Simultaneous determination of 16 brominated flame retardants in food and feed of animal origin by fast gas chromatography coupled to tandem mass spectrometry using atmospheric pressure chemical ionisation. Bichon, E.; Guiffard, I.; Vénisseau, A.; Lesquin, E.; Vaccher, V.; Brosseaud, A.; Marchand, P.; and Le Bizec, B. 1459:120–128.
Simultaneous determination of 16 brominated flame retardants in food and feed of animal origin by fast gas chromatography coupled to tandem mass spectrometry using atmospheric pressure chemical ionisation [link]Paper  doi  abstract   bibtex   
A gas chromatography tandem mass spectrometry method using atmospheric pressure chemical ionisation was developed for the monitoring of 16 brominated flame retardants (7 usually monitored polybromodiphenylethers (PBDEs) and BDE #209 and 8 additional emerging and novel BFRs) in food and feed of animal origin. The developed analytical method has decreased the run time by three compared to conventional strategies, using a 2.5 m column length (5% phenyl stationary phase, 0.1 mm i.d., 0.1 ␮m f.t.), a pulsed split injection (1:5) with carrier gas helium flow rate at 0.48 mL min−1 in one run of 20 min. For most BFRs, analytical data were compared with the current analytical strategy relying on GC/EI/HRMS (double sector, R = 10000 at 10% valley). Performances in terms of sensitivity were found to meet the Commission recommendation (118/2014/EC) for nBFRs. GC/APCI/MS/MS represents a promising alternative for multi-BFRs analysis in complex matrices, in that it allows the monitoring of a wider list of contaminants in a single injection and a shorter run time.
@article{bichon_simultaneous_2016,
	title = {Simultaneous determination of 16 brominated flame retardants in food and feed of animal origin by fast gas chromatography coupled to tandem mass spectrometry using atmospheric pressure chemical ionisation},
	volume = {1459},
	issn = {00219673},
	url = {https://linkinghub.elsevier.com/retrieve/pii/S0021967316308937},
	doi = {10.1016/j.chroma.2016.07.003},
	abstract = {A gas chromatography tandem mass spectrometry method using atmospheric pressure chemical ionisation was developed for the monitoring of 16 brominated flame retardants (7 usually monitored polybromodiphenylethers ({PBDEs}) and {BDE} \#209 and 8 additional emerging and novel {BFRs}) in food and feed of animal origin. The developed analytical method has decreased the run time by three compared to conventional strategies, using a 2.5 m column length (5\% phenyl stationary phase, 0.1 mm i.d., 0.1 ␮m f.t.), a pulsed split injection (1:5) with carrier gas helium flow rate at 0.48 {mL} min−1 in one run of 20 min. For most {BFRs}, analytical data were compared with the current analytical strategy relying on {GC}/{EI}/{HRMS} (double sector, R = 10000 at 10\% valley). Performances in terms of sensitivity were found to meet the Commission recommendation (118/2014/{EC}) for {nBFRs}. {GC}/{APCI}/{MS}/{MS} represents a promising alternative for multi-{BFRs} analysis in complex matrices, in that it allows the monitoring of a wider list of contaminants in a single injection and a shorter run time.},
	pages = {120--128},
	journaltitle = {Journal of Chromatography A},
	author = {Bichon, E. and Guiffard, I. and Vénisseau, A. and Lesquin, E. and Vaccher, V. and Brosseaud, A. and Marchand, P. and Le Bizec, B.},
	urldate = {2019-03-29},
	date = {2016-08},
	langid = {english},
	file = {Bichon et al. - 2016 - Simultaneous determination of 16 brominated flame .pdf:C\:\\Users\\ygu\\Documents\\PCPOR066_YGU\\YGU\\Zotero\\storage\\KVGD2VH8\\Bichon et al. - 2016 - Simultaneous determination of 16 brominated flame .pdf:application/pdf}
}
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