Photoinduced Heterogeneous C−H Arylation by a Reusable Hybrid Copper Catalyst. Choi, I., Müller, V., Lole, G., Köhler, R., Karius, V., Viöl, W., Jooss, C., & Ackermann, L. Chemistry – A European Journal, 26(16):3509-3514, 2020. Paper doi abstract bibtex Abstract Heterogeneous copper catalysis enabled photoinduced C−H arylations under exceedingly mild conditions at room temperature. The versatile hybrid copper catalyst provided step-economical access to arylated heteroarenes, terpenes and alkaloid natural products with various aryl halides. The hybrid copper catalyst could be reused without significant loss of catalytic efficacy. Detailed studies in terms of TEM, HRTEM and XPS analysis of the hybrid copper catalyst, among others, supported its outstanding stability and reusability.
@article{https://doi.org/10.1002/chem.202000192,
author = {Choi, Isaac and Müller, Valentin and Lole, Gaurav and Köhler, Robert and Karius, Volker and Viöl, Wolfgang and Jooss, Christian and Ackermann, Lutz},
title = {Photoinduced Heterogeneous C−H Arylation by a Reusable Hybrid Copper Catalyst},
journal = {Chemistry – A European Journal},
volume = {26},
number = {16},
pages = {3509-3514},
keywords = {C−H arylation, copper catalysis, heterogeneous catalysis, hybrid catalysis, photocatalysis},
doi = {https://doi.org/10.1002/chem.202000192},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.202000192},
eprint = {https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.202000192},
abstract = {Abstract Heterogeneous copper catalysis enabled photoinduced C−H arylations under exceedingly mild conditions at room temperature. The versatile hybrid copper catalyst provided step-economical access to arylated heteroarenes, terpenes and alkaloid natural products with various aryl halides. The hybrid copper catalyst could be reused without significant loss of catalytic efficacy. Detailed studies in terms of TEM, HRTEM and XPS analysis of the hybrid copper catalyst, among others, supported its outstanding stability and reusability.},
year = {2020}
}
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