Synthesis and hydrogen sorption properties of TiV(2−x)Mnx BCC alloys. Bibienne, T., Tousignant, M., Bobet, J., & Huot, J. Journal of Alloys and Compounds, 624:247–250, March, 2015.
Paper doi abstract bibtex We report here the effect of activation process of TiV2−xMnx samples (x=0.2,0.4,0.6,0.8,0.9). Crystal structures are investigated for the as-cast, hydrogenated and desorbed states. The as-cast samples crystallise with a Body Centered Cubic (BCC) structure, and the lattice parameter decreases as x increases in the TiV2−xMnx series. Upon hydrogenation, the BCC structure expands and turns into a Body Centered Tetragonal (BCT) structure for the monohydride phase and into a Face Centered Cubic (FCC) for the dihydride phase. Pressure–Composition-Isotherms (P–C–I) measurements were performed to study the thermodynamic of TiV2−xMnx alloys and their hydrogen capacities. The maximum hydrogen uptake is observed for TiV1.2Mn0.8 composition, which store 3.4wt.% of hydrogen at 100°C. The effect of a new activation process on the hydrogen storage capacities of these alloys is discussed.
@article{bibienne_synthesis_2015,
title = {Synthesis and hydrogen sorption properties of {TiV}(2−x){Mnx} {BCC} alloys},
volume = {624},
issn = {0925-8388},
url = {http://www.sciencedirect.com/science/article/pii/S0925838814027030},
doi = {10.1016/j.jallcom.2014.11.060},
abstract = {We report here the effect of activation process of TiV2−xMnx samples (x=0.2,0.4,0.6,0.8,0.9). Crystal structures are investigated for the as-cast, hydrogenated and desorbed states. The as-cast samples crystallise with a Body Centered Cubic (BCC) structure, and the lattice parameter decreases as x increases in the TiV2−xMnx series. Upon hydrogenation, the BCC structure expands and turns into a Body Centered Tetragonal (BCT) structure for the monohydride phase and into a Face Centered Cubic (FCC) for the dihydride phase. Pressure–Composition-Isotherms (P–C–I) measurements were performed to study the thermodynamic of TiV2−xMnx alloys and their hydrogen capacities. The maximum hydrogen uptake is observed for TiV1.2Mn0.8 composition, which store 3.4wt.\% of hydrogen at 100°C. The effect of a new activation process on the hydrogen storage capacities of these alloys is discussed.},
urldate = {2018-03-09},
journal = {Journal of Alloys and Compounds},
author = {Bibienne, Thomas and Tousignant, Manuel and Bobet, Jean-Louis and Huot, Jacques},
month = mar,
year = {2015},
keywords = {BCC alloys, Hydrogen storage, Metal hydrides},
pages = {247--250},
}
Downloads: 0
{"_id":"ykSWskAzeB2oDD5GP","bibbaseid":"bibienne-tousignant-bobet-huot-synthesisandhydrogensorptionpropertiesoftiv2xmnxbccalloys-2015","author_short":["Bibienne, T.","Tousignant, M.","Bobet, J.","Huot, J."],"bibdata":{"bibtype":"article","type":"article","title":"Synthesis and hydrogen sorption properties of TiV(2−x)Mnx BCC alloys","volume":"624","issn":"0925-8388","url":"http://www.sciencedirect.com/science/article/pii/S0925838814027030","doi":"10.1016/j.jallcom.2014.11.060","abstract":"We report here the effect of activation process of TiV2−xMnx samples (x=0.2,0.4,0.6,0.8,0.9). Crystal structures are investigated for the as-cast, hydrogenated and desorbed states. The as-cast samples crystallise with a Body Centered Cubic (BCC) structure, and the lattice parameter decreases as x increases in the TiV2−xMnx series. Upon hydrogenation, the BCC structure expands and turns into a Body Centered Tetragonal (BCT) structure for the monohydride phase and into a Face Centered Cubic (FCC) for the dihydride phase. Pressure–Composition-Isotherms (P–C–I) measurements were performed to study the thermodynamic of TiV2−xMnx alloys and their hydrogen capacities. The maximum hydrogen uptake is observed for TiV1.2Mn0.8 composition, which store 3.4wt.