Spin transition in a ferrous chloride complex supported by a pentapyridine ligand. Boniolo, M., Shylin, S. I., Chernev, P., Cheah, M. H., Heizmann, P. A., Huang, P., Salhi, N., Hossain, K., Thapper, A., Lundberg, M., & Messinger, J. Chemical Communications, 56(18):2703–2706, March, 2020. Publisher: The Royal Society of ChemistryPaper doi abstract bibtex Ferrous chloride complexes [FeIILxCl] commonly attain a high-spin state independently of the supporting ligand(s) and temperature. Herein, we present the first report of a complete spin crossover with T1/2 = 80 K in [FeII(Py5OH)Cl]+ (Py5OH = pyridine-2,6-diylbis[di(pyridin-2-yl)methanol]). Both spin forms of the complex are analyzed by X-ray spectroscopy and DFT calculations.
@article{boniolo_spin_2020,
title = {Spin transition in a ferrous chloride complex supported by a pentapyridine ligand},
volume = {56},
issn = {1364-548X},
url = {https://pubs.rsc.org/en/content/articlelanding/2020/cc/c9cc09630b},
doi = {10.1039/C9CC09630B},
abstract = {Ferrous chloride complexes [FeIILxCl] commonly attain a high-spin state independently of the supporting ligand(s) and temperature. Herein, we present the first report of a complete spin crossover with T1/2 = 80 K in [FeII(Py5OH)Cl]+ (Py5OH = pyridine-2,6-diylbis[di(pyridin-2-yl)methanol]). Both spin forms of the complex are analyzed by X-ray spectroscopy and DFT calculations.},
language = {en},
number = {18},
urldate = {2024-10-16},
journal = {Chemical Communications},
author = {Boniolo, Manuel and Shylin, Sergii I. and Chernev, Petko and Cheah, Mun Hon and Heizmann, Philipp A. and Huang, Ping and Salhi, Nessima and Hossain, Kamal and Thapper, Anders and Lundberg, Marcus and Messinger, Johannes},
month = mar,
year = {2020},
note = {Publisher: The Royal Society of Chemistry},
pages = {2703--2706},
}
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