@article{ title = {Nitroxide-mediated living radical polymerization: Determination of the rate coefficient for alkoxyamine C-O bond homolysis by quantitative ESR}, type = {article}, year = {1999}, pages = {8269-8276}, volume = {32}, websites = {http://pubs.acs.org/doi/abs/10.1021/ma990771r}, publisher = {American Chemical Society}, id = {0c623c85-fc2d-3065-ac59-a3ab83722aae}, created = {2024-01-02T14:09:44.218Z}, file_attached = {false}, profile_id = {36921318-7a81-32e6-acca-75b835acd8f1}, group_id = {f2d52f92-0a5a-3712-a53b-a4492da8da5f}, last_modified = {2024-01-02T14:09:44.218Z}, read = {false}, starred = {false}, authored = {false}, confirmed = {true}, hidden = {false}, citation_key = {bon1999nitroxide}, source_type = {article}, private_publication = {false}, abstract = {The rate coefficient for alkoxyamine C−O bond homolysis has been determined over a range of temperatures for both 2-tert-butoxy-1-phenyl-1-(1-oxy-2,2,6,6-tetramethylpiperidinyl)ethane (1) and a polystyrene−TEMPO (approximately 75 units) adduct using quantitative ESR. In }, bibtype = {article}, author = {Bon, Stefan A.F. and Chambard, Grégory and German, Anton L.}, doi = {10.1021/ma990771r}, journal = {Macromolecules}, number = {25} }