@article{
 title = {Use of methyl 2-(bromomethyl)acrylate as a chain-transfer agent to yield functionalized macromonomers via conventional and living radical polymerizations},
 type = {article},
 year = {2000},
 pages = {5819-5824},
 volume = {33},
 websites = {http://pubs.acs.org/doi/abs/10.1021/ma991922t},
 publisher = {ACS Publications},
 id = {97066e92-b3da-3dae-826d-569fc61774a1},
 created = {2024-01-02T14:09:40.443Z},
 file_attached = {false},
 profile_id = {36921318-7a81-32e6-acca-75b835acd8f1},
 group_id = {f2d52f92-0a5a-3712-a53b-a4492da8da5f},
 last_modified = {2024-01-02T14:09:40.443Z},
 read = {false},
 starred = {false},
 authored = {false},
 confirmed = {true},
 hidden = {false},
 citation_key = {bon2000use},
 source_type = {article},
 private_publication = {false},
 abstract = {The chain-transfer constants of methyl (2-bromomethyl)acrylate (MBrMA) in bulk polymerizations of methyl methacrylate (MMA) and styrene were determined at 70 degrees C using both the Mayo method (1/DPn as well as 2/DPw) and the chain-length-distribution procedure (Lambda). The C(MBrMA)values using 2/DPw and Lambda were consistent, i.e., 1.28 and 1.20 for MMA and 11.44 and 10.92 for styrene, respectively. MBrMA was used as a chain-transfer agent in the emulsion polymerization of MMA to yield an a-bromo-functionalized macromonomeric latex ([M-n] = 9.6 x 10(3) g mol(-1); PDI = 1.80), which was subsequently copolymerized with styrene to yield the corresponding poly(styrene-graft-MMA) copolymer. MBrMA was used as an addition-fragmentation agent in the living radical polymerization of MMA mediated by copper(I) bromide/N-(n-octyl)-2-pyridylmethanimine In situ addition of a 5-fold equivalent of MBrMA and Cu(0) to this polymerization quenched the reaction and transformed the omega-bromide into the methacrylate-based macromonomer quantitatively.},
 bibtype = {article},
 author = {Bon, Stefan A.F. and Morsley, Stuart R. and Waterson, Carl and Haddleton, David M.},
 doi = {10.1021/ma991922t},
 journal = {Macromolecules},
 number = {16}
}

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The C(MBrMA)values using 2/DPw and Lambda were consistent, i.e., 1.28 and 1.20 for MMA and 11.44 and 10.92 for styrene, respectively. MBrMA was used as a chain-transfer agent in the emulsion polymerization of MMA to yield an a-bromo-functionalized macromonomeric latex ([M-n] = 9.6 x 10(3) g mol(-1); PDI = 1.80), which was subsequently copolymerized with styrene to yield the corresponding poly(styrene-graft-MMA) copolymer. MBrMA was used as an addition-fragmentation agent in the living radical polymerization of MMA mediated by copper(I) bromide/N-(n-octyl)-2-pyridylmethanimine In situ addition of a 5-fold equivalent of MBrMA and Cu(0) to this polymerization quenched the reaction and transformed the omega-bromide into the methacrylate-based macromonomer quantitatively.","bibtype":"article","author":"Bon, Stefan A.F. and Morsley, Stuart R. and Waterson, Carl and Haddleton, David M.","doi":"10.1021/ma991922t","journal":"Macromolecules","number":"16","bibtex":"@article{\n title = {Use of methyl 2-(bromomethyl)acrylate as a chain-transfer agent to yield functionalized macromonomers via conventional and living radical polymerizations},\n type = {article},\n year = {2000},\n pages = {5819-5824},\n volume = {33},\n websites = {http://pubs.acs.org/doi/abs/10.1021/ma991922t},\n publisher = {ACS Publications},\n id = {97066e92-b3da-3dae-826d-569fc61774a1},\n created = {2024-01-02T14:09:40.443Z},\n file_attached = {false},\n profile_id = {36921318-7a81-32e6-acca-75b835acd8f1},\n group_id = {f2d52f92-0a5a-3712-a53b-a4492da8da5f},\n last_modified = {2024-01-02T14:09:40.443Z},\n read = {false},\n starred = {false},\n authored = {false},\n confirmed = {true},\n hidden = {false},\n citation_key = {bon2000use},\n source_type = {article},\n private_publication = {false},\n abstract = {The chain-transfer constants of methyl (2-bromomethyl)acrylate (MBrMA) in bulk polymerizations of methyl methacrylate (MMA) and styrene were determined at 70 degrees C using both the Mayo method (1/DPn as well as 2/DPw) and the chain-length-distribution procedure (Lambda). 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