% of hydrogen at 100°C. The effect of a new activation process on the hydrogen storage capacities of these alloys is discussed.","urldate":"2018-03-09","journal":"Journal of Alloys and Compounds","author":[{"propositions":[],"lastnames":["Bibienne"],"firstnames":["Thomas"],"suffixes":[]},{"propositions":[],"lastnames":["Tousignant"],"firstnames":["Manuel"],"suffixes":[]},{"propositions":[],"lastnames":["Bobet"],"firstnames":["Jean-Louis"],"suffixes":[]},{"propositions":[],"lastnames":["Huot"],"firstnames":["Jacques"],"suffixes":[]}],"month":"March","year":"2015","keywords":"BCC alloys, Hydrogen storage, Metal hydrides","pages":"247–250","bibtex":"@article{bibienne_synthesis_2015,\n\ttitle = {Synthesis and hydrogen sorption properties of {TiV}(2−x){Mnx} {BCC} alloys},\n\tvolume = {624},\n\tissn = {0925-8388},\n\turl = {http://www.sciencedirect.com/science/article/pii/S0925838814027030},\n\tdoi = {10.1016/j.jallcom.2014.11.060},\n\tabstract = {We report here the effect of activation process of TiV2−xMnx samples (x=0.2,0.4,0.6,0.8,0.9). Crystal structures are investigated for the as-cast, hydrogenated and desorbed states. The as-cast samples crystallise with a Body Centered Cubic (BCC) structure, and the lattice parameter decreases as x increases in the TiV2−xMnx series. Upon hydrogenation, the BCC structure expands and turns into a Body Centered Tetragonal (BCT) structure for the monohydride phase and into a Face Centered Cubic (FCC) for the dihydride phase. Pressure–Composition-Isotherms (P–C–I) measurements were performed to study the thermodynamic of TiV2−xMnx alloys and their hydrogen capacities. The maximum hydrogen uptake is observed for TiV1.2Mn0.8 composition, which store 3.4wt.\\% of hydrogen at 100°C. The effect of a new activation process on the hydrogen storage capacities of these alloys is discussed.},\n\turldate = {2018-03-09},\n\tjournal = {Journal of Alloys and Compounds},\n\tauthor = {Bibienne, Thomas and Tousignant, Manuel and Bobet, Jean-Louis and Huot, Jacques},\n\tmonth = mar,\n\tyear = {2015},\n\tkeywords = {BCC alloys, Hydrogen storage, Metal hydrides},\n\tpages = {247--250},\n}\n\n\n\n\n\n\n\n","author_short":["Bibienne, T.","Tousignant, M.","Bobet, J.","Huot, J."],"key":"bibienne_synthesis_2015","id":"bibienne_synthesis_2015","bibbaseid":"bibienne-tousignant-bobet-huot-synthesisandhydrogensorptionpropertiesoftiv2xmnxbccalloys-2015","role":"author","urls":{"Paper":"http://www.sciencedirect.com/science/article/pii/S0925838814027030"},"keyword":["BCC alloys","Hydrogen storage","Metal hydrides"],"metadata":{"authorlinks":{}},"html":""},"bibtype":"article","biburl":"https://bibbase.org/zotero/robertorobles","dataSources":["8vvu6PNxwEyxJxvhj"],"keywords":["bcc alloys","hydrogen storage","metal hydrides"],"search_terms":["synthesis","hydrogen","sorption","properties","tiv","mnx","bcc","alloys","bibienne","tousignant","bobet","huot"],"title":"Synthesis and hydrogen sorption properties of TiV(2−x)Mnx BCC alloys","year":2015}