The first stereoselective Pd-catalyzed addition of boronic acids onto aldehydes. Alexandra Novodomskà, Mària Dudičovà, Frédéric R. Leroux, & Françoise Colobert Tetrahedron Asymmetry, 18(13):1628–1634, July, 2007. Paper doi abstract bibtex The coupling reaction between 2-p-tolylsulfinyl benzaldehyde and substituted boronic acids catalyzed by Pd2(dba)3·CHCl3 proceeds in a stereoselective manner, demonstrating the efficiency of the sulfinyl group as a chiral inductor. Enantiopure secondary diaryl alcohols become easily accessible by subsequent sulfoxide–lithium exchange.
@article{alexandra_novodomska_first_2007,
title = {The first stereoselective {Pd}-catalyzed addition of boronic acids onto aldehydes},
volume = {18},
issn = {0957-4166},
url = {https://www.sciencedirect.com/science/article/pii/S0957416607004727},
doi = {10.1016/j.tetasy.2007.06.031},
abstract = {The coupling reaction between 2-p-tolylsulfinyl benzaldehyde and substituted boronic acids catalyzed by Pd2(dba)3·CHCl3 proceeds in a stereoselective manner, demonstrating the efficiency of the sulfinyl group as a chiral inductor. Enantiopure secondary diaryl alcohols become easily accessible by subsequent sulfoxide–lithium exchange.},
number = {13},
journal = {Tetrahedron Asymmetry},
author = {{Alexandra Novodomskà} and {Mària Dudičovà} and {Frédéric R. Leroux} and {Françoise Colobert}},
month = jul,
year = {2007},
pages = {1628--1634},
}
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