@article{
 title = {Water-Soluble and Water Dispersible Polymers by Living Radical Polymerisation BT  - Stimuli Responsive Water-Soluble and Amphiphilic (Co)polymers},
 type = {article},
 year = {2009},
 pages = {148-161},
 volume = {780},
 websites = {http://pubs.acs.org/doi/abs/10.1021/bk-2001-0780.ch009%5Cnpapers3://publication/doi/10.1021/bk-2001-0780.ch009},
 publisher = {ACS Publications},
 id = {3c145f49-41b6-36db-aa86-9100ee681ab2},
 created = {2024-01-02T14:09:41.364Z},
 file_attached = {false},
 profile_id = {36921318-7a81-32e6-acca-75b835acd8f1},
 group_id = {f2d52f92-0a5a-3712-a53b-a4492da8da5f},
 last_modified = {2024-01-02T14:09:41.364Z},
 read = {false},
 starred = {false},
 authored = {false},
 confirmed = {true},
 hidden = {false},
 citation_key = {bon2001water},
 source_type = {article},
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 abstract = {An overview of recent advances in living radical polymerisation under aqueous conditions and the synthesis of water-soluble and dispersible polymers by living radical polymerisation techniques is given. Living radical polymerisation involving nitroxide stabilised radicals, transition metal mediated and reversible addition fragmentation (RAFT) is covered. This overview is followed by some specific examples of the use of copper(I) mediated living radical polymerisation for the synthesis of some water soluble/dispersible polymers. Firstly the use of a modified SPAN surfactant to polymerise 2-(dimethylamino)ethyl methacrylate (DMAEMA) producing polymers with narrow polydispersity and controlled Mn is described (Mn = 6700, PDI = 1.27). These polymers disperse in acidic aqueous media with a CAC of 0.16 gL-1. Derivatised solketal is described as an initator for sequential atom transfer polymerisation of methyl methacrylate (MMA) and DMAEMA to give Y-shaped water soluble polymers. These two examples serve to illustrate the range of topology and hydrophilic functionality which can easily be incorporated into vinyl polymers through living radical methodology.},
 bibtype = {article},
 author = {Bon, Stefan A F and Ohno, Kohji and Haddleton, David M},
 doi = {10.1021/bk-2001-0780.ch009},
 journal = {Stimuli Responsive Water-Soluble and Amphiphilic (Co)polymers}
}

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