@article{Blanco2004,
abstract = {A series of Ce-Mn composites with different compositions was prepared by co-precipitation. All samples were characterized by x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), energy dispersive spectroscopy (EDS) and transmission electron microscopy (TEM). According to their size and chemical composition, two different kinds of particles were observed: (a) small crystallites of Ce-Mn solid solution (<7nm), and (b) large particles of manganese oxides with different reduction degrees (>50nm). These results were used to explain differences between the surface and bulk compositions of the samples as well as the specific surface area. Furthermore, from XPS studies, the presence of various Mn species with different oxidation states could be stated. This fact might clarify the exceptional catalytic behaviour of the samples for the catalytic wet oxidation of toxic organic compounds. Copyright © 2004 John Wiley & Sons, Ltd.},
address = {Depto. de Ciencia de los Materiales, Facultad de Ciencias, Universidad de C\'{a}diz, Apartado 40, E-11510 Puerto Real (C\'{a}diz), Spain},
annote = {Cited By (since 1996): 26

        
Export Date: 15 January 2013

        
Source: Scopus

        
CODEN: SIAND

        
doi: 10.1002/sia.1755

        
Language of Original Document: English

        
Correspondence Address: Blanco, G.; Depto. de Ciencia de los Materiales, Facultad de Ciencias, Universidad de C\'{a}diz, Apartado 40, E-11510 Puerto Real (C\'{a}diz), Spain; email: ginesa.blanco@uca.es

        
References: Matatov-Meytal, Y.I., Sheintuch, M., (1998) Ind. Eng. Chem. Res., 37, p. 309; 
Luck, F., (1999) Catal. Today, 53, p. 81; 
Mishra, V.S., Mahajani, V.V., Joshi, J.B., (1995) Ind. Eng. Chem. Res., 34, p. 2; 
Tagashira, Y., Takagi, K., Inagaki, K., (1976), Japan Patent number 75 106 862Shende, R.V., Mahajani, V.V., Vijaykumar, V., (1997) Ind. Eng. Chem. Res., 36, p. 4809; 
Hamoudi, S., Larachi, F., Sayari, A., (1998) J. Catal., 177, p. 247; 
Imamura, S., Nakamura, M., Kawabata, N., Yoshida, J., (1986) Ind. Eng. Chem. Prod. Res. Dev., 25, p. 34; 
Hamoudi, S., Belkacemi, K., Larachi, F., (1999) Chem. Eng. Sci., 54, p. 3569; 
Imamura, S., Doi, A., Ishida, S., (1985) Ind. Eng. Chem. Prod. Res. Dev., 24, p. 75; 
Imamura, S., Okumura, Y., Nishio, T., Utani, K., Matsumura, Y., (1998) Ind. Eng. Chem. Res., 37, p. 1136; 
Delgado, J.J., (2003), PhD Thesis, University of CadizChen, H., Sayari, A., Adnot, A., Larachi, F., (2001) Appl. Catal. B., 32, p. 195; 
Stochmeier, B.R., Hercules, D.M., (1984) J. Phys. Chem., 88, p. 4922; 
Galtayries, A., Blanco, G., Cifredo, G.A., Finol, D., Gatica, J.M., Pintado, J.M., Vidai, H., Bernai, S., (1999) Surf. Interface Anal., 27, p. 941; 
Laachir, A., Perrichon, V., Badri, A., Lamotte, J., Catherine, E., Lavalley, J.C., El Fallah, J., Touret, O., (1991) J. Chem. Soc. Faraday Trans., 87, p. 1601; 
Mirabella, F., Johnson, R.L., Ghijsen, J., (2002) Surf. Sci., 506, p. 172},
author = {Blanco, G and Cauqui, M A and Delgado, J J and Galtayries, A and P\'{e}rez-Omil, J A and Rodr\'{\i}guez-Izquierdo, J M},
issn = {01422421 (ISSN)},
journal = {Surface and Interface Analysis},
keywords = {Catalysis,Catalytic wet oxidation,Ce-Mn-O composites,Composite materials,EDS,Energy dispersive spectroscopy,Oxidation,Reduction,Surface characterization,Surface chemistry,TEM,X ray diffraction analysis,X ray photoelectron spectroscopy,XPS},
number = {8},
pages = {752--755},
title = {{Preparation and characterization of Ce-Mn-O composites with applications in catalytic wet oxidation processes}},
url = {https://www.scopus.com/inward/record.url?eid=2-s2.0-4444221609&partnerID=40&md5=33e74f95b4b86556f9037a571bc4f656},
volume = {36},
year = {2004}
}

