@article{choi_two_2018,
	title = {Two dimensional {Zn}-stilbenedicarboxylic acid ({SDC}) metal-organic frameworks for cyclic carbonate synthesis from {CO}$_{\textrm{2}}$ and epoxides},
	volume = {35},
	issn = {0256-1115, 1975-7220},
	url = {http://link.springer.com/10.1007/s11814-018-0023-y},
	doi = {10.1007/s11814-018-0023-y},
	abstract = {A two-dimensional Zn-based metal-organic framework has been synthesized by using Zn(II) ions and H2SDC (4,4'-stilbenedicarboxylic acid) under solvothermal conditions. The framework having a trinuclear Zn3-(RCO2)6 SBUs connected by the 4,4'-stilbenedicarboxylic acid to form a hexagonal network, shows a two-dimensional structure and displays high thermal stability up to approximately 330 oC. The role of Zn2+ (from Zn-SDC) for epoxide activation and Br- ion (from TBABr) for ring opening of epoxide was studied for the cycloaddition reaction of CO2 and propylene oxide (PO) under ambient conditions. Zn-SDC was found catalytically efficient towards CO2-epoxide coupling under ambient reaction conditions with high selectivity towards the desired cyclic carbonates under solvent-free conditions. The effects of various reaction parameters such as catalyst loading, temperature, CO2 pressure, and time were evaluated. Zn-SDC was easily separable and reusable at least five times without any considerable loss in the initial activity. A plausible reaction mechanism for the cycloaddition reaction was also proposed based on literature and experimental inferences.},
	language = {en},
	number = {6},
	urldate = {2021-02-26},
	journal = {Korean Journal of Chemical Engineering},
	author = {Choi, Gak-Gyu and Kurisingal, Jintu Francis and Chung, Yongchul G. and Park, Dae-Won},
	month = jun,
	year = {2018},
	pages = {1373--1379},
}

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The framework having a trinuclear Zn3-(RCO2)6 SBUs connected by the 4,4'-stilbenedicarboxylic acid to form a hexagonal network, shows a two-dimensional structure and displays high thermal stability up to approximately 330 oC. The role of Zn2+ (from Zn-SDC) for epoxide activation and Br- ion (from TBABr) for ring opening of epoxide was studied for the cycloaddition reaction of CO2 and propylene oxide (PO) under ambient conditions. Zn-SDC was found catalytically efficient towards CO2-epoxide coupling under ambient reaction conditions with high selectivity towards the desired cyclic carbonates under solvent-free conditions. The effects of various reaction parameters such as catalyst loading, temperature, CO2 pressure, and time were evaluated. Zn-SDC was easily separable and reusable at least five times without any considerable loss in the initial activity. A plausible reaction mechanism for the cycloaddition reaction was also proposed based on literature and experimental inferences.","language":"en","number":"6","urldate":"2021-02-26","journal":"Korean Journal of Chemical Engineering","author":[{"propositions":[],"lastnames":["Choi"],"firstnames":["Gak-Gyu"],"suffixes":[]},{"propositions":[],"lastnames":["Kurisingal"],"firstnames":["Jintu","Francis"],"suffixes":[]},{"propositions":[],"lastnames":["Chung"],"firstnames":["Yongchul","G."],"suffixes":[]},{"propositions":[],"lastnames":["Park"],"firstnames":["Dae-Won"],"suffixes":[]}],"month":"June","year":"2018","pages":"1373–1379","bibtex":"@article{choi_two_2018,\n\ttitle = {Two dimensional {Zn}-stilbenedicarboxylic acid ({SDC}) metal-organic frameworks for cyclic carbonate synthesis from {CO}$_{\\textrm{2}}$ and epoxides},\n\tvolume = {35},\n\tissn = {0256-1115, 1975-7220},\n\turl = {http://link.springer.com/10.1007/s11814-018-0023-y},\n\tdoi = {10.1007/s11814-018-0023-y},\n\tabstract = {A two-dimensional Zn-based metal-organic framework has been synthesized by using Zn(II) ions and H2SDC (4,4'-stilbenedicarboxylic acid) under solvothermal conditions. The framework having a trinuclear Zn3-(RCO2)6 SBUs connected by the 4,4'-stilbenedicarboxylic acid to form a hexagonal network, shows a two-dimensional structure and displays high thermal stability up to approximately 330 oC. The role of Zn2+ (from Zn-SDC) for epoxide activation and Br- ion (from TBABr) for ring opening of epoxide was studied for the cycloaddition reaction of CO2 and propylene oxide (PO) under ambient conditions. Zn-SDC was found catalytically efficient towards CO2-epoxide coupling under ambient reaction conditions with high selectivity towards the desired cyclic carbonates under solvent-free conditions. The effects of various reaction parameters such as catalyst loading, temperature, CO2 pressure, and time were evaluated. Zn-SDC was easily separable and reusable at least five times without any considerable loss in the initial activity. 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