@article{RN88,
  abstract = {Organometallic derivatives of the cyclotriphosphazene N3P3[OC6H4CH2CN center dot TiClCp2](6) (1), N3P3(O6H5)(5)[OC6H4N center dot W(CO)(5)] (2), N3P3[OC6H4CH2CN center dot Mo(CO)(5)](6) (3), [N3P3(O6H5)(5)(OC5H4N center dot CpRu(PPh3)(2))][PF6] (4), [N3P3(O2C12H8)(2)OC5H4N center dot Ag(PPh3)][OSO2CF3] (5), N3P3[OC6H5](5) [OC5H4N center dot Cu][PF6] (6) and N3P3[OC6H4CH2CN center dot CuCl](6)[PF6](6) (7),were incorporated inside SiO2 through the sol-gel method. The metal-organic nanocomposites of the general formula N3P3[OC6H4CH2CN center dot TiClCp2](6)center dot nSiO(2) (G (1) ), N3P3[OC6H4N center dot W(CO)(5)]center dot nSiO(2) (G (2) ), N3P3[OC6H4CH2CN center dot Mo(CO)(5)](6)center dot nSiO(2) (G (3) ), N3P3(O6H5)(5)OC5H4N center dot CpRu(PPh3)(2)][PF6]center dot nSiO(2) (G (4) ), [N3P3(O2C12H8)(2)OC5H4N center dot Ag(PPh3)][OSO2CF3]center dot nSiO(2) (G (5) ), N3P3[OC6H5](5)[OC5H4N center dot Cu][PF6]center dot(SiO2) (n) (G (6) ), and N3P3[OC6H4CH2CN center dot CuCl](6)[PF6](6)center dot(SiO2) (n) (G (7) ), were characterized by IR spectroscopy; C-12, (31) P and Si-29 MAS NMR measurements as well as UV-Visible diffuse reflectance spectra, indicating the presence of the respective organometallic derivatives of the cyclotriphosphazene incorporated into SiO2. Pyrolysis of these nanocomposites under air at 800 A degrees C gives rise to nanostructured metal-oxides and metal phosphates incorporated into amorphous SiO2, with the presence in some cases of complexes phase mixtures. From some precursors, we obtained metal-oxides/phosphates nanoparticles separated from the SiO2 nanoparticles instead the oxides/phosphates nanoparticles inside the SiO2 matrix. Additionally and for comparison purposes, we used the compound N3P3[NH(CH2)(3)Si(OEt)(3)](6) as gelator. Nanocomposites (G' (1) ), (G' (2) ) and (G' (3) ) exhibited mainly morphological differences while in some cases composition differences when using TEOS as gelator., Some simple metal-containing compounds as (O3SCF3)Ag(PPh3)(HOC5H4N), [CuCl2 center dot NC5H4OH] and [CuCl2 center dot NCCH2C6H4OH]-which are useful models of the most complexes (G (5) ), (G (6) ) and (G (7) ) were also prepared and incorporated in amorphous silica. Their pyrolytic products were compared with those of more complex cyclotriphosphazene analogous. Interestingly, the pyrolysis of the nanocomposite [(O3SCF3)Ag(PPh3)(HOC5H4N)][SiO2] (n) affords the firstly-reported materials containing Ag2O along with SiO2 nanoparticles.},
  added-at = {2019-12-04T03:57:35.000+0100},
  author = {Diaz, C. and Valenzuela, M.L. and Carrillo, D. and Riquelme, J. and Diaz, R.},
  biburl = {https://www.bibsonomy.org/bibtex/265c32203c6a766958aa2cd71c9d7a467/dqcauchile},
  doi = {10.1007/s10904-012-9692-x},
  interhash = {38b7a429abd52fbdbda0490779a651bc},
  intrahash = {65c32203c6a766958aa2cd71c9d7a467},
  issn = {1574-1443},
  journal = {Journal of Inorganic and Organometallic Polymers and Materials},
  keywords = {polysilsesquioxanes, thermolytic silica, phosphoric-acid sol-gel, sol-gel metallic precursors, synthesis, xerogel, dqcauchile copper cyclotriphospahzenes, nanoparticles, thin-films, nanostructures, bridged mesoporous catalyst, transformation,},
