Carbon nanodot-based heterostructures for improving the charge separation and the photocurrent generation. Bettini, S., Sawalha, S., Carbone, L., Giancane, G., Prato, M., & Valli, L. Nanoscale, 11(15):7414-7423, Royal Society of Chemistry, 2019. cited By 8![Carbon nanodot-based heterostructures for improving the charge separation and the photocurrent generation [link]](https://bibbase.org/img/filetypes/link.svg "link")
Paper doi abstract bibtex The possibility to employ carbon nanodots (CNDs) in solar devices was exploited by combining them with a fulleropyrrolidine derivative (FP2). The interaction between the two species was promoted by the presence of opposite electrostatic charges on CNDs (negatively charged) and FP2 (positively charged). The supramolecular dyad CNDs/FP2 generation was induced at the air/water interface of a Langmuir trough: water soluble CNDs were dissolved in the subphase and FP2 chloroform solution was spread on the subphase; the electrostatic interaction promoted the formation of the supramolecular adduct FP2/CNDs, which was then transferred onto solid substrates. Photo-induced charge transfer was promoted in the FP2/CNDs dyad and we demonstrated that the presence of CNDs increased the short-circuit current density, under light illumination, of a porphyrin-FP2/CNDs thin film by about 300% when compared with a more traditional porphyrin-FP2 solar device. © 2019 The Royal Society of Chemistry.
@ARTICLE{Bettini20197414,
author={Bettini, S. and Sawalha, S. and Carbone, L. and Giancane, G. and Prato, M. and Valli, L.},
title={Carbon nanodot-based heterostructures for improving the charge separation and the photocurrent generation},
journal={Nanoscale},
year={2019},
volume={11},
number={15},
pages={7414-7423},
doi={10.1039/c9nr00951e},
note={cited By 8},
url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-85064256003&doi=10.1039%2fc9nr00951e&partnerID=40&md5=60e6517206c33fb9332c35826de54398},
abstract={The possibility to employ carbon nanodots (CNDs) in solar devices was exploited by combining them with a fulleropyrrolidine derivative (FP2). The interaction between the two species was promoted by the presence of opposite electrostatic charges on CNDs (negatively charged) and FP2 (positively charged). The supramolecular dyad CNDs/FP2 generation was induced at the air/water interface of a Langmuir trough: water soluble CNDs were dissolved in the subphase and FP2 chloroform solution was spread on the subphase; the electrostatic interaction promoted the formation of the supramolecular adduct FP2/CNDs, which was then transferred onto solid substrates. Photo-induced charge transfer was promoted in the FP2/CNDs dyad and we demonstrated that the presence of CNDs increased the short-circuit current density, under light illumination, of a porphyrin-FP2/CNDs thin film by about 300% when compared with a more traditional porphyrin-FP2 solar device. © 2019 The Royal Society of Chemistry.},
publisher={Royal Society of Chemistry},
issn={20403364},
pubmed_id={30938748},
document_type={Article},
source={Scopus},
}
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