A Calcium Coordination Framework Having Permanent Porosity and High CO $_{\textrm{2}}$ /N $_{\textrm{2}}$ Selectivity. Banerjee, D., Zhang, Z., Plonka, A. M., Li, J., & Parise, J. B. Crystal Growth & Design, 12(5):2162–2165, May, 2012. ![A Calcium Coordination Framework Having Permanent Porosity and High CO $_{\textrm{2}}$ /N $_{\textrm{2}}$ Selectivity [link]](https://bibbase.org/img/filetypes/link.svg "link")
Paper doi abstract bibtex A thermally stable, microporous calcium coordination network shows a reversible 5.75 wt % CO2 uptake at 273 K and 1 atm pressure, with an enthalpy of interaction of ∼31 kJ/mol and a CO2/N2 selectivity over 45 under ideal flue gas conditions. The absence of open metal sites in the activated material suggests a different mechanism for selectivity and high interaction energy compared to those for frameworks with open metal sites.
@article{banerjee_calcium_2012,
title = {A {Calcium} {Coordination} {Framework} {Having} {Permanent} {Porosity} and {High} {CO} $_{\textrm{2}}$ /{N} $_{\textrm{2}}$ {Selectivity}},
volume = {12},
issn = {1528-7483, 1528-7505},
url = {https://pubs.acs.org/doi/10.1021/cg300274n},
doi = {10.1021/cg300274n},
abstract = {A thermally stable, microporous calcium coordination network shows a reversible 5.75 wt \% CO2 uptake at 273 K and 1 atm pressure, with an enthalpy of interaction of ∼31 kJ/mol and a CO2/N2 selectivity over 45 under ideal flue gas conditions. The absence of open metal sites in the activated material suggests a different mechanism for selectivity and high interaction energy compared to those for frameworks with open metal sites.},
language = {en},
number = {5},
urldate = {2020-02-04},
journal = {Crystal Growth \& Design},
author = {Banerjee, Debasis and Zhang, Zhijuan and Plonka, Anna M. and Li, Jing and Parise, John B.},
month = may,
year = {2012},
pages = {2162--2165},
}
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