Some pH-controlling redox reactions in natural waters. Bostrom, K. 1967.
abstract   bibtex   
Using stoichiomtric model systems, it can be shown that some naturally occurring redox processes have a pronounced pH-controlling action, even in the presence of substances that act as buffers. High pH values can be reached particularly in systems where higher metal oxides act as oxidizers whereas an acid condition often develops when free oxygen is the oxidizer. However, in most natural systems carbonates and siliates have a more pronounced pH controlling effect than redox processes.
@article{ bostrom_ph-controlling_1967,
  title = {Some {pH}-controlling redox reactions in natural waters.},
  shorttitle = {Some {pH}-controlling redox reactions in natural waters.},
  abstract = {Using stoichiomtric model systems, it can be shown that some naturally occurring redox processes have a pronounced {pH}-controlling action, even in the presence of substances that act as buffers. High {pH} values can be reached particularly in systems where higher metal oxides act as oxidizers whereas an acid condition often develops when free oxygen is the oxidizer. However, in most natural systems carbonates and siliates have a more pronounced {pH} controlling effect than redox processes.},
  author = {Bostrom, K.},
  year = {1967},
  pages = {286--311}
}

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