  number = 5,
  pages = {1101-1112},
  timestamp = {2019-12-04T03:58:17.000+0100},
  title = {The Inclusion of Organometallic Derivatives of Cyclotriphosphazenes inside Sio2 Matrix and Their Conversion to Nanostructured Metal-Oxides and Phosphates},
  type = {Journal Article},
  url = {/brokenurl#<Go to ISI>://WOS:000307754600022},
  volume = 22,
  year = 2012
}

{"_id":"RdGedDxQafafkMTZn","bibbaseid":"diaz-valenzuela-carrillo-riquelme-diaz-theinclusionoforganometallicderivativesofcyclotriphosphazenesinsidesio2matrixandtheirconversiontonanostructuredmetaloxidesandphosphates-2012","authorIDs":[],"author_short":["Diaz, C.","Valenzuela, M.","Carrillo, D.","Riquelme, J.","Diaz, R."],"bibdata":{"bibtype":"article","type":"Journal Article","abstract":"Organometallic derivatives of the cyclotriphosphazene N3P3[OC6H4CH2CN center dot TiClCp2](6) (1), N3P3(O6H5)(5)[OC6H4N center dot W(CO)(5)] (2), N3P3[OC6H4CH2CN center dot Mo(CO)(5)](6) (3), [N3P3(O6H5)(5)(OC5H4N center dot CpRu(PPh3)(2))][PF6] (4), [N3P3(O2C12H8)(2)OC5H4N center dot Ag(PPh3)][OSO2CF3] (5), N3P3[OC6H5](5) [OC5H4N center dot Cu][PF6] (6) and N3P3[OC6H4CH2CN center dot CuCl](6)[PF6](6) (7),were incorporated inside SiO2 through the sol-gel method. The metal-organic nanocomposites of the general formula N3P3[OC6H4CH2CN center dot TiClCp2](6)center dot nSiO(2) (G (1) ), N3P3[OC6H4N center dot W(CO)(5)]center dot nSiO(2) (G (2) ), N3P3[OC6H4CH2CN center dot Mo(CO)(5)](6)center dot nSiO(2) (G (3) ), N3P3(O6H5)(5)OC5H4N center dot CpRu(PPh3)(2)][PF6]center dot nSiO(2) (G (4) ), [N3P3(O2C12H8)(2)OC5H4N center dot Ag(PPh3)][OSO2CF3]center dot nSiO(2) (G (5) ), N3P3[OC6H5](5)[OC5H4N center dot Cu][PF6]center dot(SiO2) (n) (G (6) ), and N3P3[OC6H4CH2CN center dot CuCl](6)[PF6](6)center dot(SiO2) (n) (G (7) ), were characterized by IR spectroscopy; C-12, (31) P and Si-29 MAS NMR measurements as well as UV-Visible diffuse reflectance spectra, indicating the presence of the respective organometallic derivatives of the cyclotriphosphazene incorporated into SiO2. Pyrolysis of these nanocomposites under air at 800 A degrees C gives rise to nanostructured metal-oxides and metal phosphates incorporated into amorphous SiO2, with the presence in some cases of complexes phase mixtures. From some precursors, we obtained metal-oxides/phosphates nanoparticles separated from the SiO2 nanoparticles instead the oxides/phosphates nanoparticles inside the SiO2 matrix. Additionally and for comparison purposes, we used the compound N3P3[NH(CH2)(3)Si(OEt)(3)](6) as gelator. Nanocomposites (G' (1) ), (G' (2) ) and (G' (3) ) exhibited mainly morphological differences while in some cases composition differences when using TEOS as gelator., Some simple metal-containing compounds as (O3SCF3)Ag(PPh3)(HOC5H4N), [CuCl2 center dot NC5H4OH] and [CuCl2 center dot NCCH2C6H4OH]-which are useful models of the most complexes (G (5) ), (G (6) ) and (G (7) ) were also prepared and incorporated in amorphous silica. Their pyrolytic products were compared with those of more complex cyclotriphosphazene analogous. Interestingly, the pyrolysis of the nanocomposite [(O3SCF3)Ag(PPh3)(HOC5H4N)][SiO2] (n) affords the firstly-reported materials containing Ag2O along with SiO2 