Biomass into chemicals: One-pot two- and three-step synthesis of quinoxalines from biomass-derived glycols and 1,2-dinitrobenzene derivatives using supported gold nanoparticles as catalysts. Climent, J, M., Corma, A., Herńandez, C, J., Hungría, B, A., Iborra, S., & Martínez-Silvestre, S. Journal of Catalysis, 292:118--129, Instituto de Tecnología Química (UPV-CSIC), Universitat Politècnica de Valencia, Consejo Superior de Investigaciones Científicas, Avenida de los Naranjos s/n, 46022 Valencia, Spain, 2012.
Biomass into chemicals: One-pot two- and three-step synthesis of quinoxalines from biomass-derived glycols and 1,2-dinitrobenzene derivatives using supported gold nanoparticles as catalysts [link]Paper  abstract   bibtex   
An efficient and selective one-pot two-step method, for the synthesis of quinoxalines by oxidative coupling of vicinal diols with 1,2-phenylenediamine derivatives, has been developed by using gold nanoparticles supported on nanoparticulated ceria (Au/CeO 2) or hydrotalcite (Au/HT) as catalysts and air as oxidant, in the absence of any homogeneous base. Reaction kinetics shows that the reaction controlling step is the oxidation of the diol to $α$-hydroxycarbonyl compound. Furthermore, a one-pot three-step synthesis of 2-methylquinoxaline starting from 1,2-dinitrobenzene and 1,2-propanediol has been successfully carried out with 98% conversion and 83% global yield to the final product. © 2012 Elsevier Ltd. All rights reserved.
@article{ Climent2012,
  abstract = {An efficient and selective one-pot two-step method, for the synthesis of quinoxalines by oxidative coupling of vicinal diols with 1,2-phenylenediamine derivatives, has been developed by using gold nanoparticles supported on nanoparticulated ceria (Au/CeO 2) or hydrotalcite (Au/HT) as catalysts and air as oxidant, in the absence of any homogeneous base. Reaction kinetics shows that the reaction controlling step is the oxidation of the diol to $α$-hydroxycarbonyl compound. Furthermore, a one-pot three-step synthesis of 2-methylquinoxaline starting from 1,2-dinitrobenzene and 1,2-propanediol has been successfully carried out with 98% conversion and 83% global yield to the final product. © 2012 Elsevier Ltd. All rights reserved.},
  address = {Instituto de Tecnología Química (UPV-CSIC), Universitat Politècnica de Valencia, Consejo Superior de Investigaciones Científicas, Avenida de los Naranjos s/n, 46022 Valencia, Spain},
  annote = {Cited By (since 1996): 1

        
Export Date: 15 January 2013

        
Source: Scopus

        
CODEN: JCTLA

        
doi: 10.1016/j.jcat.2012.05.002

        
Language of Original Document: English

        
Correspondence Address: Corma, A.; Instituto de Tecnología Química (UPV-CSIC), Universitat Politècnica de Valencia, Consejo Superior de Investigaciones Científicas, Avenida de los Naranjos s/n, 46022 Valencia, Spain; email: acorma@itq.upv.es

        
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  author = {Climent, M J and Corma, A and Herń{a}ndez, J C and Hungría, A B and Iborra, S and Martínez-Silvestre, S},
  issn = {00219517 (ISSN)},
  journal = {Journal of Catalysis},
  keywords = {1,2-Phenylenediamine,2-Methylquinoxaline,Au/CeO                          2 ,Au/HT,Biomass,Cascade process,Catalysts,Cerium compounds,Diol,Glycols,Heterogeneous catalyst,Metal nanoparticles,Quinoxaline,Quinoxalines,Reaction kinetics},
  pages = {118--129},
  title = {{Biomass into chemicals: One-pot two- and three-step synthesis of quinoxalines from biomass-derived glycols and 1,2-dinitrobenzene derivatives using supported gold nanoparticles as catalysts}},
  url = {https://www.scopus.com/inward/record.url?eid=2-s2.0-84863724897\&partnerID=40\&md5=cd7aca662d2bd4a0f98a285ac2bd67c6},
  volume = {292},
  year = {2012}
}
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