Freezing-induced ordering of block copolymer micelles. Dhainaut, J., Piana, G., Deville, S., Guizard, C., & Klotz, M. Chem. Commun., 50(83):12572–12574, 2014. Paper doi abstract bibtex Silica monoliths presenting both hierarchical and mesostructured porosity were obtained by the combination of ice-templating and block-copolymers following a freezing-induced self-assembly process. , We demonstrate here the ordering of block copolymer micelles by ice templating, below 0 °C. We used this for the preparation of silica monoliths that present an ice-templated macroporosity, combined with a 2D hexagonal mesostructure templated by the addition of P123. We propose a mechanism triggered by the progressive freezing-induced concentration.
@article{dhainaut_freezing-induced_2014,
title = {Freezing-induced ordering of block copolymer micelles},
volume = {50},
issn = {1359-7345, 1364-548X},
url = {http://xlink.rsc.org/?DOI=C4CC05556J},
doi = {10.1039/C4CC05556J},
abstract = {Silica monoliths presenting both hierarchical and mesostructured porosity were obtained by the combination of ice-templating and block-copolymers following a freezing-induced self-assembly process.
,
We demonstrate here the ordering of block copolymer micelles by ice templating, below 0 °C. We used this for the preparation of silica monoliths that present an ice-templated macroporosity, combined with a 2D hexagonal mesostructure templated by the addition of P123. We propose a mechanism triggered by the progressive freezing-induced concentration.},
language = {en},
number = {83},
urldate = {2020-02-03},
journal = {Chem. Commun.},
author = {Dhainaut, Jérémy and Piana, Giulia and Deville, Sylvain and Guizard, Christian and Klotz, Michaela},
year = {2014},
pages = {12572--12574},
}
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