@article{
 title = {Kinetics of the gas-phase reactions of NO3 radicals with a series of alcohols, glycol ethers, ethers and chloroalkenes},
 type = {article},
 year = {1998},
 pages = {1083-1089},
 volume = {94},
 id = {4cbcbf0f-91fe-389f-b894-497ca3f17eae},
 created = {2015-05-08T02:27:44.000Z},
 file_attached = {false},
 profile_id = {f8c267c4-4c39-31dc-80fa-3a9691373386},
 group_id = {63e349d6-2c70-3938-9e67-2f6483f6cbab},
 last_modified = {2015-05-08T12:58:09.000Z},
 read = {false},
 starred = {false},
 authored = {false},
 confirmed = {true},
 hidden = {false},
 source_type = {Journal Article},
 notes = {<m:note>Article</m:note>},
 abstract = {Using a relative rate method, rate constants have been measured for the gas-phase reactions of the NO3 radical with methacrolein, a series of ethers, glycol ethers, alcohols and chloroalkenes at 298 +/- 2 K and atmospheric pressure of air. The rate constants determined tin units of 10(-16) cm(3) molecule(-1) s(-1)) were: methacrolein, 33 +/- 10; diethyl ether, 31 +/- 10; di-n-propyl ether, 49 +/- 16; diisopropyl ether, 40 +/- 13; ethyl tert-butyl ether, 45 +/- 14; 1- methoxypropan-2-ol, less than or equal to 15 +/- 5; 2- butoxyethanol, less than or equal to 31 +/- 11; propan-1-ol, less than or equal to 21 +/- 8; propan-2-ol, less than or equal to 17 +/- 6; butan-1-ol, less than or equal to 27 +/- 10; butan-2-ol, less than or equal to 25 +/- 8; heptan-4-ol, less than or equal to 60 +/- 20; cis-1,2-dichloroethene, 1.3 +/- 1.3; 1,1-dichloroethene, 18(-6)(+9); trichloroethene, 3.6(- 1.5)(+2.0); tetrachloroethene, <1.8; and 3-chloropropene, 5.8(- 2.0)(+3.0). Carbonyl products of the alcohol reactions arising after H-atom abstraction at the carbon atom to which the -OH group is attached were observed, and rate constants for this reaction pathway obtained. Significant discrepancies with the literature concern propan-2-ol, ethyl tert-butyl ether and 3- chloropropene, with our relative rate constants for these compounds being factors of ca. 2, ca. 2, and ca. 8 lower, respectively, than previously reported absolute rate constant determinations.},
 bibtype = {article},
 author = {Chew, A A and Atkinson, R and Aschmann, S M},
 journal = {Journal of the Chemical Society-Faraday Transactions},
 number = {8}
}

{"_id":"HyR4HQbMyRopEbWSw","bibbaseid":"chew-atkinson-aschmann-kineticsofthegasphasereactionsofno3radicalswithaseriesofalcoholsglycolethersethersandchloroalkenes-1998","downloads":0,"creationDate":"2017-01-12T21:32:09.178Z","title":"Kinetics of the gas-phase reactions of NO3 radicals with a series of alcohols, glycol ethers, ethers and chloroalkenes","author_short":["Chew, A., A.","Atkinson, R.","Aschmann, S., M."],"year":1998,"bibtype":"article","biburl":null,"bibdata":{"title":"Kinetics of the gas-phase reactions of NO3 radicals with a series of alcohols, glycol ethers, ethers and chloroalkenes","type":"article","year":"1998","pages":"1083-1089","volume":"94","id":"4cbcbf0f-91fe-389f-b894-497ca3f17eae","created":"2015-05-08T02:27:44.000Z","file_attached":false,"profile_id":"f8c267c4-4c39-31dc-80fa-3a9691373386","group_id":"63e349d6-2c70-3938-9e67-2f6483f6cbab","last_modified":"2015-05-08T12:58:09.000Z","read":false,"starred":false,"authored":false,"confirmed":"true","hidden":false,"source_type":"Journal Article","notes":"<m:note>Article</m:note>","abstract":"Using a relative rate method, rate constants have been measured for the gas-phase reactions of the NO3 radical with methacrolein, a series of ethers, glycol ethers, alcohols and chloroalkenes at 298 +/- 2 K and atmospheric pressure of air. The rate constants determined tin units of 10(-16) cm(3) molecule(-1) s(-1)) were: methacrolein, 33 +/- 10; diethyl ether, 31 +/- 10; di-n-propyl ether, 49 +/- 16; diisopropyl ether, 40 +/- 13; ethyl tert-butyl ether, 45 +/- 14; 1- methoxypropan-2-ol, less than or