Pyridonate-Supported Titanium(III). Benzylamine as an Easy-To-Use Reductant. Chong, E., Xue, W., Storr, T., Kennepohl, P., & Schafer, L., L. Organometallics, 34(20):4941-4945, 10, 2015.
![Pyridonate-Supported Titanium(III). Benzylamine as an Easy-To-Use Reductant [pdf]](https://bibbase.org/img/filetypes/pdf.svg "pdf")
Paper ![Pyridonate-Supported Titanium(III). Benzylamine as an Easy-To-Use Reductant [link]](https://bibbase.org/img/filetypes/link.svg "link")
Website doi abstract bibtex 1 download
Paper Website doi abstract bibtex 1 download The reaction of bis(3-phenyl-2-pyridonate)Ti- (NMe2)2 with excess benzylamine leads to an unexpected reduction of the metal center from Ti(IV) to Ti(III). The reduced titanium species was isolated and revealed as tris(3- phenyl-2-pyridonate)Ti(NH2Bn)2. Ammonia and N-benzyl-1- phenylmethanimine are released as byproducts of the reaction, thereby confirming benzylamine as a mild reductant. This new pyridonate-supported titanium(III) complex has been fully characterized, and experimental data and theoretical calculations confirm a d1 metal center with no ligand-based radical character. This Ti(III) complex does not react with aminoalkenes, suggesting that radical species are not viable intermediates for the hydroaminoalkylation or hydroamination reaction.
@article{
title = {Pyridonate-Supported Titanium(III). Benzylamine as an Easy-To-Use Reductant},
type = {article},
year = {2015},
keywords = {EPR},
pages = {4941-4945},
volume = {34},
websites = {http://pubs.acs.org/doi/10.1021/acs.organomet.5b00469},
month = {10},
day = {26},
id = {d3dbfb8a-9bee-3c2d-9663-83f229a9df3b},
created = {2017-09-06T15:15:20.751Z},
file_attached = {true},
profile_id = {8c5f55f8-b69e-30e2-981b-01f0d567bbfe},
last_modified = {2017-10-19T01:44:52.356Z},
read = {true},
starred = {false},
authored = {true},
confirmed = {true},
hidden = {false},
private_publication = {false},
abstract = {The reaction of bis(3-phenyl-2-pyridonate)Ti- (NMe2)2 with excess benzylamine leads to an unexpected reduction of the metal center from Ti(IV) to Ti(III). The reduced titanium species was isolated and revealed as tris(3- phenyl-2-pyridonate)Ti(NH2Bn)2. Ammonia and N-benzyl-1- phenylmethanimine are released as byproducts of the reaction, thereby confirming benzylamine as a mild reductant. This new pyridonate-supported titanium(III) complex has been fully characterized, and experimental data and theoretical calculations confirm a d1 metal center with no ligand-based radical character. This Ti(III) complex does not react with aminoalkenes, suggesting that radical species are not viable intermediates for the hydroaminoalkylation or hydroamination reaction.},
bibtype = {article},
author = {Chong, Eugene and Xue, Wei and Storr, Tim and Kennepohl, Pierre and Schafer, Laurel L.},
doi = {10.1021/acs.organomet.5b00469},
journal = {Organometallics},
number = {20}
}Downloads: 1
