Rubidium pure long-range ion-pair molecules. Ban, T., Beuc, R., Skenderović, H., & Pichler, G. Europhysics Letters (EPL), 66(4):485-491, 2004. Website abstract bibtex The Rb$\$n 2 ion-pair satellite band located in the blue wing of the rubidium second resonance doublet line was observed in the absorption measurements of a dense rubidium vapor. The observed satellite band was identified as a long-range ion-pair state, by using the Rb$\$n 2 long-range potential curves based on ab initio calculations. In order to perform the semiclassical spectral simulations of the observed satellite band, the relevant Rb$\$n 2 long-range potential curves and corresponding molecular dipole oscillator strengths were calculated using the asymptotic method. The importance of the observed satellite band (long-range ion-pair state) is discussed in connection with the formation of Rb$\$n 2 ultracold molecules.
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abstract = {The Rb$\$n 2 ion-pair satellite band located in the blue wing of the rubidium second resonance doublet line was observed in the absorption measurements of a dense rubidium vapor. The observed satellite band was identified as a long-range ion-pair state, by using the Rb$\$n 2 long-range potential curves based on ab initio calculations. In order to perform the semiclassical spectral simulations of the observed satellite band, the relevant Rb$\$n 2 long-range potential curves and corresponding molecular dipole oscillator strengths were calculated using the asymptotic method. The importance of the observed satellite band (long-range ion-pair state) is discussed in connection with the formation of Rb$\$n 2 ultracold molecules.},
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author = {Ban, Ticijana and Beuc, Robert and Skenderović, Hrvoje and Pichler, Goran},
journal = {Europhysics Letters (EPL)},
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