Nano-spots induced break of the chemical inertness of boron: a new route toward reversible hydrogen storage applications. Depardieu, M., Janot, R., Sanchez, C., Deleuze, H., Gervais, C., Birot, M., Morcrette, M., & Backov, R. Journal of Materials Chemistry A, 2(21):7694--7701, May, 2014. ![Nano-spots induced break of the chemical inertness of boron: a new route toward reversible hydrogen storage applications [link]](https://bibbase.org/img/filetypes/link.svg "link")
Paper doi abstract bibtex Novel LiBH4–metal-loaded carbonaceous foams have been designed to trigger reversible hydrogen storage properties. The metallic nanoparticles favour preferential wetting of LiBH4 on their surface and subsequent nucleation and growth, a configuration in which borate formation is strongly minimized. A cooperative effect between lower boron oxidation and the presence of metallic particles bearing intrinsic high heat capacity (acting as high temperature nanospots) promotes a strong improvement toward the rehydrogenation process, where the chemical inertness of boron has been overcome in this way for the first time. Hence, the LiBH4–M@C-HIPE(25HF) hybrid macrocellular foams (with M = Pd or Au) facilitate a reversible hydrogen storage process with a remnant capacity of about 7.4 wt% H2 (related to LiBH4) after 5 desorption–absorption ) hybrid…” and throughout the article should “absorption” be changed to “adsorption”??\textgreatercycles.
@article{ depardieu_nano-spots_2014,
title = {Nano-spots induced break of the chemical inertness of boron: a new route toward reversible hydrogen storage applications},
volume = {2},
shorttitle = {Nano-spots induced break of the chemical inertness of boron},
url = {http://pubs.rsc.org/en/content/articlelanding/2014/ta/c4ta00736k},
doi = {10.1039/C4TA00736K},
abstract = {Novel LiBH4–metal-loaded carbonaceous foams have been designed to trigger reversible hydrogen storage properties. The metallic nanoparticles favour preferential wetting of LiBH4 on their surface and subsequent nucleation and growth, a configuration in which borate formation is strongly minimized. A cooperative effect between lower boron oxidation and the presence of metallic particles bearing intrinsic high heat capacity (acting as high temperature nanospots) promotes a strong improvement toward the rehydrogenation process, where the chemical inertness of boron has been overcome in this way for the first time. Hence, the LiBH4–M@C-HIPE(25HF) hybrid macrocellular foams (with M = Pd or Au) facilitate a reversible hydrogen storage process with a remnant capacity of about 7.4 wt% H2 (related to LiBH4) after 5 desorption–absorption ) hybrid…” and throughout the article should “absorption” be changed to “adsorption”??{\textgreater}cycles.},
language = {en},
number = {21},
urldate = {2014-11-05},
journal = {Journal of Materials Chemistry A},
author = {Depardieu, Martin and Janot, Raphaël and Sanchez, Clément and Deleuze, Hervé and Gervais, Christel and Birot, Marc and Morcrette, Mathieu and Backov, Rénal},
month = {May},
year = {2014},
pages = {7694--7701},
file = {Snapshot:C\:\\Users\̧onsultation\\AppData\\Roaming\\Mozilla\\Firefox\\Profiles\\1rk8mjlp.julien\\zotero\\storage\\E4GTUT4H\̧4ta00736k.html:text/html}
}
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Hence, the LiBH4–M@C-HIPE(25HF) hybrid macrocellular foams (with M = Pd or Au) facilitate a reversible hydrogen storage process with a remnant capacity of about 7.4 wt% H2 (related to LiBH4) after 5 desorption–absorption ) hybrid…” and throughout the article should “absorption” be changed to “adsorption”??\\textgreatercycles.","author":["Depardieu, Martin","Janot, Raphaël","Sanchez, Clément","Deleuze, Hervé","Gervais, Christel","Birot, Marc","Morcrette, Mathieu","Backov, Rénal"],"author_short":["Depardieu, M.","Janot, R.","Sanchez, C.","Deleuze, H.","Gervais, C.","Birot, M.","Morcrette, M.","Backov, R."],"bibtex":"@article{ depardieu_nano-spots_2014,\n title = {Nano-spots induced break of the chemical inertness of boron: a new route toward reversible hydrogen storage applications},\n volume = {2},\n shorttitle = {Nano-spots induced break of the chemical inertness of boron},\n url = {http://pubs.rsc.org/en/content/articlelanding/2014/ta/c4ta00736k},\n doi = {10.1039/C4TA00736K},\n abstract = {Novel LiBH4–metal-loaded carbonaceous foams have been designed to trigger reversible hydrogen storage properties. The metallic nanoparticles favour preferential wetting of LiBH4 on their surface and subsequent nucleation and growth, a configuration in which borate formation is strongly minimized. A cooperative effect between lower boron oxidation and the presence of metallic particles bearing intrinsic high heat capacity (acting as high temperature nanospots) promotes a strong improvement toward the rehydrogenation process, where the chemical inertness of boron has been overcome in this way for the first time. 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