Synthesis and characterization of tributyltin(IV) complexes of 2-[(E)-2-(3-formyl-4-hydroxyphenyl)-1-diazenyl]benzoic acid and 4-[((E)-1-\2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1-diazenyl]phenyl\methylidene) amino]aryls - Crystal structures of polymeric (Bu. Baul, T. S. B., Singh, K. S., Song, X., Zapata, A., Eng, G., Lycka, A., & Linden, A. Journal of Organometallic Chemistry, 689(25 SPEC. ISS.):4702–4711, 2004. doi abstract bibtex The tri-n-butyltin(IV) complexes of 2-[(E)-2-(3-formyl-4-hydroxyphenyl)-1- diazenyl]benzoic acid and 4-[((E)-1-\2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1- diazenyl]phenyl\methylidene)amino]aryls (aryls = 4-CH3, 4-Br, 4-Cl, 4-OCH3) have been synthesized and characterized by 1H, 13C, 119Sn NMR, IR and 119mSn Mössbauer spectroscopic techniques in combination with elemental analysis. The crystal structures of two compounds, (Bu3Sn[O2CC6H 4\NN(C6H3-4-OH-5-CHO)\-o])n and (Bu3Sn[O2CC6H4\NN(C 6H3-4-OH(C(H)NC6H4Cl-4))\-o]) n, are reported.The crystallographic and 119Sn Mössbauer data both indicate that the tributyltin complexes form single-stranded polymeric structures in which the carboxylate O atoms of each aryl ligand bridge two Sn atoms. The Sn atoms have a slighly distorted trigonal bipyramidal coordination geometry with equatorial butyl groups and carboxylate O atoms occupying axial positions. The 119Sn NMR spectroscopic data and the 1J(13C-119/117Sn) coupling constant indicate a tetrahedral coordination geometry in non-coordinating solvents. The results of a toxicity study of a tributyltin compound on the second larval instar of Aedes aegypti mosquito larvae are reported. © 2004 Elsevier B.V. All rights reserved.
@article{baul_synthesis_2004,
title = {Synthesis and characterization of tributyltin({IV}) complexes of 2-[({E})-2-(3-formyl-4-hydroxyphenyl)-1-diazenyl]benzoic acid and 4-[(({E})-1-\{2-hydroxy-5-[({E})-2-(2-carboxyphenyl)-1-diazenyl]phenyl\}methylidene) amino]aryls - {Crystal} structures of polymeric ({Bu}},
volume = {689},
issn = {0022328X},
doi = {10.1016/j.jorganchem.2004.08.038},
abstract = {The tri-n-butyltin(IV) complexes of 2-[(E)-2-(3-formyl-4-hydroxyphenyl)-1- diazenyl]benzoic acid and 4-[((E)-1-\{2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1- diazenyl]phenyl\}methylidene)amino]aryls (aryls = 4-CH3, 4-Br, 4-Cl, 4-OCH3) have been synthesized and characterized by 1H, 13C, 119Sn NMR, IR and 119mSn Mössbauer spectroscopic techniques in combination with elemental analysis. The crystal structures of two compounds, (Bu3Sn[O2CC6H 4\{NN(C6H3-4-OH-5-CHO)\}-o])n and (Bu3Sn[O2CC6H4\{NN(C 6H3-4-OH(C(H)NC6H4Cl-4))\}-o]) n, are reported.The crystallographic and 119Sn Mössbauer data both indicate that the tributyltin complexes form single-stranded polymeric structures in which the carboxylate O atoms of each aryl ligand bridge two Sn atoms. The Sn atoms have a slighly distorted trigonal bipyramidal coordination geometry with equatorial butyl groups and carboxylate O atoms occupying axial positions. The 119Sn NMR spectroscopic data and the 1J(13C-119/117Sn) coupling constant indicate a tetrahedral coordination geometry in non-coordinating solvents. The results of a toxicity study of a tributyltin compound on the second larval instar of Aedes aegypti mosquito larvae are reported. © 2004 Elsevier B.V. All rights reserved.},
number = {25 SPEC. ISS.},
journal = {Journal of Organometallic Chemistry},
author = {Baul, Tushar S. Basu and Singh, Keisham Surjit and Song, Xueqing and Zapata, Alejandra and Eng, George and Lycka, Antonin and Linden, Anthony},
year = {2004},
keywords = {2-[(E)-2-(3-formyl-4-hydroxyphenyl)-1-diazenyl] be, 4-[((E)-1-\{\vphantom{\}}2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1-, Carboxylates, Crystal structure, Mössbauer, NMR, Toxicity study, Tributyltin},
pages = {4702--4711},
}
