@article{beckmann_formation_2008,
	title = {Formation of stoichiometrically {18O}-labelled oxygen from the oxidation of {18O}-enriched water mediated by a dinuclear manganese complex—a mass spectrometry and {EPR} study},
	volume = {1},
	issn = {1754-5706},
	url = {https://pubs.rsc.org/en/content/articlelanding/2008/ee/b811806j},
	doi = {10.1039/B811806J},
	abstract = {Oxygen formation was detected for the oxidations of various multinuclear manganese complexes by oxone (HSO5−) in aqueous solution. To determine to what extent water was the source of the evolved O2, H218O isotope-labelling experiments coupled with membrane inlet mass spectrometry (MIMS) were carried out. We discovered that during the reaction of oxone with [Mn2(OAc)2(bpmp)]+ (1), stoichiometrically labelled oxygen (18O2) was formed. This is the first example of a homogeneous reaction mediated by a synthetic manganese complex where the addition of a strong chemical oxidant yields 18O2 with labelling percentages matching the theoretically expected values for the case of both O-atoms originating from water. Experiments using lead acetate as an alternative oxidant supported this finding. A detailed investigation of the reaction by EPR spectroscopy, MIMS and Clark-type oxygen detection enabled us to propose potential reaction pathways.},
	language = {en},
	number = {6},
	urldate = {2024-11-29},
	journal = {Energy \& Environmental Science},
	author = {Beckmann, Katrin and Uchtenhagen, Hannes and Berggren, Gustav and Anderlund, Magnus F. and Thapper, Anders and Messinger, Johannes and Styring, Stenbjörn and Kurz, Philipp},
	month = dec,
	year = {2008},
	note = {Publisher: The Royal Society of Chemistry},
	pages = {668--676},
}

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To determine to what extent water was the source of the evolved O2, H218O isotope-labelling experiments coupled with membrane inlet mass spectrometry (MIMS) were carried out. We discovered that during the reaction of oxone with [Mn2(OAc)2(bpmp)]+ (1), stoichiometrically labelled oxygen (18O2) was formed. This is the first example of a homogeneous reaction mediated by a synthetic manganese complex where the addition of a strong chemical oxidant yields 18O2 with labelling percentages matching the theoretically expected values for the case of both O-atoms originating from water. Experiments using lead acetate as an alternative oxidant supported this finding. A detailed investigation of the reaction by EPR spectroscopy, MIMS and Clark-type oxygen detection enabled us to propose potential reaction pathways.","language":"en","number":"6","urldate":"2024-11-29","journal":"Energy & Environmental Science","author":[{"propositions":[],"lastnames":["Beckmann"],"firstnames":["Katrin"],"suffixes":[]},{"propositions":[],"lastnames":["Uchtenhagen"],"firstnames":["Hannes"],"suffixes":[]},{"propositions":[],"lastnames":["Berggren"],"firstnames":["Gustav"],"suffixes":[]},{"propositions":[],"lastnames":["Anderlund"],"firstnames":["Magnus","F."],"suffixes":[]},{"propositions":[],"lastnames":["Thapper"],"firstnames":["Anders"],"suffixes":[]},{"propositions":[],"lastnames":["Messinger"],"firstnames":["Johannes"],"suffixes":[]},{"propositions":[],"lastnames":["Styring"],"firstnames":["Stenbjörn"],"suffixes":[]},{"propositions":[],"lastnames":["Kurz"],"firstnames":["Philipp"],"suffixes":[]}],"month":"December","year":"2008","note":"Publisher: The Royal Society of Chemistry","pages":"668–676","bibtex":"@article{beckmann_formation_2008,\n\ttitle = {Formation of stoichiometrically {18O}-labelled oxygen from the oxidation of {18O}-enriched water mediated by a dinuclear manganese complex—a mass spectrometry and {EPR} study},\n\tvolume = {1},\n\tissn = {1754-5706},\n\turl = {https://pubs.rsc.org/en/content/articlelanding/2008/ee/b811806j},\n\tdoi = {10.1039/B811806J},\n\tabstract = {Oxygen formation was detected for the oxidations of various multinuclear manganese complexes by oxone (HSO5−) in aqueous solution. To determine to what extent water was the source of the evolved O2, H218O isotope-labelling experiments coupled with membrane inlet mass spectrometry (MIMS) were carried out. We discovered that during the reaction of oxone with [Mn2(OAc)2(bpmp)]+ (1), stoichiometrically labelled oxygen (18O2) was formed. This is the first example of a homogeneous reaction mediated by a synthetic manganese complex where the addition of a strong chemical oxidant yields 18O2 with labelling percentages matching the theoretically expected values for the case of both O-atoms originating from water. Experiments using lead acetate as an alternative oxidant supported this finding. A detailed investigation of the reaction by EPR spectroscopy, MIMS and Clark-type oxygen detection enabled us to propose potential reaction pathways.},\n\tlanguage = {en},\n\tnumber = {6},\n\turldate = {2024-11-29},\n\tjournal = {Energy \\& Environmental Science},\n\tauthor = {Beckmann, Katrin and Uchtenhagen, Hannes and Berggren, Gustav and Anderlund, Magnus F. and Thapper, Anders and Messinger, Johannes and Styring, Stenbjörn and Kurz, Philipp},\n\tmonth = dec,\n\tyear = {2008},\n\tnote = {Publisher: The Royal Society of Chemistry},\n\tpages = {668--676},\n}\n\n\n\n","author_short":["Beckmann, K.","Uchtenhagen, H.","Berggren, G.","Anderlund, M. F.","Thapper, A.","Messinger, J.","Styring, S.","Kurz, P."],"key":"beckmann_formation_2008","id":"beckmann_formation_2008","bibbaseid":"beckmann-uchtenhagen-berggren-anderlund-thapper-messinger-styring-kurz-formationofstoichiometrically18olabelledoxygenfromtheoxidationof18oenrichedwatermediatedbyadinuclearmanganesecomplexamassspectrometryandeprstudy-2008","role":"author","urls":{"Paper":"https://pubs.rsc.org/en/content/articlelanding/2008/ee/b811806j"},"metadata":{"authorlinks":{}}},"bibtype":"article","biburl":"https://bibbase.org/zotero/upscpub","dataSources":["9cGcv2t8pRzC92kzs"],"keywords":[],"search_terms":["formation","stoichiometrically","18o","labelled","oxygen","oxidation","18o","enriched","water","mediated","dinuclear","manganese","complex","mass","spectrometry","epr","study","beckmann","uchtenhagen","berggren","anderlund","thapper","messinger","styring","kurz"],"title":"Formation of stoichiometrically 18O-labelled oxygen from the oxidation of 18O-enriched water mediated by a dinuclear manganese complex—a mass spectrometry and EPR study","year":2008}