PMMA-N,N,N-trimethyl chitosan nanoparticles for fabrication of antibacterial natural rubber latex gloves. Arpornwichanop, T., Polpanich, D., Thiramanas, R., Suteewong, T., & Tangboriboonrat, P. CARBOHYDRATE POLYMERS, 109:1-6, AUG 30, 2014. doi abstract bibtex This paper presents one-pot synthesis of N,N,N-trimethyl chitosan (TMC) stabilized poly(methyl methacrylate) (PMMA) latex particles via the miniemulsion polymerization technique. From H-1 NMR, synthesized TMC contains 52% degree of quaternization. Compared to native biopolymer chitosan, TMC possesses permanently positive charges as well as provides greater antibacterial activity. Combining properties of PMMA and TMC, PMMA-TMC latex nanoparticles (hydrodynamic size approximate to 282 nm) could be used in place of inorganic lubricating powder in fabrication of latex gloves at pH >= 7. After immersing sulphur prevulcanized natural rubber (SPNR) film into 3 wt% of PMMA-TMC latex at pH 7, significant amount of nanoparticles uniformly deposited onto SPNR film was observed under SEM. A number of nanoparticles present on film surface would increase surface roughness of the rubber film and potentially inhibit the bacterial (Escherichia coli and Staphylococcus aureus) growth, which would be useful for fabrication of special gloves with antibacterial property. (c) 2014 Elsevier Ltd. All rights reserved.
@article{ ISI:000336711500001,
Author = {Arpornwichanop, Thanida and Polpanich, Duangporn and Thiramanas,
Raweewan and Suteewong, Teeraporn and Tangboriboonrat, Pramuan},
Title = {{PMMA-N,N,N-trimethyl chitosan nanoparticles for fabrication of
antibacterial natural rubber latex gloves}},
Journal = {{CARBOHYDRATE POLYMERS}},
Year = {{2014}},
Volume = {{109}},
Pages = {{1-6}},
Month = {{AUG 30}},
Abstract = {{This paper presents one-pot synthesis of N,N,N-trimethyl chitosan (TMC)
stabilized poly(methyl methacrylate) (PMMA) latex particles via the
miniemulsion polymerization technique. From H-1 NMR, synthesized TMC
contains 52\% degree of quaternization. Compared to native biopolymer
chitosan, TMC possesses permanently positive charges as well as provides
greater antibacterial activity. Combining properties of PMMA and TMC,
PMMA-TMC latex nanoparticles (hydrodynamic size approximate to 282 nm)
could be used in place of inorganic lubricating powder in fabrication of
latex gloves at pH >= 7. After immersing sulphur prevulcanized natural
rubber (SPNR) film into 3 wt\% of PMMA-TMC latex at pH 7, significant
amount of nanoparticles uniformly deposited onto SPNR film was observed
under SEM. A number of nanoparticles present on film surface would
increase surface roughness of the rubber film and potentially inhibit
the bacterial (Escherichia coli and Staphylococcus aureus) growth, which
would be useful for fabrication of special gloves with antibacterial
property. (c) 2014 Elsevier Ltd. All rights reserved.}},
DOI = {{10.1016/j.carbpol.2014.03.030}},
ISSN = {{0144-8617}},
EISSN = {{1879-1344}},
ResearcherID-Numbers = {{Tangboriboonrat, Pramuan/AAB-1780-2019}},
Unique-ID = {{ISI:000336711500001}},
}
