Evaluation of flurbiprofen removal from aqueous solution by electrosynthesized ferrate(VI) ion and electrocoagulation process. Barisci, S., Ulu, F., Sillanpaa, M., & Dimoglo, A. CHEMICAL ENGINEERING JOURNAL, 262:1218-1225, 2015. abstract bibtex The removal of flurbiprofen (FLU) by electrosynthesized ferrate(VI) ion
and electrocoagulation (EC) process was investigated. The degradation of
FLU by ferrate(VI) was affected by pH, applied ferrate(VI) dose and
initial drug concentration. Complete removal of FLU was achieved at pH 4
and applied ferrate(VI) dose was 1/1 in volume ratio for its initial
concentration of 1 mg/L. Removal decreased with increasing pH.
Increasing the ferrate(VI) dose increased the efficiency, but there was
no significant difference between 3/1 and 1/1 (v/v) ferrate(VI) doses
for FLU removal. The effect of current density and pH for the removal of
FLU by EC process were investigated. The optimum conditions were current
density of 2.5 mA/cm(2) and the solution pH of 6.5. Basic condition (pH
9) showed poor removal efficiency by EC process. Equilibrium
concentration was reached within 20 min. TOC removal trends were also
investigated for both process. While oxidation was the main mechanism
for the removal of FLU by ferrate(VI), charge neutralization was the
main removal mechanism by EC process. (C) 2014 Elsevier B.V. All rights
reserved.
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title = {Evaluation of flurbiprofen removal from aqueous solution by electrosynthesized ferrate(VI) ion and electrocoagulation process},
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year = {2015},
identifiers = {[object Object]},
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abstract = {The removal of flurbiprofen (FLU) by electrosynthesized ferrate(VI) ion
and electrocoagulation (EC) process was investigated. The degradation of
FLU by ferrate(VI) was affected by pH, applied ferrate(VI) dose and
initial drug concentration. Complete removal of FLU was achieved at pH 4
and applied ferrate(VI) dose was 1/1 in volume ratio for its initial
concentration of 1 mg/L. Removal decreased with increasing pH.
Increasing the ferrate(VI) dose increased the efficiency, but there was
no significant difference between 3/1 and 1/1 (v/v) ferrate(VI) doses
for FLU removal. The effect of current density and pH for the removal of
FLU by EC process were investigated. The optimum conditions were current
density of 2.5 mA/cm(2) and the solution pH of 6.5. Basic condition (pH
9) showed poor removal efficiency by EC process. Equilibrium
concentration was reached within 20 min. TOC removal trends were also
investigated for both process. While oxidation was the main mechanism
for the removal of FLU by ferrate(VI), charge neutralization was the
main removal mechanism by EC process. (C) 2014 Elsevier B.V. All rights
reserved.},
bibtype = {article},
author = {Barisci, Sibel and Ulu, Feride and Sillanpaa, Mika and Dimoglo, Anatholy},
journal = {CHEMICAL ENGINEERING JOURNAL}
}
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