In operando monitoring of the state of charge and species distribution in zinc air batteries using X-ray tomography and model-based simulations. Arlt, T., Schröder, D., Krewer, U., & Manke, I. Physical Chemistry Chemical Physics, 16(40):22273–22280, 2014. doi abstract bibtex A novel combination of in operando X-ray tomography and model-based analysis of zinc air batteries is introduced. Using this approach the correlation between the three-dimensional morphological properties of the electrode - on the one hand - and the electrochemical properties of the battery - on the other hand is revealed. In detail, chemical dissolution of zinc particles and the electrode volume were investigated non-destructively during battery operation by X-ray tomography (applying a spatial resolution of 9 μm), while simulation yielded cell potentials of each electrode and allows for the prediction of long-term operation behavior. Furthermore, the analysis of individual zinc particles revealed an electrochemical dissolution process that can be explained using an adapted shrinking-core model.
@article{arlt_operando_2014,
title = {In operando monitoring of the state of charge and species distribution in zinc air batteries using {X}-ray tomography and model-based simulations},
volume = {16},
copyright = {All rights reserved},
issn = {14639076},
doi = {10.1039/c4cp02878c},
abstract = {A novel combination of in operando X-ray tomography and model-based analysis of zinc air batteries is introduced. Using this approach the correlation between the three-dimensional morphological properties of the electrode - on the one hand - and the electrochemical properties of the battery - on the other hand is revealed. In detail, chemical dissolution of zinc particles and the electrode volume were investigated non-destructively during battery operation by X-ray tomography (applying a spatial resolution of 9 μm), while simulation yielded cell potentials of each electrode and allows for the prediction of long-term operation behavior. Furthermore, the analysis of individual zinc particles revealed an electrochemical dissolution process that can be explained using an adapted shrinking-core model.},
number = {40},
journal = {Physical Chemistry Chemical Physics},
author = {Arlt, Tobias and Schröder, Daniel and Krewer, Ulrike and Manke, Ingo},
year = {2014},
pmid = {25220061},
pages = {22273--22280},
}
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Using this approach the correlation between the three-dimensional morphological properties of the electrode - on the one hand - and the electrochemical properties of the battery - on the other hand is revealed. In detail, chemical dissolution of zinc particles and the electrode volume were investigated non-destructively during battery operation by X-ray tomography (applying a spatial resolution of 9 μm), while simulation yielded cell potentials of each electrode and allows for the prediction of long-term operation behavior. Furthermore, the analysis of individual zinc particles revealed an electrochemical dissolution process that can be explained using an adapted shrinking-core model.","number":"40","journal":"Physical Chemistry Chemical Physics","author":[{"propositions":[],"lastnames":["Arlt"],"firstnames":["Tobias"],"suffixes":[]},{"propositions":[],"lastnames":["Schröder"],"firstnames":["Daniel"],"suffixes":[]},{"propositions":[],"lastnames":["Krewer"],"firstnames":["Ulrike"],"suffixes":[]},{"propositions":[],"lastnames":["Manke"],"firstnames":["Ingo"],"suffixes":[]}],"year":"2014","pmid":"25220061","pages":"22273–22280","bibtex":"@article{arlt_operando_2014,\n\ttitle = {In operando monitoring of the state of charge and species distribution in zinc air batteries using {X}-ray tomography and model-based simulations},\n\tvolume = {16},\n\tcopyright = {All rights reserved},\n\tissn = {14639076},\n\tdoi = {10.1039/c4cp02878c},\n\tabstract = {A novel combination of in operando X-ray tomography and model-based analysis of zinc air batteries is introduced. Using this approach the correlation between the three-dimensional morphological properties of the electrode - on the one hand - and the electrochemical properties of the battery - on the other hand is revealed. In detail, chemical dissolution of zinc particles and the electrode volume were investigated non-destructively during battery operation by X-ray tomography (applying a spatial resolution of 9 μm), while simulation yielded cell potentials of each electrode and allows for the prediction of long-term operation behavior. 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