Hückel-like rule of superaromaticity for charged paracyclophanes. Aihara, J. Chemical Physics Letters, 381(1–2):147–153, 2003. ISBN: 0009-2614Paper doi abstract bibtex Paracyclophanes, in which four or more benzene units are linked at the 1,4-positions by ethylene bridges, show annulene characteristics upon charging. It was proved that a Hückel-like rule of superaromaticity holds for molecular ions of these species. Here superaromaticity represents energetic stabilization due to cyclic motion of ��-electrons along the macrocycle. If this type of paracyclophane molecule or any of its closed-shell molecular ions is super-antiaromatic, it will probably become superaromatic either by acquiring two more π-electrons or by losing two π-electrons.
@article{aihara_huckel-like_2003,
title = {Hückel-like rule of superaromaticity for charged paracyclophanes},
volume = {381},
url = {http://www.sciencedirect.com/science/article/pii/S0009261403016890},
doi = {http://dx.doi.org/10.1016/j.cplett.2003.09.114},
abstract = {Paracyclophanes, in which four or more benzene units are linked at the 1,4-positions by ethylene bridges, show annulene characteristics upon charging. It was proved that a Hückel-like rule of superaromaticity holds for molecular ions of these species. Here superaromaticity represents energetic stabilization due to cyclic motion of ��-electrons along the macrocycle. If this type of paracyclophane molecule or any of its closed-shell molecular ions is super-antiaromatic, it will probably become superaromatic either by acquiring two more π-electrons or by losing two π-electrons.},
number = {1–2},
journal = {Chemical Physics Letters},
author = {Aihara, Jun-ichi},
year = {2003},
note = {ISBN: 0009-2614},
pages = {147--153},
}
Downloads: 0
{"_id":"mMDFnpFh7kWi5Pa4C","bibbaseid":"aihara-hckellikeruleofsuperaromaticityforchargedparacyclophanes-2003","author_short":["Aihara, J."],"bibdata":{"bibtype":"article","type":"article","title":"Hückel-like rule of superaromaticity for charged paracyclophanes","volume":"381","url":"http://www.sciencedirect.com/science/article/pii/S0009261403016890","doi":"http://dx.doi.org/10.1016/j.cplett.2003.09.114","abstract":"Paracyclophanes, in which four or more benzene units are linked at the 1,4-positions by ethylene bridges, show annulene characteristics upon charging. It was proved that a Hückel-like rule of superaromaticity holds for molecular ions of these species. Here superaromaticity represents energetic stabilization due to cyclic motion of ��-electrons along the macrocycle. If this type of paracyclophane molecule or any of its closed-shell molecular ions is super-antiaromatic, it will probably become superaromatic either by acquiring two more π-electrons or by losing two π-electrons.","number":"1–2","journal":"Chemical Physics Letters","author":[{"propositions":[],"lastnames":["Aihara"],"firstnames":["Jun-ichi"],"suffixes":[]}],"year":"2003","note":"ISBN: 0009-2614","pages":"147–153","bibtex":"@article{aihara_huckel-like_2003,\n\ttitle = {Hückel-like rule of superaromaticity for charged paracyclophanes},\n\tvolume = {381},\n\turl = {http://www.sciencedirect.com/science/article/pii/S0009261403016890},\n\tdoi = {http://dx.doi.org/10.1016/j.cplett.2003.09.114},\n\tabstract = {Paracyclophanes, in which four or more benzene units are linked at the 1,4-positions by ethylene bridges, show annulene characteristics upon charging. It was proved that a Hückel-like rule of superaromaticity holds for molecular ions of these species. Here superaromaticity represents energetic stabilization due to cyclic motion of ��-electrons along the macrocycle. If this type of paracyclophane molecule or any of its closed-shell molecular ions is super-antiaromatic, it will probably become superaromatic either by acquiring two more π-electrons or by losing two π-electrons.},\n\tnumber = {1–2},\n\tjournal = {Chemical Physics Letters},\n\tauthor = {Aihara, Jun-ichi},\n\tyear = {2003},\n\tnote = {ISBN: 0009-2614},\n\tpages = {147--153},\n}\n\n","author_short":["Aihara, J."],"key":"aihara_huckel-like_2003","id":"aihara_huckel-like_2003","bibbaseid":"aihara-hckellikeruleofsuperaromaticityforchargedparacyclophanes-2003","role":"author","urls":{"Paper":"http://www.sciencedirect.com/science/article/pii/S0009261403016890"},"metadata":{"authorlinks":{}},"html":""},"bibtype":"article","biburl":"https://bibbase.org/zotero/kjelljorner","dataSources":["64RFiGdCa5JLg5kLH"],"keywords":[],"search_terms":["ckel","rule","superaromaticity","charged","paracyclophanes","aihara"],"title":"Hückel-like rule of superaromaticity for charged paracyclophanes","year":2003}