Organometallic ruthenium and iridium transfer-hydrogenation catalysts using coenzyme NADH as a cofactor

Organometallic ruthenium and iridium transfer-hydrogenation catalysts using coenzyme NADH as a cofactor. Betanzos-Lara, S., Liu, Z., Habtemariam, A., Pizarro, A. M., Qamar, B., & Sadler, P. J. Angewandte Chemie - International Edition, 51(16):3897–3900, 2012.
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Artificial enzymes: Half-sandwich arene ruthenium(II) and cyclopentadienyl iridium(III) complexes containing N,N-chelated ligands can use NADH as a source of hydride for the reduction of ketones (see picture). Moreover, cyclopentadienyl phenanthroline iridium(III) derivatives at micromolar concentrations are robust catalysts for the production of H 2 from NADH in water and can raise the NAD +/NADH ratio in cancer cells. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

@article{betanzos-lara_organometallic_2012,
	title = {Organometallic ruthenium and iridium transfer-hydrogenation catalysts using coenzyme {NADH} as a cofactor},
	volume = {51},
	issn = {14337851},
	doi = {10.1002/anie.201108175},
	abstract = {Artificial enzymes: Half-sandwich arene ruthenium(II) and cyclopentadienyl iridium(III) complexes containing N,N-chelated ligands can use NADH as a source of hydride for the reduction of ketones (see picture). Moreover, cyclopentadienyl phenanthroline iridium(III) derivatives at micromolar concentrations are robust catalysts for the production of H 2 from NADH in water and can raise the NAD +/NADH ratio in cancer cells. Copyright © 2012 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.},
	number = {16},
	journal = {Angewandte Chemie - International Edition},
	author = {Betanzos-Lara, Soledad and Liu, Zhe and Habtemariam, Abraha and Pizarro, Ana M. and Qamar, Bushra and Sadler, Peter J.},
	year = {2012},
	pmid = {22415924},
	keywords = {arenes, bio-organometallics, hydride transfer, iridium, ruthenium},
	pages = {3897--3900},
}

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