@article{ ISI:000312061000045,
Author = {Botas, Cristina and Alvarez, Patricia and Blanco, Clara and Dolores
   Gutierrez, M. and Ares, Pablo and Zamani, Reza and Arbiol, Jordi and
   Morante, Joan R. and Menendez, Rosa},
Title = {{Tailored graphene materials by chemical reduction of graphene oxides of
   different atomic structure}},
Journal = {{RSC ADVANCES}},
Year = {{2012}},
Volume = {{2}},
Number = {{25}},
Pages = {{9643-9650}},
Abstract = {{Graphene materials with different characteristics in terms of sheet size
   and defects (structural and/or functional groups) were obtained by the
   reduction with hydrazine of two graphene oxides with similar oxygen
   content, but with functional groups of different type and location. The
   oxides were prepared from two synthetic graphites with distinct
   crystalline structure. Our research has obtained experimental evidence
   of a greater reactivity of the oxygen functional groups located in the
   interior of the aromatic domains on the basal planes (mainly epoxy) and
   a lower reactivity of oxygen functional groups located at the edges
   (mainly carboxyl and OH). Furthermore, these edge-located groups were
   found to be responsible for hydrogen bonding lateral interactions
   between sheets (these occur through the residual OH groups), which cause
   a substantial increase in the size of the reduced graphene oxide with
   respect to that of the parent graphene oxide. These results offer a way
   to tailor the characteristics of graphene materials for diverse
   applications.}},
DOI = {{10.1039/c2ra21447d}},
ISSN = {{2046-2069}},
ResearcherID-Numbers = {{Morante, Joan Ramon/J-2375-2012
   Ares, Pablo/N-2272-2017
   Alvarez, Patricia/G-1038-2016
   Blanco, Clara/Q-1846-2019
   Botas, Cristina/L-8206-2014
   Zamani, Reza/L-5079-2014
   Gutierrez, Dolores/K-9783-2017
   Morante, Joan-Ramon/A-4480-2014
   Arbiol, Jordi/B-6048-2008}},
ORCID-Numbers = {{Ares, Pablo/0000-0001-5905-540X
   Alvarez, Patricia/0000-0001-9676-0546
   Blanco, Clara/0000-0002-0922-1980
   Botas, Cristina/0000-0002-7600-6324
   Zamani, Reza/0000-0001-6940-0000
   Gutierrez, Dolores/0000-0003-3565-0671
   Morante, Joan-Ramon/0000-0002-4981-4633
   Arbiol, Jordi/0000-0002-0695-1726}},
Unique-ID = {{ISI:000312061000045}},
}

{"_id":"nJb7LLgk2YHSwkw55","bibbaseid":"botas-alvarez-blanco-doloresgutierrez-ares-zamani-arbiol-morante-etal-tailoredgraphenematerialsbychemicalreductionofgrapheneoxidesofdifferentatomicstructure-2012","authorIDs":[],"author_short":["Botas, C.","Alvarez, P.","Blanco, C.","Dolores Gutierrez, M.","Ares, P.","Zamani, R.","Arbiol, J.","Morante, J. R.","Menendez, R."],"bibdata":{"bibtype":"article","type":"article","author":[{"propositions":[],"lastnames":["Botas"],"firstnames":["Cristina"],"suffixes":[]},{"propositions":[],"lastnames":["Alvarez"],"firstnames":["Patricia"],"suffixes":[]},{"propositions":[],"lastnames":["Blanco"],"firstnames":["Clara"],"suffixes":[]},{"propositions":[],"lastnames":["Dolores","Gutierrez"],"firstnames":["M."],"suffixes":[]},{"propositions":[],"lastnames":["Ares"],"firstnames":["Pablo"],"suffixes":[]},{"propositions":[],"lastnames":["Zamani"],"firstnames":["Reza"],"suffixes":[]},{"propositions":[],"lastnames":["Arbiol"],"firstnames":["Jordi"],"suffixes":[]},{"propositions":[],"lastnames":["Morante"],"firstnames":["Joan","R."],"suffixes":[]},{"propositions":[],"lastnames":["Menendez"],"firstnames":["Rosa"],"suffixes":[]}],"title":"Tailored graphene materials by chemical reduction of graphene oxides of different atomic structure","journal":"RSC ADVANCES","year":"2012","volume":"2","number":"25","pages":"9643-9650","abstract":"Graphene materials with different characteristics in terms of sheet size and defects (structural and/or functional groups) were obtained by the reduction with hydrazine of two graphene oxides with similar oxygen content, but with functional groups of different type and location. The oxides were prepared from two synthetic graphites with distinct crystalline structure. Our research has obtained experimental evidence of a greater reactivity of the oxygen functional groups located in the interior of the aromatic domains on the basal planes (mainly epoxy) and a lower reactivity of oxygen functional groups located at the edges (mainly carboxyl