equal to 15 +/- 5; 2- butoxyethanol, less than or equal to 31 +/- 11; propan-1-ol, less than or equal to 21 +/- 8; propan-2-ol, less than or equal to 17 +/- 6; butan-1-ol, less than or equal to 27 +/- 10; butan-2-ol, less than or equal to 25 +/- 8; heptan-4-ol, less than or equal to 60 +/- 20; cis-1,2-dichloroethene, 1.3 +/- 1.3; 1,1-dichloroethene, 18(-6)(+9); trichloroethene, 3.6(- 1.5)(+2.0); tetrachloroethene, <1.8; and 3-chloropropene, 5.8(- 2.0)(+3.0). Carbonyl products of the alcohol reactions arising after H-atom abstraction at the carbon atom to which the -OH group is attached were observed, and rate constants for this reaction pathway obtained. Significant discrepancies with the literature concern propan-2-ol, ethyl tert-butyl ether and 3- chloropropene, with our relative rate constants for these compounds being factors of ca. 2, ca. 2, and ca. 8 lower, respectively, than previously reported absolute rate constant determinations.","bibtype":"article","author":"Chew, A A and Atkinson, R and Aschmann, S M","journal":"Journal of the Chemical Society-Faraday Transactions","number":"8","bibtex":"@article{\n title = {Kinetics of the gas-phase reactions of NO3 radicals with a series of alcohols, glycol ethers, ethers and chloroalkenes},\n type = {article},\n year = {1998},\n pages = {1083-1089},\n volume = {94},\n id = {4cbcbf0f-91fe-389f-b894-497ca3f17eae},\n created = {2015-05-08T02:27:44.000Z},\n file_attached = {false},\n profile_id = {f8c267c4-4c39-31dc-80fa-3a9691373386},\n group_id = {63e349d6-2c70-3938-9e67-2f6483f6cbab},\n last_modified = {2015-05-08T12:58:09.000Z},\n read = {false},\n starred = {false},\n authored = {false},\n confirmed = {true},\n hidden = {false},\n source_type = {Journal Article},\n notes = {<m:note>Article</m:note>},\n abstract = {Using a relative rate method, rate constants have been measured for the gas-phase reactions of the NO3 radical with methacrolein, a series of ethers, glycol ethers, alcohols and chloroalkenes at 298 +/- 2 K and atmospheric pressure of air. The rate constants determined tin units of 10(-16) cm(3) molecule(-1) s(-1)) were: methacrolein, 33 +/- 10; diethyl ether, 31 +/- 10; di-n-propyl ether, 49 +/- 16; diisopropyl ether, 40 +/- 13; ethyl tert-butyl ether, 45 +/- 14; 1- methoxypropan-2-ol, less than or equal to 15 +/- 5; 2- butoxyethanol, less than or equal to 31 +/- 11; propan-1-ol, less than or equal to 21 +/- 8; propan-2-ol, less than or equal to 17 +/- 6; butan-1-ol, less than or equal to 27 +/- 10; butan-2-ol, less than or equal to 25 +/- 8; heptan-4-ol, less than or equal to 60 +/- 20; cis-1,2-dichloroethene, 1.3 +/- 1.3; 1,1-dichloroethene, 18(-6)(+9); trichloroethene, 3.6(- 1.5)(+2.0); tetrachloroethene, <1.8; and 3-chloropropene, 5.8(- 2.0)(+3.0). Carbonyl products of the alcohol reactions arising after H-atom abstraction at the carbon atom to which the -OH group is attached were observed, and rate constants for this reaction pathway obtained. Significant discrepancies with the literature concern propan-2-ol, ethyl tert-butyl ether and 3- chloropropene, with our relative rate constants for these compounds being factors of ca. 2, ca. 2, and ca. 8 lower, respectively, than previously reported absolute rate constant determinations.},\n bibtype = {article},\n author = {Chew, A A and Atkinson, R and Aschmann, S M},\n journal = {Journal of the Chemical Society-Faraday Transactions},\n number = {8}\n}","author_short":["Chew, A., A.","Atkinson, R.","Aschmann, S., M."],"bibbaseid":"chew-atkinson-aschmann-kineticsofthegasphasereactionsofno3radicalswithaseriesofalcoholsglycolethersethersandchloroalkenes-1998","role":"author","urls":{},"downloads":0},"search_terms":["kinetics","gas","phase","reactions","no3","radicals","series","alcohols","glycol","ethers","ethers","chloroalkenes","chew","atkinson","aschmann"],"keywords":[],"authorIDs":[]}