The synthesis and characterisation of diacidobis(ethylenediamine) ruthenium(III) complexes and related compounds. Broomhead, J. A. & Kane-Maguire, L. A. P. Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry, 1967. doi abstract bibtex New ruthenium(III) complexes of the type [RuX2en2] A(en = ethylenediamine, X2 = C2O4, Cl H 2O, Cl l, Cl2, Br2, or l2; A = Cl, Br, l, ClO4, or p-Me·C6H4·SO 2·O) have been isolated, together with complexes of the related ligands triethylenetramine and optically active propylenediamine. Magnetic susceptibilities show that all the compounds have the spin-paired d5 configuration. The cation [RuCl2en2] + has been resolved into its optical enantiomorphs, and its structure related to that of other bis(ethylenediamine)ruthenium(III) compounds, all of which are assigned a cis configuration. Ultraviolet, visible, and infrared spectra are reported, and the use of infrared spectra in the detection of geometrical isomerism is discussed. New mono-ethylenediamine complexes [RuX 4en]- have been isolated in combination with the cations [RuX2en2]+ and (phen H)+ (phen = 1,10-phenanthroline; X = Cl, Br, l, or 1/2;C2O4).
@article{broomhead_synthesis_1967,
title = {The synthesis and characterisation of diacidobis(ethylenediamine) ruthenium({III}) complexes and related compounds},
issn = {00224944},
doi = {10.1039/J19670000546},
abstract = {New ruthenium(III) complexes of the type [RuX2en2] A(en = ethylenediamine, X2 = C2O4, Cl H 2O, Cl l, Cl2, Br2, or l2; A = Cl, Br, l, ClO4, or p-Me·C6H4·SO 2·O) have been isolated, together with complexes of the related ligands triethylenetramine and optically active propylenediamine. Magnetic susceptibilities show that all the compounds have the spin-paired d5 configuration. The cation [RuCl2en2] + has been resolved into its optical enantiomorphs, and its structure related to that of other bis(ethylenediamine)ruthenium(III) compounds, all of which are assigned a cis configuration. Ultraviolet, visible, and infrared spectra are reported, and the use of infrared spectra in the detection of geometrical isomerism is discussed. New mono-ethylenediamine complexes [RuX 4en]- have been isolated in combination with the cations [RuX2en2]+ and (phen H)+ (phen = 1,10-phenanthroline; X = Cl, Br, l, or 1/2;C2O4).},
number = {546},
journal = {Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry},
author = {Broomhead, John A. and Kane-Maguire, L. A. P.},
year = {1967},
pages = {546--553},
}
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