@article{
 title = {Crystal structure and magnetic properties of Co7(TeO3)4Br6—a new cobalt tellurite bromide},
 type = {article},
 year = {2006},
 identifiers = {[object Object]},
 keywords = {Antiferromagnetic,Cobalt,Ferromagnetic,Magnetic ordering,Oxohalide,Stereochemically active lone pair},
 pages = {836-842},
 volume = {8},
 websites = {http://linkinghub.elsevier.com/retrieve/pii/S1293255806001282},
 month = {7},
 id = {dcef78d1-9f99-31a6-b87c-e483eafaf126},
 created = {2016-12-14T15:29:04.000Z},
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 last_modified = {2016-12-19T13:12:07.000Z},
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 authored = {false},
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 citation_key = {Becker2006},
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 abstract = {The crystal structure of the new compound Co7(TeO3)4Br6 is described together with the magnetic properties. The new compound crystallizes in the monoclinic space group C2/c with the unit cell parameters a=20.6532(5) Å, b=8.6533(2) Å, c=14.7262(5) Å, β=124.897(3)°, Z=4. The crystal structure was solved from single crystal data, R=0.0242. The structure can be considered as layered and the building units are [CoO4Br2] and [CoO2Br4] octahedra and [TeO3E] tetrahedra, E being the 5s2 lone pair on the Te(IV) ions. The magnetic properties of the compound are characterised by antiferromagnetic correlations at high temperatures, strong deviation from the Curie–Weiss behaviour in a broad intermediate temperature range and long range magnetic ordering setting-in at low temperatures. Magnetic ordering takes place in stages, being represented by two susceptibility anomalies, at TN=33 K and TC=27 K. The magnetic transition at TC is ferromagnetic (or ferrimagnetic) in character.},
 bibtype = {article},
 author = {Becker, Richard and Johnsson, Mats and Berger, Helmuth and Prester, Mladen and Zivkovic, Ivica and Drobac, Djuro and Miljak, Marko and Herak, Mirta},
 journal = {Solid State Sciences},
 number = {7}
}

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The new compound crystallizes in the monoclinic space group C2/c with the unit cell parameters a=20.6532(5) Å, b=8.6533(2) Å, c=14.7262(5) Å, β=124.897(3)°, Z=4. The crystal structure was solved from single crystal data, R=0.0242. The structure can be considered as layered and the building units are [CoO4Br2] and [CoO2Br4] octahedra and [TeO3E] tetrahedra, E being the 5s2 lone pair on the Te(IV) ions. The magnetic properties of the compound are characterised by antiferromagnetic correlations at high temperatures, strong deviation from the Curie–Weiss behaviour in a broad intermediate temperature range and long range magnetic ordering setting-in at low temperatures. Magnetic ordering takes place in stages, being represented by two susceptibility anomalies, at TN=33 K and TC=27 K. The magnetic transition at TC is ferromagnetic (or ferrimagnetic) in character.","bibtype":"article","author":"Becker, Richard and Johnsson, Mats and Berger, Helmuth and Prester, Mladen and Zivkovic, Ivica and Drobac, Djuro and Miljak, Marko and Herak, Mirta","journal":"Solid State Sciences","number":"7","bibtex":"@article{\n title = {Crystal structure and magnetic properties of Co7(TeO3)4Br6—a new cobalt tellurite bromide},\n type = {article},\n year = {2006},\n identifiers = {[object Object]},\n keywords = {Antiferromagnetic,Cobalt,Ferromagnetic,Magnetic ordering,Oxohalide,Stereochemically active lone pair},\n pages = {836-842},\n volume = {8},\n websites = {http://linkinghub.elsevier.com/retrieve/pii/S1293255806001282},\n month = {7},\n id = {dcef78d1-9f99-31a6-b87c-e483eafaf126},\n created = {2016-12-14T15:29:04.000Z},\n file_attached = {false},\n profile_id = {12182ba0-f80b-33ff-8da5-1813b38b682d},\n group_id = {a98b63fd-d1ec-31d9-941c-369676d9ff02},\n last_modified = {2016-12-19T13:12:07.000Z},\n read = {false},\n starred = {false},\n authored = {false},\n confirmed = {true},\n hidden = {false},\n citation_key = {Becker2006},\n source_type = {article},\n abstract = {The crystal structure of the new compound Co7(TeO3)4Br6 is described together with the magnetic properties. 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