and OH). Furthermore, these edge-located groups were found to be responsible for hydrogen bonding lateral interactions between sheets (these occur through the residual OH groups), which cause a substantial increase in the size of the reduced graphene oxide with respect to that of the parent graphene oxide. These results offer a way to tailor the characteristics of graphene materials for diverse applications.","doi":"10.1039/c2ra21447d","issn":"2046-2069","researcherid-numbers":"Morante, Joan Ramon/J-2375-2012 Ares, Pablo/N-2272-2017 Alvarez, Patricia/G-1038-2016 Blanco, Clara/Q-1846-2019 Botas, Cristina/L-8206-2014 Zamani, Reza/L-5079-2014 Gutierrez, Dolores/K-9783-2017 Morante, Joan-Ramon/A-4480-2014 Arbiol, Jordi/B-6048-2008","orcid-numbers":"Ares, Pablo/0000-0001-5905-540X Alvarez, Patricia/0000-0001-9676-0546 Blanco, Clara/0000-0002-0922-1980 Botas, Cristina/0000-0002-7600-6324 Zamani, Reza/0000-0001-6940-0000 Gutierrez, Dolores/0000-0003-3565-0671 Morante, Joan-Ramon/0000-0002-4981-4633 Arbiol, Jordi/0000-0002-0695-1726","unique-id":"ISI:000312061000045","bibtex":"@article{ ISI:000312061000045,\nAuthor = {Botas, Cristina and Alvarez, Patricia and Blanco, Clara and Dolores\n Gutierrez, M. and Ares, Pablo and Zamani, Reza and Arbiol, Jordi and\n Morante, Joan R. and Menendez, Rosa},\nTitle = {{Tailored graphene materials by chemical reduction of graphene oxides of\n different atomic structure}},\nJournal = {{RSC ADVANCES}},\nYear = {{2012}},\nVolume = {{2}},\nNumber = {{25}},\nPages = {{9643-9650}},\nAbstract = {{Graphene materials with different characteristics in terms of sheet size\n and defects (structural and/or functional groups) were obtained by the\n reduction with hydrazine of two graphene oxides with similar oxygen\n content, but with functional groups of different type and location. The\n oxides were prepared from two synthetic graphites with distinct\n crystalline structure. Our research has obtained experimental evidence\n of a greater reactivity of the oxygen functional groups located in the\n interior of the aromatic domains on the basal planes (mainly epoxy) and\n a lower reactivity of oxygen functional groups located at the edges\n (mainly carboxyl and OH). Furthermore, these edge-located groups were\n found to be responsible for hydrogen bonding lateral interactions\n between sheets (these occur through the residual OH groups), which cause\n a substantial increase in the size of the reduced graphene oxide with\n respect to that of the parent graphene oxide. These results offer a way\n to tailor the characteristics of graphene materials for diverse\n applications.}},\nDOI = {{10.1039/c2ra21447d}},\nISSN = {{2046-2069}},\nResearcherID-Numbers = {{Morante, Joan Ramon/J-2375-2012\n Ares, Pablo/N-2272-2017\n Alvarez, Patricia/G-1038-2016\n Blanco, Clara/Q-1846-2019\n Botas, Cristina/L-8206-2014\n Zamani, Reza/L-5079-2014\n Gutierrez, Dolores/K-9783-2017\n Morante, Joan-Ramon/A-4480-2014\n Arbiol, Jordi/B-6048-2008}},\nORCID-Numbers = {{Ares, Pablo/0000-0001-5905-540X\n Alvarez, Patricia/0000-0001-9676-0546\n Blanco, Clara/0000-0002-0922-1980\n Botas, Cristina/0000-0002-7600-6324\n Zamani, Reza/0000-0001-6940-0000\n Gutierrez, Dolores/0000-0003-3565-0671\n Morante, Joan-Ramon/0000-0002-4981-4633\n Arbiol, Jordi/0000-0002-0695-1726}},\nUnique-ID = {{ISI:000312061000045}},\n}\n\n","author_short":["Botas, C.","Alvarez, P.","Blanco, C.","Dolores Gutierrez, M.","Ares, P.","Zamani, R.","Arbiol, J.","Morante, J. R.","Menendez, R."],"key":"ISI:000312061000045","id":"ISI:000312061000045","bibbaseid":"botas-alvarez-blanco-doloresgutierrez-ares-zamani-arbiol-morante-etal-tailoredgraphenematerialsbychemicalreductionofgrapheneoxidesofdifferentatomicstructure-2012","role":"author","urls":{},"downloads":0},"bibtype":"article","biburl":"http://nanotec.cnr.it/data/nanotec/nanotec-full.bib","creationDate":"2020-04-22T21:25:44.334Z","downloads":0,"keywords":[],"search_terms":["tailored","graphene","materials","chemical","reduction","graphene","oxides","different","atomic","structure","botas","alvarez","blanco","dolores gutierrez","ares","zamani","arbiol","morante","menendez"],"title":"Tailored graphene materials by chemical reduction of graphene oxides of different atomic structure","year":2012,"dataSources":["ZTEbWc6bW5f9DTsjF"]}