{"_id":"rhK3bRXawvhx67P2X","bibbaseid":"chong-xue-storr-kennepohl-schafer-pyridonatesupportedtitaniumiiibenzylamineasaneasytousereductant-2015","downloads":1,"creationDate":"2015-10-25T10:49:40.424Z","title":"Pyridonate-Supported Titanium(III). Benzylamine as an Easy-To-Use Reductant","author_short":["Chong, E.","Xue, W.","Storr, T.","Kennepohl, P.","Schafer, L., L."],"year":2015,"bibtype":"article","biburl":"https://bibbase.org/service/mendeley/8c5f55f8-b69e-30e2-981b-01f0d567bbfe","bibdata":{"title":"Pyridonate-Supported Titanium(III). Benzylamine as an Easy-To-Use Reductant","type":"article","year":"2015","keywords":"EPR","pages":"4941-4945","volume":"34","websites":"http://pubs.acs.org/doi/10.1021/acs.organomet.5b00469","month":"10","day":"26","id":"d3dbfb8a-9bee-3c2d-9663-83f229a9df3b","created":"2017-09-06T15:15:20.751Z","file_attached":"true","profile_id":"8c5f55f8-b69e-30e2-981b-01f0d567bbfe","last_modified":"2017-10-19T01:44:52.356Z","read":"true","starred":false,"authored":"true","confirmed":"true","hidden":false,"private_publication":false,"abstract":"The reaction of bis(3-phenyl-2-pyridonate)Ti- (NMe2)2 with excess benzylamine leads to an unexpected reduction of the metal center from Ti(IV) to Ti(III). The reduced titanium species was isolated and revealed as tris(3- phenyl-2-pyridonate)Ti(NH2Bn)2. Ammonia and N-benzyl-1- phenylmethanimine are released as byproducts of the reaction, thereby confirming benzylamine as a mild reductant. This new pyridonate-supported titanium(III) complex has been fully characterized, and experimental data and theoretical calculations confirm a d1 metal center with no ligand-based radical character. This Ti(III) complex does not react with aminoalkenes, suggesting that radical species are not viable intermediates for the hydroaminoalkylation or hydroamination reaction.","bibtype":"article","author":"Chong, Eugene and Xue, Wei and Storr, Tim and Kennepohl, Pierre and Schafer, Laurel L.","doi":"10.1021/acs.organomet.5b00469","journal":"Organometallics","number":"20","bibtex":"@article{\n title = {Pyridonate-Supported Titanium(III). Benzylamine as an Easy-To-Use Reductant},\n type = {article},\n year = {2015},\n keywords = {EPR},\n pages = {4941-4945},\n volume = {34},\n websites = {http://pubs.acs.org/doi/10.1021/acs.organomet.5b00469},\n month = {10},\n day = {26},\n id = {d3dbfb8a-9bee-3c2d-9663-83f229a9df3b},\n created = {2017-09-06T15:15:20.751Z},\n file_attached = {true},\n profile_id = {8c5f55f8-b69e-30e2-981b-01f0d567bbfe},\n last_modified = {2017-10-19T01:44:52.356Z},\n read = {true},\n starred = {false},\n authored = {true},\n confirmed = {true},\n hidden = {false},\n private_publication = {false},\n abstract = {The reaction of bis(3-phenyl-2-pyridonate)Ti- (NMe2)2 with excess benzylamine leads to an unexpected reduction of the metal center from Ti(IV) to Ti(III). The reduced titanium species was isolated and revealed as tris(3- phenyl-2-pyridonate)Ti(NH2Bn)2. Ammonia and N-benzyl-1- phenylmethanimine are released as byproducts of the reaction, thereby confirming benzylamine as a mild reductant. This new pyridonate-supported titanium(III) complex has been fully characterized, and experimental data and theoretical calculations confirm a d1 metal center with no ligand-based radical character. This Ti(III) complex does not react with aminoalkenes, suggesting that radical species are not viable intermediates for the hydroaminoalkylation or hydroamination reaction.},\n bibtype = {article},\n author = {Chong, Eugene and Xue, Wei and Storr, Tim and Kennepohl, Pierre and Schafer, Laurel L.