Experimental evaluation of the cross-sections for the Cs(6D)→Cs(7PJ) and Cs(6D5/2)→Cs(6D3/2) collisional transfer processes induced by He and Ar. Correll, T., L., Horvatić, V., Omenetto, N., Winefordner, J., D., & Vadla, C. Spectrochimica Acta Part B: Atomic Spectroscopy, 61(6):623-633, 6, 2006. Website abstract bibtex The cross-sections for collisional excitation transfer Cs (6 D) over(→, QD 3) Cs (7 P1 / 2) and Cs (6 D) over(→, QD 4) Cs (7 P3 / 2), and fine structure mixing Cs (6 D5 / 2) over(→, Q65) Cs (6 D3 / 2) due to collisions with helium and argon atoms at temperatures in the range between 333 and 367 K were determined using atomic fluorescence. The cross-sections for the processes Cs(6D) + He, Ar → Cs(7PJ) + He, Ar were found to be QD3 He = (0.9 ± 0.4) × 10- 16 cm2, QD4 He = (2.6 ± 1.2) × 10- 16 cm2, QD3 Ar = (1.2 ± 0.6) × 10- 18 cm2 and QD4 Ar = (2.6 ± 1.3) × 10- 18 cm2. These values are consistent with the results obtained at higher temperatures and reported previously. The cross-sections for the He and Ar-induced 6DJ fine-structure mixing were determined to be Q65 He = (54 ± 15) × 10- 16 cm2 and Q65 Ar = (17 ± 5) × 10- 16 cm2 and were found to fit very well into the existing body of cross-section data for intra-multiplet (nP1 / 2 → nP3 / 2; nD5 / 2 → nD3 / 2) mixing in cesium induced by collisions with helium and argon. © 2005 Elsevier B.V. All rights reserved.
@article{
title = {Experimental evaluation of the cross-sections for the Cs(6D)→Cs(7PJ) and Cs(6D5/2)→Cs(6D3/2) collisional transfer processes induced by He and Ar},
type = {article},
year = {2006},
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pages = {623-633},
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month = {6},
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abstract = {The cross-sections for collisional excitation transfer Cs (6 D) over(→, QD 3) Cs (7 P1 / 2) and Cs (6 D) over(→, QD 4) Cs (7 P3 / 2), and fine structure mixing Cs (6 D5 / 2) over(→, Q65) Cs (6 D3 / 2) due to collisions with helium and argon atoms at temperatures in the range between 333 and 367 K were determined using atomic fluorescence. The cross-sections for the processes Cs(6D) + He, Ar → Cs(7PJ) + He, Ar were found to be QD3 He = (0.9 ± 0.4) × 10- 16 cm2, QD4 He = (2.6 ± 1.2) × 10- 16 cm2, QD3 Ar = (1.2 ± 0.6) × 10- 18 cm2 and QD4 Ar = (2.6 ± 1.3) × 10- 18 cm2. These values are consistent with the results obtained at higher temperatures and reported previously. The cross-sections for the He and Ar-induced 6DJ fine-structure mixing were determined to be Q65 He = (54 ± 15) × 10- 16 cm2 and Q65 Ar = (17 ± 5) × 10- 16 cm2 and were found to fit very well into the existing body of cross-section data for intra-multiplet (nP1 / 2 → nP3 / 2; nD5 / 2 → nD3 / 2) mixing in cesium induced by collisions with helium and argon. © 2005 Elsevier B.V. All rights reserved.},
bibtype = {article},
author = {Correll, Tiffany L and Horvatić, Vlasta and Omenetto, Nicoló and Winefordner, James D and Vadla, Cedomil},
journal = {Spectrochimica Acta Part B: Atomic Spectroscopy},
number = {6}
}
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The cross-sections for the processes Cs(6D) + He, Ar → Cs(7PJ) + He, Ar were found to be QD3 He = (0.9 ± 0.4) × 10- 16 cm2, QD4 He = (2.6 ± 1.2) × 10- 16 cm2, QD3 Ar = (1.2 ± 0.6) × 10- 18 cm2 and QD4 Ar = (2.6 ± 1.3) × 10- 18 cm2. These values are consistent with the results obtained at higher temperatures and reported previously. The cross-sections for the He and Ar-induced 6DJ fine-structure mixing were determined to be Q65 He = (54 ± 15) × 10- 16 cm2 and Q65 Ar = (17 ± 5) × 10- 16 cm2 and were found to fit very well into the existing body of cross-section data for intra-multiplet (nP1 / 2 → nP3 / 2; nD5 / 2 → nD3 / 2) mixing in cesium induced by collisions with helium and argon. © 2005 Elsevier B.V. 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