@article{angamuthu_electrocatalytic_2010,
	title = {Electrocatalytic {CO}2 {Conversion} to {Oxalate} by a {Copper} {Complex}},
	volume = {327},
	url = {http://www.sciencemag.org/cgi/content/abstract/327/5963/313},
	doi = {10.1126/science.1177981},
	abstract = {Global warming concern has dramatically increased interest in using CO2 as a feedstock for preparation of value-added compounds, thereby helping to reduce its atmospheric concentration. Here, we describe a dinuclear copper(I) complex that is oxidized in air by CO2 rather than O2; the product is a tetranuclear copper(II) complex containing two bridging CO2-derived oxalate groups. Treatment of the copper(II) oxalate complex in acetonitrile with a soluble lithium salt results in quantitative precipitation of lithium oxalate. The copper(II) complex can then be nearly quantitatively electrochemically reduced at a relatively accessible potential, regenerating the initial dinuclear copper(I) compound. Preliminary results demonstrate six turnovers (producing 12 equivalents of oxalate) during 7 hours of catalysis at an applied potential of -0.03 volts versus the normal hydrogen electrode.},
	number = {5963},
	urldate = {2010-02-03TZ},
	journal = {Science},
	author = {Angamuthu, Raja and Byers, Philip and Lutz, Martin and Spek, Anthony L. and Bouwman, Elisabeth},
	month = jan,
	year = {2010},
	note = {Cited by 0060},
	pages = {313--315}
}

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