Polymer Functionalization by RAFT Interchange. Courtney, O. R., Clouthier, S. M., Perrier, S., Tanaka, J., & You, W. ACS MACRO LETTERS, 12(10):1306–1310, September, 2023. doi abstract bibtex Here, we report a simple approach for end group functionalization of linear polymers and graft copolymers via an interchange process of reversible addition-fragmentation chain transfer (RAFT) polymerization chain transfer agents (CTAs). The high functional group tolerance of the RAFT process allows a library of functionalities to be introduced. Moreover, this approach allows multiple functional groups to be installed simultaneously. Furthermore, as an alternative to end group analysis, we report the utility of the supernatant of the reaction mixture to determine the degree of functionalization.
@article{courtney_polymer_2023,
title = {Polymer {Functionalization} by {RAFT} {Interchange}},
volume = {12},
issn = {2161-1653},
doi = {10.1021/acsmacrolett.3c00495},
abstract = {Here, we report a simple approach for end group functionalization of linear polymers and graft copolymers via an interchange process of reversible addition-fragmentation chain transfer (RAFT) polymerization chain transfer agents (CTAs). The high functional group tolerance of the RAFT process allows a library of functionalities to be introduced. Moreover, this approach allows multiple functional groups to be installed simultaneously. Furthermore, as an alternative to end group analysis, we report the utility of the supernatant of the reaction mixture to determine the degree of functionalization.},
number = {10},
urldate = {2023-10-10},
journal = {ACS MACRO LETTERS},
author = {Courtney, Owen Reid and Clouthier, Samantha Marie and Perrier, Sebastien and Tanaka, Joji and You, Wei},
month = sep,
year = {2023},
pages = {1306--1310},
}
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