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From H-1 NMR, synthesized TMC contains 52% degree of quaternization. Compared to native biopolymer chitosan, TMC possesses permanently positive charges as well as provides greater antibacterial activity. Combining properties of PMMA and TMC, PMMA-TMC latex nanoparticles (hydrodynamic size approximate to 282 nm) could be used in place of inorganic lubricating powder in fabrication of latex gloves at pH >= 7. After immersing sulphur prevulcanized natural rubber (SPNR) film into 3 wt% of PMMA-TMC latex at pH 7, significant amount of nanoparticles uniformly deposited onto SPNR film was observed under SEM. A number of nanoparticles present on film surface would increase surface roughness of the rubber film and potentially inhibit the bacterial (Escherichia coli and Staphylococcus aureus) growth, which would be useful for fabrication of special gloves with antibacterial property. (c) 2014 Elsevier Ltd. All rights reserved.","doi":"10.1016/j.carbpol.2014.03.030","issn":"0144-8617","eissn":"1879-1344","researcherid-numbers":"Tangboriboonrat, Pramuan/AAB-1780-2019","unique-id":"ISI:000336711500001","bibtex":"@article{ ISI:000336711500001,\nAuthor = {Arpornwichanop, Thanida and Polpanich, Duangporn and Thiramanas,\n Raweewan and Suteewong, Teeraporn and Tangboriboonrat, Pramuan},\nTitle = {{PMMA-N,N,N-trimethyl chitosan nanoparticles for fabrication of\n antibacterial natural rubber latex gloves}},\nJournal = {{CARBOHYDRATE POLYMERS}},\nYear = {{2014}},\nVolume = {{109}},\nPages = {{1-6}},\nMonth = {{AUG 30}},\nAbstract = {{This paper presents one-pot synthesis of N,N,N-trimethyl chitosan (TMC)\n stabilized poly(methyl methacrylate) (PMMA) latex particles via the\n miniemulsion polymerization technique. From H-1 NMR, synthesized TMC\n contains 52\\% degree of quaternization. Compared to native biopolymer\n chitosan, TMC possesses permanently positive charges as well as provides\n greater antibacterial activity. Combining properties of PMMA and TMC,\n PMMA-TMC latex nanoparticles (hydrodynamic size approximate to 282 nm)\n could be used in place of inorganic lubricating powder in fabrication of\n latex gloves at pH >= 7. After immersing sulphur prevulcanized natural\n rubber (SPNR) film into 3 wt\\% of PMMA-TMC latex at pH 7, significant\n amount of nanoparticles uniformly deposited onto SPNR film was observed\n under SEM. A number of nanoparticles present on film surface would\n increase surface roughness of the rubber film and potentially inhibit\n the bacterial (Escherichia coli and Staphylococcus aureus) growth, which\n would be useful for fabrication of special gloves with antibacterial\n property. (c) 2014 Elsevier Ltd. All rights reserved.}},\nDOI = {{10.1016/j.carbpol.2014.03.030}},\nISSN = {{0144-8617}},\nEISSN = {{1879-1344}},\nResearcherID-Numbers = {{Tangboriboonrat, Pramuan/AAB-1780-2019}},\nUnique-ID = {{ISI:000336711500001}},\n}\n\n","author_short":["Arpornwichanop, T.","Polpanich, D.","Thiramanas, R.","Suteewong, T.","Tangboriboonrat, P."],"key":"ISI:000336711500001","id":"ISI:000336711500001","bibbaseid":"arpornwichanop-polpanich-thiramanas-suteewong-tangboriboonrat-pmmannntrimethylchitosannanoparticlesforfabricationofantibacterialnaturalrubberlatexgloves-2014","role":"author","urls":{},"downloads":0},"bibtype":"article","biburl":"http://nanotec.cnr.it/data/nanotec/nanotec-full.bib","creationDate":"2020-04-22T21:25:44.054Z","downloads":0,"keywords":[],"search_terms":["pmma","trimethyl","chitosan","nanoparticles","fabrication","antibacterial","natural","rubber","latex","gloves","arpornwichanop","polpanich","thiramanas","suteewong","tangboriboonrat"],"title":"PMMA-N,N,N-trimethyl chitosan nanoparticles for fabrication of antibacterial natural rubber latex gloves","year":2014,"dataSources":["ZTEbWc6bW5f9DTsjF"]}