},\n doi = {10.1021/acs.organomet.5b00469},\n journal = {Organometallics},\n number = {20}\n}","author_short":["Chong, E.","Xue, W.","Storr, T.","Kennepohl, P.","Schafer, L., L."],"urls":{"Paper":"https://bibbase.org/service/mendeley/8c5f55f8-b69e-30e2-981b-01f0d567bbfe/file/4289968f-f7a0-0d2f-72a2-55dbf7bc12e5/2015___Organometallics___Chong_et_al.pdf.pdf","Website":"http://pubs.acs.org/doi/10.1021/acs.organomet.5b00469"},"biburl":"https://bibbase.org/service/mendeley/8c5f55f8-b69e-30e2-981b-01f0d567bbfe","bibbaseid":"chong-xue-storr-kennepohl-schafer-pyridonatesupportedtitaniumiiibenzylamineasaneasytousereductant-2015","role":"author","keyword":["EPR"],"metadata":{"authorlinks":{"kennepohl, p":"https://bibbase.org/service/mendeley/8c5f55f8-b69e-30e2-981b-01f0d567bbfe"}},"downloads":1,"html":""},"search_terms":["pyridonate","supported","titanium","iii","benzylamine","easy","use","reductant","chong","xue","storr","kennepohl","schafer"],"keywords":["epr"],"authorIDs":["3iLerqnFcxCPMtJpn","4c6QnidJqyh8QxqkX","549f69158e3bca5f370014e6","5de7ed0bc8f9f6df010001e4","5de839c88cf0fbde0100006d","5deacdf2cd660bde01000195","5debd29aca1cdddf01000146","5df7dc76dc100cde010000ff","5e042bf8c51eb3de0100007b","5e07c8ccea5f0bdf010000cf","5e0dc56cc7ca67df01000115","5e0ec889b68da9de01000034","5e0f7abf99975cde0100009e","5e10afd9cfb06ddf0100006d","5e1177267da100de0100012f","5e13d054280ddede0100016e","5e164e4428f1c0de0100031d","5e1693f8da4561de0100001f","5e177475cf35a4de01000031","5e1a947969523cde01000099","5e257428f58a5cde010000f1","5e2882d967e11edf010000ac","5e28f4bc41639df301000044","5e2e93568d5204de0100007e","5e31e94fbba4d0de01000241","5e326d5e5633c9de010000a3","5e342fca41f782de0100012d","5e35488dba591ddf0100008c","5e3665ad4b25bbf2010000d2","5e382dc30691b8de010001ff","5e3c4312c798e0de01000034","5e46844d71278bde010000cc","5e4eb15264b624de010001a8","5e4f912b42a908de010000f4","5e4fbd2d2c51e8de0100008d","5e5d63ddad47bcde01000122","5e5f86ed8d89c5de0100002e","5e5fd8e65241b5de0100001c","5e60ecfe839e59df01000140","5e61652b417d19de01000061","5e64d2ac0b8008df01000036","5e6741214d24a6df01000086","5e676b211dcaf4de010001ef","5e67802710be53de010000fe","5e68480a9cef79de01000273","5e68d91fae547ede010002af","5e69ce636423dfde010001a0","5e6b12e986bf9cde01000035","5e6b62aac024f9de01000010","5e6b9bf038517edf0100001b","79eiZqbXtAgB2qPwQ","7KTqYg8mwkZFhEzQ3","8M6CKnvXwvJZjw5rQ","8ZH5wCb244dTyjZTo","8gLLyGmGk6zrBNnSW","93wznsAiG6N6RWh3W","BdW2bNumN7KSubzZi","Brx9MCCWjaRcQLgmv","BunZ7u5vo6YP89dqC","CdmkqgCC7YQ3nCxbq","DNPrMfAuXetAfDs8R","E5dirXnhp3dj3aHkh","Fj7MuNTuEZrfjfxxi","HJ3Zeg39qQTmYHYt6","JnXN6mSgNQkfpmqTs","KLFz9Quyco9WRMzEo","MQPkCA7hCG5nHRDGK","MvxLkRFmWAmFzJ62x","NLLPFwcypsnqCdjtt","NgvWrQNZ8WSMvaySr","Qu6vBYRGk4HxjEQHP","RLApear4PKw8oDouR","S5uha8vZYCJgdy3wz","SrePPBjyQrYFJYWuq","TGJLqTRjTSCvjnKnM","TLPpMRduCgvt23KNA","ThXjmMxsKShGXGo9R","WCpGFZGKoopYdccrA","WkmF3PHxRiTFvpvMu","X3CoQQujbB6uEfeCq","XKcJSHf8DcpdPnfNm","XmtnqTvJBkZkvLBZP","YfXHeLKqBXYYzPAww","Zsrup8X5fqoNSkFPe","bHfLw2QkQGko4KjYg","cGwiLTEeZWEYwb88s","cqKH7BXTaAZGZDGzc","eDEjrBSoXdYAJegvm","ev4vmj6dMZpbEWwmy","fKj3TXX3ietf3qGt8","fM3TRWpPB6oRA8rB9","i4ftws6i5ecsWkmYD","k4yef9HxWgNCdW8b3","mReJFExBwnFax3ALu","mZCESDX4P5jLi3pce","nm4T2AcjanPHL4Szj","oaugrfPtDqADRQgJ4","ofGYJBrWWZQYsEGFR","pKG2zHMNxFQDkZHyb","rhhh4xdaNHz94oEm2","rrvwjEikXmbdXZkGx","tCt2KazanazJ3yQzz","vdvk9eCQyAxmSxLqs","xeyEua6SaCWFan2H4"],"dataSources":["MwHF28s95RpwxtWh3","ya2CyA73rpZseyrZ8"]}