A noble-metal-free catalyst derived from Ni-Al hydrotalcite for hydrogen generation from N 2H 4·H 2O decomposition

A noble-metal-free catalyst derived from Ni-Al hydrotalcite for hydrogen generation from N 2H 4·H 2O decomposition. He, b, L., Huang, Y., Wang, A., Wang, X., Chen, X., Delgado, J‥, & Zhang, T. Angewandte Chemie - International Edition, 51(25):6191--6194, 2012.

Paper doi abstract bibtex

Free of nobility: A supported nickel catalyst derived from Ni-Al hydrotalcite is a promising candidate to replace noble metals for hydrogen generation from the catalytic decomposition of N 2H 4·H 2O under ambient conditions. The catalyst produces H 2 at 30 °C in 93 % selectivity. The catalytic function is due to the cooperation of highly dispersed Ni nanoparticles and strong basic sites located nearby. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

@article{ He20126191,
  abstract = {Free of nobility: A supported nickel catalyst derived from Ni-Al hydrotalcite is a promising candidate to replace noble metals for hydrogen generation from the catalytic decomposition of N 2H 4·H 2O under ambient conditions. The catalyst produces H 2 at 30 °C in 93 % selectivity. The catalytic function is due to the cooperation of highly dispersed Ni nanoparticles and strong basic sites located nearby. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.},
  annote = {cited By (since 1996)4},
  author = {He, L.a b and Huang, Y.a and Wang, A.a and Wang, X.a and Chen, X.c and Delgado, J.J.c and Zhang, T.a},
  doi = {10.1002/anie.201201737},
  issn = {14337851},
  journal = {Angewandte Chemie - International Edition},
  keywords = { Alkalinity; Aluminum; Catalysis; Hydrogen production; Hydrogen storage; Precious metals, Catalyst selectivity,Ambient conditions; Basic sites; Catalytic decomposition; Catalytic functions; Dispersed Ni; Hydrazine decomposition; Hydrogen generations; Hydrotalcites; Supported nickel},
  number = {25},
  pages = {6191--6194},
  title = {{A noble-metal-free catalyst derived from Ni-Al hydrotalcite for hydrogen generation from N 2H 4·H 2O decomposition}},
  url = {https://www.scopus.com/inward/record.url?eid=2-s2.0-84862696400\&partnerID=40\&md5=6034caeb76086522552219b8613d3d3c},
  volume = {51},
  year = {2012}
}

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The catalyst produces H 2 at 30 °C in 93 % selectivity. The catalytic function is due to the cooperation of highly dispersed Ni nanoparticles and strong basic sites located nearby. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.},\n annote = {cited By (since 1996)4},\n author = {He, L.a b and Huang, Y.a and Wang, A.a and Wang, X.a and Chen, X.c and Delgado, J.J.c and Zhang, T.a},\n doi = {10.1002/anie.201201737},\n issn = {14337851},\n journal = {Angewandte Chemie - International Edition},\n keywords = { Alkalinity; Aluminum; Catalysis; Hydrogen production; Hydrogen storage; Precious metals, Catalyst selectivity,Ambient conditions; Basic sites; Catalytic decomposition; Catalytic functions; Dispersed Ni; Hydrazine decomposition; Hydrogen generations; Hydrotalcites; Supported nickel},\n number = {25},\n pages = {6191--6194},\n title = {{A noble-metal-free catalyst derived from Ni-Al hydrotalcite for hydrogen generation from N 2H 4·H 2O decomposition}},\n url = {https://www.scopus.com/inward/record.url?eid=2-s2.0-84862696400\\&partnerID=40\\&md5=6034caeb76086522552219b8613d3d3c},\n volume = {51},\n year = {2012}\n}</pre>\n</div>\n\n\n<div class=\"well well-small bibbase\" id=\"abstract_He20126191\"\n style=\"display:none\">\n Free of nobility: A supported nickel catalyst derived from Ni-Al hydrotalcite is a promising candidate to replace noble metals for hydrogen generation from the catalytic decomposition of N 2H 4·H 2O under ambient conditions. The catalyst produces H 2 at 30 °C in 93 % selectivity. The catalytic function is due to the cooperation of highly dispersed Ni nanoparticles and strong basic sites located nearby. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.\n</div>\n\n\n</div>\n","downloads":0,"keyword":["Alkalinity; Aluminum; Catalysis; Hydrogen production; Hydrogen storage; Precious metals","Catalyst selectivity","Ambient conditions; Basic sites; Catalytic decomposition; Catalytic functions; Dispersed Ni; Hydrazine decomposition; Hydrogen generations; Hydrotalcites; Supported nickel"],"abstract":"Free of nobility: A supported nickel catalyst derived from Ni-Al hydrotalcite is a promising candidate to replace noble metals for hydrogen generation from the catalytic decomposition of N 2H 4·H 2O under ambient conditions. The catalyst produces H 2 at 30 °C in 93 % selectivity. The catalytic function is due to the cooperation of highly dispersed Ni nanoparticles and strong basic sites located nearby. 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