The kinetics and mechanism of the reaction of the oxidation of aminothiols by hydrogen peroxide in aqueous solutions. Bagiyan, G., Grachev, S., Koroleva, I., & Soroka, N. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 25(5):966-971, Kluwer Academic Publishers-Plenum Publishers, 1976. cited By 1
Paper doi abstract bibtex 1. A study was made of the interaction of aminothiols (AT) with H 2 O 2 , as affected by the acidity of the medium, the temperature, the ionic strength of the solution, and the structure of the AT; the reacting particles were the thiolate anion and the molecular form of hydrogen peroxide. 2. The reaction was promoted by hydrogen bonding between the OH - group splitting off and the amino group of the AT, and by the attraction between the OH - group and the positively charged end of the zwitterion form of the AT. 3. Intermolecular hydrogen bonding and the electrostatic effect introduced equal contributions to the activation of the reaction. © 1976 Plenum Publishing Corporation.
@ARTICLE{Bagiyan1976966,
author={Bagiyan, G.A. and Grachev, S.A. and Koroleva, I.K. and Soroka, N.V.},
title={The kinetics and mechanism of the reaction of the oxidation of aminothiols by hydrogen peroxide in aqueous solutions},
journal={Bulletin of the Academy of Sciences of the USSR Division of Chemical Science},
year={1976},
volume={25},
number={5},
pages={966-971},
doi={10.1007/BF00921973},
note={cited By 1},
url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-0344653256&doi=10.1007%2fBF00921973&partnerID=40&md5=aa38555dc411cba3964c2bb6aa87c5ee},
affiliation={B. P. Konstantin Institute of Nuclear Physics, Leningrad, Russian Federation; The Academy of Sciences of the USSR, Gatchina, Russian Federation},
abstract={1. A study was made of the interaction of aminothiols (AT) with H 2 O 2 , as affected by the acidity of the medium, the temperature, the ionic strength of the solution, and the structure of the AT; the reacting particles were the thiolate anion and the molecular form of hydrogen peroxide. 2. The reaction was promoted by hydrogen bonding between the OH - group splitting off and the amino group of the AT, and by the attraction between the OH - group and the positively charged end of the zwitterion form of the AT. 3. Intermolecular hydrogen bonding and the electrostatic effect introduced equal contributions to the activation of the reaction. © 1976 Plenum Publishing Corporation.},
correspondence_address1={Bagiyan, G.A.; B. P. Konstantin Institute of Nuclear Physics, Leningrad, Russian Federation},
publisher={Kluwer Academic Publishers-Plenum Publishers},
issn={05685230},
language={English},
abbrev_source_title={Russ Chem Bull},
document_type={Article},
source={Scopus},
}
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