (2003) Solid State Ionics, 160, p. 317; \nMamontov, E., Brezny, R., Koranne, M., Egami, T., (2003) J. Phys. Chem. B, 107, p. 13007},\n author = {Pérez-Omil, J A and Bernal, S and Calvino, J J and Herń{a}ndez, J C and Mira, C and Rodríguez-Luque, M P and Erni, R and Browning, N D},\n issn = {08974756 (ISSN)},\n journal = {Chemistry of Materials},\n keywords = {Age hardening,Ceria-Zirconia mixed oxides,Crystal lattices,Heat treatment,High resolution electron microscopy,High-angle annular dark field (HAADF) scanning ele,Positive ions,Scanning electron microscopy,Sublattices,Thermal ageign,Zirconia},\n number = {17},\n pages = {4282--4285},\n title = {{Combined HREM and HAADF scanning transmission electron microscopy: A powerful tool for investigating structural changes in thermally aged Ceria-Zirconia mixed oxides}},\n url = {https://www.scopus.com/inward/record.url?eid=2-s2.0-24944496885\\&partnerID=40\\&md5=b0a8ec860259046c6e39ce4a7f28040e},\n volume = {17},\n year = {2005}\n}","bibtype":"article","id":"Perez-Omil2005","issn":"08974756 (ISSN)","journal":"Chemistry of Materials","key":"Perez-Omil2005","keywords":"Age hardening,Ceria-Zirconia mixed oxides,Crystal lattices,Heat treatment,High resolution electron microscopy,High-angle annular dark field (HAADF) scanning ele,Positive ions,Scanning electron microscopy,Sublattices,Thermal ageign,Zirconia","number":"17","pages":"4282--4285","title":"Combined HREM and HAADF scanning transmission electron microscopy: A powerful tool for investigating structural changes in thermally aged Ceria-Zirconia mixed oxides","type":"article","url":"https://www.scopus.com/inward/record.url?eid=2-s2.0-24944496885\\&partnerID=40\\&md5=b0a8ec860259046c6e39ce4a7f28040e","volume":"17","year":"2005","role":"author","urls":{"Paper":"https://www.scopus.com/inward/record.url?eid=2-s2.0-24944496885\\&partnerID=40\\&md5=b0a8ec860259046c6e39ce4a7f28040e"},"bibbaseid":"-a-bernal--j--c-mira--p-erni--d-combinedhremandhaadfscanningtransmissionelectronmicroscopyapowerfultoolforinvestigatingstructuralchangesinthermallyagedceriazirconiamixedoxides-2005"},"bibtype":"article","biburl":"http://www2.uca.es/dept/cmat_qinor/nanomat/People/Calvino2.bib","downloads":0,"search_terms":["combined","hrem","haadf","scanning","transmission","electron","microscopy","powerful","tool","investigating","structural","changes","thermally","aged","ceria","zirconia","mixed","oxides","pérez-omil","a","bernal","calvino","j","herńandez","c","mira","rodríguez-luque","p","erni","browning","d"],"title":"Combined HREM and HAADF scanning transmission electron microscopy: A powerful tool for investigating structural changes in thermally aged Ceria-Zirconia mixed oxides","title_words":["combined","hrem","haadf","scanning","transmission","electron","microscopy","powerful","tool","investigating","structural","changes","thermally","aged","ceria","zirconia","mixed","oxides"],"year":2005,"dataSources":["Qe5Mh2foqdg6ySpWW"]}