Synthesis of a new ligand to facilitate multi-metallic chains. Beetem, S., A., Cilwa, K., & Walters, K., A. Abstracts of Papers, 227th ACS National Meeting, Anaheim, CA, United States, March 28-April 1, 2004, 2004.
abstract   bibtex   
The objective of the research project is to synthesize a modification of a recently reported ligand that enables a transition metal chromophore to be encapsulated within the backbone of a p-conjugated PPE-type oligomeric or polymeric backbone. The tethered phenanthroline \"superligand\" assures a linear geometry, which greatly simplifies construction of the new multimetallic systems. These new supramol. systems hope to improve upon previous organometallic oligomers and polymers where the transition metal is pendant to the org. backbone, thus reducing the potential for the two subsystems to interact. The synthetic strategy of this ligand is presented, along with details of a comprehensive photophys. study of both the ligand and some model transition metal complexes. [on SciFinder (R)]
@article{
 title = {Synthesis of a new ligand to facilitate multi-metallic chains},
 type = {article},
 year = {2004},
 pages = {CHED-462},
 id = {54a4ff11-9ff9-3a63-9828-f6453f311516},
 created = {2012-06-10T19:41:58.000Z},
 file_attached = {false},
 profile_id = {3e7260a9-6e8d-3223-930b-f5ea025e6d3f},
 last_modified = {2015-05-20T13:34:59.000Z},
 read = {false},
 starred = {false},
 authored = {true},
 confirmed = {true},
 hidden = {false},
 citation_key = {Beetem2004},
 source_type = {Journal Article},
 abstract = {The objective of the research project is to synthesize a modification of a recently reported ligand that enables a transition metal chromophore to be encapsulated within the backbone of a p-conjugated PPE-type oligomeric or polymeric backbone. The tethered phenanthroline \"superligand\" assures a linear geometry, which greatly simplifies construction of the new multimetallic systems. These new supramol. systems hope to improve upon previous organometallic oligomers and polymers where the transition metal is pendant to the org. backbone, thus reducing the potential for the two subsystems to interact. The synthetic strategy of this ligand is presented, along with details of a comprehensive photophys. study of both the ligand and some model transition metal complexes. [on SciFinder (R)]},
 bibtype = {article},
 author = {Beetem, Sarah A and Cilwa, Katherine and Walters, Keith A},
 journal = {Abstracts of Papers, 227th ACS National Meeting, Anaheim, CA, United States, March 28-April 1, 2004}
}

Downloads: 0