@article{
 title = {Functionalized Graphene as an Electron-Cascade Acceptor for Air-Processed Organic Ternary Solar Cells},
 type = {article},
 year = {2015},
 identifiers = {[object Object]},
 keywords = {bulk heterojunctions,graphene,nanoflakes,organic photovoltaics,ternary blends},
 volume = {25},
 id = {bbf45169-ff09-360a-b5bf-8cf2c114d338},
 created = {2020-09-22T06:58:36.668Z},
 file_attached = {false},
 profile_id = {27227121-76ad-362c-989c-d92a526ac39d},
 last_modified = {2020-09-22T06:58:36.668Z},
 read = {false},
 starred = {false},
 authored = {true},
 confirmed = {false},
 hidden = {false},
 private_publication = {true},
 abstract = {© 2015 WILEY-VCH Verlag GmbH  &  Co. KGaA, Weinheim. Functionalized graphene nanoflakes (GNFs) are used as an electron-cascade acceptor material in air-processed organic ternary bulk heterojunction solar cells. The functionalization is realized via the attachment of the ethylenedinitrobenzoyl (EDNB) molecule to the GNFs. Simulation and experimental results show that such nanoscale modification greatly influences the density of states near the Fermi level. Consequently, the GNF-EDNB blend presents favorable highest occupied molecular orbital and lowest unoccupied molecular orbital energy levels to function as a bridge structure between the poly[N-9′-heptadecanyl-2,7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole)] (PCDTBT) and the [6,6]-phenyl-C71-butyric-acid-methyl-ester (PC71BM). The improved exciton dissociation and charge transport are associated with the better energy level alignment of the ternary blend and the high electrical conductivity of the GNFs, which act as additional electron transport channels within the photoactive layer. The resulting PCDTBT/GNF-EDNB/PC71BM ternary organic solar cells, fabricated entirely under ambient conditions, exhibit an average power conversion efficiency enhancement of ≈18% as compared with the binary blend PCDTBT/PC71BM.},
 bibtype = {article},
 author = {Bonaccorso, F. and Balis, N. and Stylianakis, M.M. and Savarese, M. and Adamo, C. and Gemmi, M. and Pellegrini, V. and Stratakis, E. and Kymakis, E.},
 journal = {Advanced Functional Materials},
 number = {25}
}

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KGaA, Weinheim. Functionalized graphene nanoflakes (GNFs) are used as an electron-cascade acceptor material in air-processed organic ternary bulk heterojunction solar cells. The functionalization is realized via the attachment of the ethylenedinitrobenzoyl (EDNB) molecule to the GNFs. Simulation and experimental results show that such nanoscale modification greatly influences the density of states near the Fermi level. Consequently, the GNF-EDNB blend presents favorable highest occupied molecular orbital and lowest unoccupied molecular orbital energy levels to function as a bridge structure between the poly[N-9′-heptadecanyl-2,7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole)] (PCDTBT) and the [6,6]-phenyl-C71-butyric-acid-methyl-ester (PC71BM). The improved exciton dissociation and charge transport are associated with the better energy level alignment of the ternary blend and the high electrical conductivity of the GNFs, which act as additional electron transport channels within the photoactive layer. The resulting PCDTBT/GNF-EDNB/PC71BM ternary organic solar cells, fabricated entirely under ambient conditions, exhibit an average power conversion efficiency enhancement of ≈18% as compared with the binary blend PCDTBT/PC71BM.","bibtype":"article","author":"Bonaccorso, F. and Balis, N. and Stylianakis, M.M. and Savarese, M. and Adamo, C. and Gemmi, M. and Pellegrini, V. and Stratakis, E. and Kymakis, E.","journal":"Advanced Functional Materials","number":"25","bibtex":"@article{\n title = {Functionalized Graphene as an Electron-Cascade Acceptor for Air-Processed Organic Ternary Solar Cells},\n type = {article},\n year = {2015},\n identifiers = {[object Object]},\n keywords = {bulk heterojunctions,graphene,nanoflakes,organic photovoltaics,ternary blends},\n volume = {25},\n id = {bbf45169-ff09-360a-b5bf-8cf2c114d338},\n created = {2020-09-22T06:58:36.668Z},\n file_attached = {false},\n profile_id = {27227121-76ad-362c-989c-d92a526ac39d},\n last_modified = {2020-09-22T06:58:36.668Z},\n read = {false},\n starred = {false},\n authored = {true},\n confirmed = {false},\n hidden = {false},\n private_publication = {true},\n abstract = {© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Functionalized graphene nanoflakes (GNFs) are used as an electron-cascade acceptor material in air-processed organic ternary bulk heterojunction solar cells. The functionalization is realized via the attachment of the ethylenedinitrobenzoyl (EDNB) molecule to the GNFs. Simulation and experimental results show that such nanoscale modification greatly influences the density of states near the Fermi level. Consequently, the GNF-EDNB blend presents favorable highest occupied molecular orbital and lowest unoccupied molecular orbital energy levels to function as a bridge structure between the poly[N-9′-heptadecanyl-2,7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole)] (PCDTBT) and the [6,6]-phenyl-C71-butyric-acid-methyl-ester (PC71BM). The improved exciton dissociation and charge transport are associated with the better energy level alignment of the ternary blend and the high electrical conductivity of the GNFs, which act as additional electron transport channels within the photoactive layer. The resulting PCDTBT/GNF-EDNB/PC71BM ternary organic solar cells, fabricated entirely under ambient conditions, exhibit an average power conversion efficiency enhancement of ≈18% as compared with the binary blend PCDTBT/PC71BM.},\n bibtype = {article},\n author = {Bonaccorso, F. and Balis, N. and Stylianakis, M.M. and Savarese, M. and Adamo, C. and Gemmi, M. and Pellegrini, V. and Stratakis, E. and Kymakis, E.},\n journal = {Advanced Functional Materials},\n number = {25}\n}","author_short":["Bonaccorso, F.","Balis, N.","Stylianakis, M.","Savarese, M.","Adamo, C.","Gemmi, M.","Pellegrini, V.","Stratakis, E.","Kymakis, E."],"bibbaseid":"bonaccorso-balis-stylianakis-savarese-adamo-gemmi-pellegrini-stratakis-etal-functionalizedgrapheneasanelectroncascadeacceptorforairprocessedorganicternarysolarcells-2015","role":"author","urls":{},"keyword":["bulk heterojunctions","graphene","nanoflakes","organic photovoltaics","ternary blends"],"downloads":0},"bibtype":"article","creationDate":"2021-01-14T18:40:54.184Z","downloads":0,"keywords":["bulk heterojunctions","graphene","nanoflakes","organic photovoltaics","ternary blends"],"search_terms":["functionalized","graphene","electron","cascade","acceptor","air","processed","organic","ternary","solar","cells","bonaccorso","balis","stylianakis","savarese","adamo","gemmi","pellegrini","stratakis","kymakis"],"title":"Functionalized Graphene as an Electron-Cascade Acceptor for Air-Processed Organic Ternary Solar Cells","year":2015}