nanoparticles.","added-at":"2019-12-04T03:57:35.000+0100","author":[{"propositions":[],"lastnames":["Diaz"],"firstnames":["C."],"suffixes":[]},{"propositions":[],"lastnames":["Valenzuela"],"firstnames":["M.L."],"suffixes":[]},{"propositions":[],"lastnames":["Carrillo"],"firstnames":["D."],"suffixes":[]},{"propositions":[],"lastnames":["Riquelme"],"firstnames":["J."],"suffixes":[]},{"propositions":[],"lastnames":["Diaz"],"firstnames":["R."],"suffixes":[]}],"biburl":"https://www.bibsonomy.org/bibtex/265c32203c6a766958aa2cd71c9d7a467/dqcauchile","doi":"10.1007/s10904-012-9692-x","interhash":"38b7a429abd52fbdbda0490779a651bc","intrahash":"65c32203c6a766958aa2cd71c9d7a467","issn":"1574-1443","journal":"Journal of Inorganic and Organometallic Polymers and Materials","keywords":"polysilsesquioxanes, thermolytic silica, phosphoric-acid sol-gel, sol-gel metallic precursors, synthesis, xerogel, dqcauchile copper cyclotriphospahzenes, nanoparticles, thin-films, nanostructures, bridged mesoporous catalyst, transformation,","number":"5","pages":"1101-1112","timestamp":"2019-12-04T03:58:17.000+0100","title":"The Inclusion of Organometallic Derivatives of Cyclotriphosphazenes inside Sio2 Matrix and Their Conversion to Nanostructured Metal-Oxides and Phosphates","url":"/brokenurl#<Go to ISI>://WOS:000307754600022","volume":"22","year":"2012","bibtex":"@article{RN88,\n abstract = {Organometallic derivatives of the cyclotriphosphazene N3P3[OC6H4CH2CN center dot TiClCp2](6) (1), N3P3(O6H5)(5)[OC6H4N center dot W(CO)(5)] (2), N3P3[OC6H4CH2CN center dot Mo(CO)(5)](6) (3), [N3P3(O6H5)(5)(OC5H4N center dot CpRu(PPh3)(2))][PF6] (4), [N3P3(O2C12H8)(2)OC5H4N center dot Ag(PPh3)][OSO2CF3] (5), N3P3[OC6H5](5) [OC5H4N center dot Cu][PF6] (6) and N3P3[OC6H4CH2CN center dot CuCl](6)[PF6](6) (7),were incorporated inside SiO2 through the sol-gel method. The metal-organic nanocomposites of the general formula N3P3[OC6H4CH2CN center dot TiClCp2](6)center dot nSiO(2) (G (1) ), N3P3[OC6H4N center dot W(CO)(5)]center dot nSiO(2) (G (2) ), N3P3[OC6H4CH2CN center dot Mo(CO)(5)](6)center dot nSiO(2) (G (3) ), N3P3(O6H5)(5)OC5H4N center dot CpRu(PPh3)(2)][PF6]center dot nSiO(2) (G (4) ), [N3P3(O2C12H8)(2)OC5H4N center dot Ag(PPh3)][OSO2CF3]center dot nSiO(2) (G (5) ), N3P3[OC6H5](5)[OC5H4N center dot Cu][PF6]center dot(SiO2) (n) (G (6) ), and N3P3[OC6H4CH2CN center dot CuCl](6)[PF6](6)center dot(SiO2) (n) (G (7) ), were characterized by IR spectroscopy; C-12, (31) P and Si-29 MAS NMR measurements as well as UV-Visible diffuse reflectance spectra, indicating the presence of the respective organometallic derivatives of the cyclotriphosphazene incorporated into SiO2. Pyrolysis of these nanocomposites under air at 800 A degrees C gives rise to nanostructured metal-oxides and metal phosphates incorporated into amorphous SiO2, with the presence in some cases of complexes phase mixtures. From some precursors, we obtained metal-oxides/phosphates nanoparticles separated from the SiO2 nanoparticles instead the oxides/phosphates nanoparticles inside the SiO2 matrix. Additionally and for comparison purposes, we used the compound N3P3[NH(CH2)(3)Si(OEt)(3)](6) as gelator. Nanocomposites (G' (1) ), (G' (2) ) and (G' (3) ) exhibited mainly morphological differences while