@article{damario_towards_2022,
	title = {Towards time resolved characterization of electrochemical reactions: electrochemically-induced {Raman} spectroscopy},
	volume = {13},
	issn = {2041-6539},
	shorttitle = {Towards time resolved characterization of electrochemical reactions},
	url = {https://pubs.rsc.org/en/content/articlelanding/2022/sc/d2sc01967a},
	doi = {10.1039/D2SC01967A},
	abstract = {Structural characterization of transient electrochemical species in the sub-millisecond time scale is the all-time wish of any electrochemist. Presently, common time resolution of structural spectro-electrochemical methods is about 0.1 seconds. Herein, a transient spectro-electrochemical Raman setup of easy implementation is described which allows sub-ms time resolution. The technique studies electrochemical processes by initiating the reaction with an electric potential (or current) pulse and analyses the product with a synchronized laser pulse of the modified Raman spectrometer. The approach was validated by studying a known redox driven isomerization of a Ru-based molecular switch grafted, as monolayer, on a SERS active Au microelectrode. Density-functional-theory calculations confirmed the spectral assignments to sub-ms transient species. This study paves the way to a new generation of time-resolved spectro-electrochemical techniques which will be of fundamental help in the development of next generation electrolizers, fuel cells and batteries.},
	language = {en},
	number = {36},
	urldate = {2024-10-16},
	journal = {Chemical Science},
	author = {D'Amario, Luca and Stella, Maria Bruna and Edvinsson, Tomas and Persico, Maurizio and Messinger, Johannes and Dau, Holger},
	month = sep,
	year = {2022},
	note = {Publisher: The Royal Society of Chemistry},
	pages = {10734--10742},
}

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Herein, a transient spectro-electrochemical Raman setup of easy implementation is described which allows sub-ms time resolution. The technique studies electrochemical processes by initiating the reaction with an electric potential (or current) pulse and analyses the product with a synchronized laser pulse of the modified Raman spectrometer. The approach was validated by studying a known redox driven isomerization of a Ru-based molecular switch grafted, as monolayer, on a SERS active Au microelectrode. Density-functional-theory calculations confirmed the spectral assignments to sub-ms transient species. This study paves the way to a new generation of time-resolved spectro-electrochemical techniques which will be of fundamental help in the development of next generation electrolizers, fuel cells and batteries.","language":"en","number":"36","urldate":"2024-10-16","journal":"Chemical Science","author":[{"propositions":[],"lastnames":["D'Amario"],"firstnames":["Luca"],"suffixes":[]},{"propositions":[],"lastnames":["Stella"],"firstnames":["Maria","Bruna"],"suffixes":[]},{"propositions":[],"lastnames":["Edvinsson"],"firstnames":["Tomas"],"suffixes":[]},{"propositions":[],"lastnames":["Persico"],"firstnames":["Maurizio"],"suffixes":[]},{"propositions":[],"lastnames":["Messinger"],"firstnames":["Johannes"],"suffixes":[]},{"propositions":[],"lastnames":["Dau"],"firstnames":["Holger"],"suffixes":[]}],"month":"September","year":"2022","note":"Publisher: The Royal Society of Chemistry","pages":"10734–10742","bibtex":"@article{damario_towards_2022,\n\ttitle = {Towards time resolved characterization of electrochemical reactions: electrochemically-induced {Raman} spectroscopy},\n\tvolume = {13},\n\tissn = {2041-6539},\n\tshorttitle = {Towards time resolved characterization of electrochemical reactions},\n\turl = {https://pubs.rsc.org/en/content/articlelanding/2022/sc/d2sc01967a},\n\tdoi = {10.1039/D2SC01967A},\n\tabstract = {Structural characterization of transient electrochemical species in the sub-millisecond time scale is the all-time wish of any electrochemist. Presently, common time resolution of structural spectro-electrochemical methods is about 0.1 seconds. Herein, a transient spectro-electrochemical Raman setup of easy implementation is described which allows sub-ms time resolution. The technique studies electrochemical processes by initiating the reaction with an electric potential (or current) pulse and analyses the product with a synchronized laser pulse of the modified Raman spectrometer. The approach was validated by studying a known redox driven isomerization of a Ru-based molecular switch grafted, as monolayer, on a SERS active Au microelectrode. Density-functional-theory calculations confirmed the spectral assignments to sub-ms transient species. This study paves the way to a new generation of time-resolved spectro-electrochemical techniques which will be of fundamental help in the development of next generation electrolizers, fuel cells and batteries.},\n\tlanguage = {en},\n\tnumber = {36},\n\turldate = {2024-10-16},\n\tjournal = {Chemical Science},\n\tauthor = {D'Amario, Luca and Stella, Maria Bruna and Edvinsson, Tomas and Persico, Maurizio and Messinger, Johannes and Dau, Holger},\n\tmonth = sep,\n\tyear = {2022},\n\tnote = {Publisher: The Royal Society of Chemistry},\n\tpages = {10734--10742},\n}\n\n\n\n","author_short":["D'Amario, L.","Stella, M. 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