Orthogonal electronic coupling in multicentre arylamine mixed-valence compounds based on a dibenzofulvene-thiophene conjugated bridge. Beneduci, A., Corrente, G., Fabiano, E., Maltese, V., Cospito, S., Ciccarella, G., Chidichimo, G., Gigli, G., & Capodilupo, A. Chemical Communications, 53(64):8960-8963, Royal Society of Chemistry, 2017. cited By 12
Orthogonal electronic coupling in multicentre arylamine mixed-valence compounds based on a dibenzofulvene-thiophene conjugated bridge [link]Paper  doi  abstract   bibtex   
Herein we present organic mixed-valence compounds with an innovative H-shape design, where four redox centres are bridged "vertically" via a dibenzofulvene backbone and "horizontally" via a bis-(dibenzofulvene)-thiophene bridge. These compounds are easily oxidized to stable highly charged radical species which show intense intervalence charge transfer transitions in the near infrared region. Interestingly, depending on the position of the arylamine substituents on the bridge, both vertical and horizontal electron transfer pathways can be optically induced. © 2017 The Royal Society of Chemistry.
@ARTICLE{Beneduci20178960,
author={Beneduci, A. and Corrente, G.A. and Fabiano, E. and Maltese, V. and Cospito, S. and Ciccarella, G. and Chidichimo, G. and Gigli, G. and Capodilupo, A.-L.},
title={Orthogonal electronic coupling in multicentre arylamine mixed-valence compounds based on a dibenzofulvene-thiophene conjugated bridge},
journal={Chemical Communications},
year={2017},
volume={53},
number={64},
pages={8960-8963},
doi={10.1039/c7cc03156d},
note={cited By 12},
url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-85027126974&doi=10.1039%2fc7cc03156d&partnerID=40&md5=3b27c2435f7eca2324771d55d0a16a44},
abstract={Herein we present organic mixed-valence compounds with an innovative H-shape design, where four redox centres are bridged "vertically" via a dibenzofulvene backbone and "horizontally" via a bis-(dibenzofulvene)-thiophene bridge. These compounds are easily oxidized to stable highly charged radical species which show intense intervalence charge transfer transitions in the near infrared region. Interestingly, depending on the position of the arylamine substituents on the bridge, both vertical and horizontal electron transfer pathways can be optically induced. © 2017 The Royal Society of Chemistry.},
publisher={Royal Society of Chemistry},
issn={13597345},
coden={CHCOF},
pubmed_id={28639656},
document_type={Article},
source={Scopus},
}

Downloads: 0