in some cases composition differences when using TEOS as gelator., Some simple metal-containing compounds as (O3SCF3)Ag(PPh3)(HOC5H4N), [CuCl2 center dot NC5H4OH] and [CuCl2 center dot NCCH2C6H4OH]-which are useful models of the most complexes (G (5) ), (G (6) ) and (G (7) ) were also prepared and incorporated in amorphous silica. Their pyrolytic products were compared with those of more complex cyclotriphosphazene analogous. Interestingly, the pyrolysis of the nanocomposite [(O3SCF3)Ag(PPh3)(HOC5H4N)][SiO2] (n) affords the firstly-reported materials containing Ag2O along with SiO2 nanoparticles.},\n added-at = {2019-12-04T03:57:35.000+0100},\n author = {Diaz, C. and Valenzuela, M.L. and Carrillo, D. and Riquelme, J. and Diaz, R.},\n biburl = {https://www.bibsonomy.org/bibtex/265c32203c6a766958aa2cd71c9d7a467/dqcauchile},\n doi = {10.1007/s10904-012-9692-x},\n interhash = {38b7a429abd52fbdbda0490779a651bc},\n intrahash = {65c32203c6a766958aa2cd71c9d7a467},\n issn = {1574-1443},\n journal = {Journal of Inorganic and Organometallic Polymers and Materials},\n keywords = {polysilsesquioxanes, thermolytic silica, phosphoric-acid sol-gel, sol-gel metallic precursors, synthesis, xerogel, dqcauchile copper cyclotriphospahzenes, nanoparticles, thin-films, nanostructures, bridged mesoporous catalyst, transformation,},\n number = 5,\n pages = {1101-1112},\n timestamp = {2019-12-04T03:58:17.000+0100},\n title = {The Inclusion of Organometallic Derivatives of Cyclotriphosphazenes inside Sio2 Matrix and Their Conversion to Nanostructured Metal-Oxides and Phosphates},\n type = {Journal Article},\n url = {/brokenurl#<Go to ISI>://WOS:000307754600022},\n volume = 22,\n year = 2012\n}\n\n","author_short":["Diaz, C.","Valenzuela, M.","Carrillo, D.","Riquelme, J.","Diaz, R."],"key":"RN88","id":"RN88","bibbaseid":"diaz-valenzuela-carrillo-riquelme-diaz-theinclusionoforganometallicderivativesofcyclotriphosphazenesinsidesio2matrixandtheirconversiontonanostructuredmetaloxidesandphosphates-2012","role":"author","urls":{"Paper":"http://www.bibsonomy.org/brokenurl#%3CGo%20to%20ISI%3E://WOS:000307754600022"},"keyword":["polysilsesquioxanes","thermolytic silica","phosphoric-acid sol-gel","sol-gel metallic precursors","synthesis","xerogel","dqcauchile copper cyclotriphospahzenes","nanoparticles","thin-films","nanostructures","bridged mesoporous catalyst","transformation",""],"downloads":0},"bibtype":"article","biburl":"http://www.bibsonomy.org/bib/author/valenzuela?items=1000","creationDate":"2020-08-18T15:31:02.106Z","downloads":0,"keywords":["polysilsesquioxanes","thermolytic silica","phosphoric-acid sol-gel","sol-gel metallic precursors","synthesis","xerogel","dqcauchile copper cyclotriphospahzenes","nanoparticles","thin-films","nanostructures","bridged mesoporous catalyst","transformation",""],"search_terms":["inclusion","organometallic","derivatives","cyclotriphosphazenes","inside","sio2","matrix","conversion","nanostructured","metal","oxides","phosphates","diaz","valenzuela","carrillo","riquelme","diaz"],"title":"The Inclusion of Organometallic Derivatives of Cyclotriphosphazenes inside Sio2 Matrix and Their Conversion to Nanostructured Metal-Oxides and Phosphates","year":2012,"dataSources":["nBeLTcg3g4P8FeZpE"]}