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According to their size and chemical composition, two different kinds of particles were observed: (a) small crystallites of Ce-Mn solid solution (<7nm), and (b) large particles of manganese oxides with different reduction degrees (>50nm). These results were used to explain differences between the surface and bulk compositions of the samples as well as the specific surface area. Furthermore, from XPS studies, the presence of various Mn species with different oxidation states could be stated. This fact might clarify the exceptional catalytic behaviour of the samples for the catalytic wet oxidation of toxic organic compounds. Copyright © 2004 John Wiley & Sons, Ltd.","address":"Depto. de Ciencia de los Materiales, Facultad de Ciencias, Universidad de Cádiz, Apartado 40, E-11510 Puerto Real (Cádiz), Spain","annote":"Cited By (since 1996): 26 Export Date: 15 January 2013 Source: Scopus CODEN: SIAND doi: 10.1002/sia.1755 Language of Original Document: English Correspondence Address: Blanco, G.; Depto. de Ciencia de los Materiales, Facultad de Ciencias, Universidad de Cádiz, Apartado 40, E-11510 Puerto Real (Cádiz), Spain; email: ginesa.blanco@uca.es References: Matatov-Meytal, Y.I., Sheintuch, M., (1998) Ind. Eng. Chem. Res., 37, p. 309; Luck, F., (1999) Catal. Today, 53, p. 81; Mishra, V.S., Mahajani, V.V., Joshi, J.B., (1995) Ind. Eng. Chem. Res., 34, p. 2; Tagashira, Y., Takagi, K., Inagaki, K., (1976), Japan Patent number 75 106 862Shende, R.V., Mahajani, V.V., Vijaykumar, V., (1997) Ind. Eng. Chem. Res., 36, p. 4809; Hamoudi, S., Larachi, F., Sayari, A., (1998) J. Catal., 177, p. 247; Imamura, S., Nakamura, M., Kawabata, N., Yoshida, J., (1986) Ind. Eng. Chem. Prod. Res. Dev., 25, p. 34; Hamoudi, S., Belkacemi, K., Larachi, F., (1999) Chem. Eng. Sci., 54, p. 3569; Imamura, S., Doi, A., Ishida, S., (1985) Ind. Eng. Chem. Prod. Res. Dev., 24, p. 75; Imamura, S., Okumura, Y., Nishio, T., Utani, K., Matsumura, Y., (1998) Ind. Eng. Chem. Res., 37, p. 1136; Delgado, J.J., (2003), PhD Thesis, University of CadizChen, H., Sayari, A., Adnot, A., Larachi, F., (2001) Appl. Catal. B., 32, p. 195; Stochmeier, B.R., Hercules, D.M., (1984) J. Phys. Chem., 88, p. 4922; Galtayries, A., Blanco, G., Cifredo, G.A., Finol, D., Gatica, J.M., Pintado, J.M., Vidai, H., Bernai, S., (1999) Surf. Interface Anal., 27, p. 941; Laachir, A., Perrichon, V., Badri, A., Lamotte, J., Catherine, E., Lavalley, J.C., El Fallah, J., Touret, O., (1991) J. Chem. Soc. Faraday Trans., 87, p. 1601; Mirabella, F., Johnson, R.L., Ghijsen, J., (2002) Surf. 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All samples were characterized by x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), energy dispersive spectroscopy (EDS) and transmission electron microscopy (TEM). According to their size and chemical composition, two different kinds of particles were observed: (a) small crystallites of Ce-Mn solid solution (<7nm), and (b) large particles of manganese oxides with different reduction degrees (>50nm). These results were used to explain differences between the surface and bulk compositions of the samples as well as the specific surface area. Furthermore, from XPS studies, the presence of various Mn species with different oxidation states could be stated. This fact might clarify the exceptional catalytic behaviour of the samples for the catalytic wet oxidation of toxic organic compounds. 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