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S.","Song, X.","Zapata, A.","Eng, G.","Lycka, A.","Linden, A."],"bibdata":{"bibtype":"article","type":"article","title":"Synthesis and characterization of tributyltin(IV) complexes of 2-[(E)-2-(3-formyl-4-hydroxyphenyl)-1-diazenyl]benzoic acid and 4-[((E)-1-\\2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1-diazenyl]phenyl\\methylidene) amino]aryls - Crystal structures of polymeric (Bu","volume":"689","issn":"0022328X","doi":"10.1016/j.jorganchem.2004.08.038","abstract":"The tri-n-butyltin(IV) complexes of 2-[(E)-2-(3-formyl-4-hydroxyphenyl)-1- diazenyl]benzoic acid and 4-[((E)-1-\\2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1- diazenyl]phenyl\\methylidene)amino]aryls (aryls = 4-CH3, 4-Br, 4-Cl, 4-OCH3) have been synthesized and characterized by 1H, 13C, 119Sn NMR, IR and 119mSn Mössbauer spectroscopic techniques in combination with elemental analysis. The crystal structures of two compounds, (Bu3Sn[O2CC6H 4\\NN(C6H3-4-OH-5-CHO)\\-o])n and (Bu3Sn[O2CC6H4\\NN(C 6H3-4-OH(C(H)NC6H4Cl-4))\\-o]) n, are reported.The crystallographic and 119Sn Mössbauer data both indicate that the tributyltin complexes form single-stranded polymeric structures in which the carboxylate O atoms of each aryl ligand bridge two Sn atoms. The Sn atoms have a slighly distorted trigonal bipyramidal coordination geometry with equatorial butyl groups and carboxylate O atoms occupying axial positions. The 119Sn NMR spectroscopic data and the 1J(13C-119/117Sn) coupling constant indicate a tetrahedral coordination geometry in non-coordinating solvents. The results of a toxicity study of a tributyltin compound on the second larval instar of Aedes aegypti mosquito larvae are reported. © 2004 Elsevier B.V. All rights reserved.","number":"25 SPEC. ISS.","journal":"Journal of Organometallic Chemistry","author":[{"propositions":[],"lastnames":["Baul"],"firstnames":["Tushar","S.","Basu"],"suffixes":[]},{"propositions":[],"lastnames":["Singh"],"firstnames":["Keisham","Surjit"],"suffixes":[]},{"propositions":[],"lastnames":["Song"],"firstnames":["Xueqing"],"suffixes":[]},{"propositions":[],"lastnames":["Zapata"],"firstnames":["Alejandra"],"suffixes":[]},{"propositions":[],"lastnames":["Eng"],"firstnames":["George"],"suffixes":[]},{"propositions":[],"lastnames":["Lycka"],"firstnames":["Antonin"],"suffixes":[]},{"propositions":[],"lastnames":["Linden"],"firstnames":["Anthony"],"suffixes":[]}],"year":"2004","keywords":"2-[(E)-2-(3-formyl-4-hydroxyphenyl)-1-diazenyl] be, 4-[((E)-1-\\p̌hantom\\2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1-, Carboxylates, Crystal structure, Mössbauer, NMR, Toxicity study, Tributyltin","pages":"4702–4711","bibtex":"@article{baul_synthesis_2004,\n\ttitle = {Synthesis and characterization of tributyltin({IV}) complexes of 2-[({E})-2-(3-formyl-4-hydroxyphenyl)-1-diazenyl]benzoic acid and 4-[(({E})-1-\\{2-hydroxy-5-[({E})-2-(2-carboxyphenyl)-1-diazenyl]phenyl\\}methylidene) amino]aryls - {Crystal} structures of polymeric ({Bu}},\n\tvolume = {689},\n\tissn = {0022328X},\n\tdoi = {10.1016/j.jorganchem.2004.08.038},\n\tabstract = {The tri-n-butyltin(IV) complexes of 2-[(E)-2-(3-formyl-4-hydroxyphenyl)-1- diazenyl]benzoic acid and 4-[((E)-1-\\{2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1- diazenyl]phenyl\\}methylidene)amino]aryls (aryls = 4-CH3, 4-Br, 4-Cl, 4-OCH3) have been synthesized and characterized by 1H, 13C, 119Sn NMR, IR and 119mSn Mössbauer spectroscopic techniques in combination with elemental analysis. The crystal structures of two compounds, (Bu3Sn[O2CC6H 4\\{NN(C6H3-4-OH-5-CHO)\\}-o])n and (Bu3Sn[O2CC6H4\\{NN(C 6H3-4-OH(C(H)NC6H4Cl-4))\\}-o]) n, are reported.The crystallographic and 119Sn Mössbauer data both indicate that the tributyltin complexes form single-stranded polymeric structures in which the carboxylate O atoms of each aryl ligand bridge two Sn atoms. The Sn atoms have a slighly distorted trigonal bipyramidal coordination geometry with equatorial butyl groups and carboxylate O atoms occupying axial positions. The 119Sn NMR spectroscopic data and the 1J(13C-119/117Sn) coupling constant indicate a tetrahedral coordination geometry in non-coordinating solvents. The results of a toxicity study of a tributyltin compound on the second larval instar of Aedes aegypti mosquito larvae are reported. © 2004 Elsevier B.V. All rights reserved.},\n\tnumber = {25 SPEC. ISS.},\n\tjournal = {Journal of Organometallic Chemistry},\n\tauthor = {Baul, Tushar S. 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