UV-Tunable Biobased Pressure-Sensitive Adhesives Containing Piperonyl Methacrylate. Badía, A., Santos, J. I., Agirre, A., Barandiaran, M. J., & Leiza, J. R. ACS Sustainable Chemistry & Engineering, 7(23):19122–19130, December, 2019. Publisher: American Chemical Society
UV-Tunable Biobased Pressure-Sensitive Adhesives Containing Piperonyl Methacrylate [link]Paper  doi  abstract   bibtex   
Novel waterborne pressure-sensitive adhesives (PSAs) with biobased contents up to 71% and UV-light-tunable features have been developed using piperonyl methacrylate (PIPEMA) as a hard monomer. The biobased monomer was synthesized from piperonyl alcohol (derived from black pepper), and its homopolymer was fully characterized. Emulsion polymerization was chosen as a sustainable strategy to copolymerize piperonyl methacrylate together with biobased 2-octyl acrylate to produce high-solid-content latexes for pressure-sensitive adhesive applications. The UV light curing ability of the piperonyl methacrylate moieties in the copolymer backbone yielded PSAs with excellent shear resistance and reasonable adhesive properties (tack and peel).
@article{badia_uv-tunable_2019,
	title = {{UV}-{Tunable} {Biobased} {Pressure}-{Sensitive} {Adhesives} {Containing} {Piperonyl} {Methacrylate}},
	volume = {7},
	url = {https://doi.org/10.1021/acssuschemeng.9b05067},
	doi = {10.1021/acssuschemeng.9b05067},
	abstract = {Novel waterborne pressure-sensitive adhesives (PSAs) with biobased contents up to 71\% and UV-light-tunable features have been developed using piperonyl methacrylate (PIPEMA) as a hard monomer. The biobased monomer was synthesized from piperonyl alcohol (derived from black pepper), and its homopolymer was fully characterized. Emulsion polymerization was chosen as a sustainable strategy to copolymerize piperonyl methacrylate together with biobased 2-octyl acrylate to produce high-solid-content latexes for pressure-sensitive adhesive applications. The UV light curing ability of the piperonyl methacrylate moieties in the copolymer backbone yielded PSAs with excellent shear resistance and reasonable adhesive properties (tack and peel).},
	number = {23},
	urldate = {2022-08-15},
	journal = {ACS Sustainable Chemistry \& Engineering},
	author = {Badía, Adrián and Santos, José I. and Agirre, Amaia and Barandiaran, María J. and Leiza, Jose R.},
	month = dec,
	year = {2019},
	note = {Publisher: American Chemical Society},
	pages = {19122--19130},
}

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