The evolution of helium from aged Zr tritides: A thermal helium desorption spectrometry study. Cheng, G. J., Huang, G., Chen, M., Zhou, X. S., Liu, J. H., Peng, S. M., Ding, W., Wang, H. F., & Shi, L. Q. Journal of Nuclear Materials, 499:490–495, 2018. 00005 tex.ids= CHENG2018a, Cheng2018
doi  abstract   bibtex   
The evolution of He from Zr-tritides was investigated for aging times up to about 6.5 years using analytical thermal helium desorption spectrometry (THDS). Zr films were deposited onto Mo substrates and then converted into Zr-tritides (ZrT1.70∼1.95) inside a tritiding apparatus loaded with pure tritium gas. During aging, there are at least five forms of He in Zr-tritides, and more than 99% of He atoms are in the form of He bubbles. The isolated He bubbles in lattices begin to link with each other when the He/Zr atom ratio reaches about 0.21, and are connected to grain boundaries or dislocation networks at He concentration of He/Zr ≈ 0.26. An interconnected system of channels decorated by bubbles evolves from the network dislocations, dislocation loops and internal boundaries. These He filled networks are formed completely when the He/Zr atom ratio is about 0.38. Once the He/Zr reached about 0.45, the networks of He bubble penetrate to the film surface and He begins an “accelerated release”. This critical ratio of He to Zr for He accelerated release is much greater than that found previously for Ti-tritides (0.23–0.30). The difference of He retention in Zr-tritides and Ti-tritides was also discussed in this paper.
@article{cheng_evolution_2018,
	title = {The evolution of helium from aged {Zr} tritides: {A} thermal helium desorption spectrometry study},
	volume = {499},
	issn = {0022-3115},
	doi = {10/gc4fch},
	abstract = {The evolution of He from Zr-tritides was investigated for aging times up to about 6.5 years using analytical thermal helium desorption spectrometry (THDS). Zr films were deposited onto Mo substrates and then converted into Zr-tritides (ZrT1.70∼1.95) inside a tritiding apparatus loaded with pure tritium gas. During aging, there are at least five forms of He in Zr-tritides, and more than 99\% of He atoms are in the form of He bubbles. The isolated He bubbles in lattices begin to link with each other when the He/Zr atom ratio reaches about 0.21, and are connected to grain boundaries or dislocation networks at He concentration of He/Zr ≈ 0.26. An interconnected system of channels decorated by bubbles evolves from the network dislocations, dislocation loops and internal boundaries. These He filled networks are formed completely when the He/Zr atom ratio is about 0.38. Once the He/Zr reached about 0.45, the networks of He bubble penetrate to the film surface and He begins an “accelerated release”. This critical ratio of He to Zr for He accelerated release is much greater than that found previously for Ti-tritides (0.23–0.30). The difference of He retention in Zr-tritides and Ti-tritides was also discussed in this paper.},
	journal = {Journal of Nuclear Materials},
	author = {Cheng, G. J. and Huang, G. and Chen, M. and Zhou, X. S. and Liu, J. H. and Peng, S. M. and Ding, W. and Wang, H. F. and Shi, L. Q.},
	year = {2018},
	note = {00005
tex.ids= CHENG2018a, Cheng2018},
	pages = {490--495},
}

Downloads: 0