Pickering stabilized miniemulsion polymerization: Preparation of clay armored latexes. Cauvin, S., Colver, P., J., & Bon, S., A., F. Macromolecules, 38(19):7887-7889, American Chemical Society, 9, 2005.
Pickering stabilized miniemulsion polymerization: Preparation of clay armored latexes [link]Website  doi  abstract   bibtex   1 download  
Laponite clay armored latex particles of polystyrene made via a Pickering\nstabilized miniemulsion polymerization of monomer filled Laponite\ncolloidosomes of submicron dimensions were prepared. Relatively stable\nPickering emulsions were obtained when styrene was replaced by methyl\nor ethyl methacrylate and when 16.7% of 4-vinylpyridine was added\nas cationic comonomer. Polystyrene latex particles with an approximate\naverage diameter of 145 nm, armored with Laponite RD clay particles,\nwere successfully prepared. It was shown that aqueous phase polymerization\nevents should be kept to a minimum, since both the use of water-soluble\ninitiators and more polar monomers resulted in partial conversion\nand coagulation.
@article{
 title = {Pickering stabilized miniemulsion polymerization: Preparation of clay armored latexes},
 type = {article},
 year = {2005},
 pages = {7887-7889},
 volume = {38},
 websites = {http://dx.doi.org/10.1021/ma051070z},
 month = {9},
 publisher = {American Chemical Society},
 id = {119af17a-269f-3afa-8ab3-981fef35ffbc},
 created = {2024-01-02T14:09:46.936Z},
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 abstract = {Laponite clay armored latex particles of polystyrene made via a Pickering\nstabilized miniemulsion polymerization of monomer filled Laponite\ncolloidosomes of submicron dimensions were prepared. Relatively stable\nPickering emulsions were obtained when styrene was replaced by methyl\nor ethyl methacrylate and when 16.7% of 4-vinylpyridine was added\nas cationic comonomer. Polystyrene latex particles with an approximate\naverage diameter of 145 nm, armored with Laponite RD clay particles,\nwere successfully prepared. It was shown that aqueous phase polymerization\nevents should be kept to a minimum, since both the use of water-soluble\ninitiators and more polar monomers resulted in partial conversion\nand coagulation.},
 bibtype = {article},
 author = {Cauvin, Séverine and Colver, Patrick J. and Bon, Stefan A F},
 doi = {10.1021/ma051070z},
 journal = {Macromolecules},
 number = {19}
}

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