Rotational propensities in the state selection of NH3+ by pulsed-field ionization. Dickinson, H, Rolland, D, & Softley, T P Philosophical Transactions of the Royal Society of London A, 355(1729):1585–1606, August, 1997. Publisher: ROYAL SOC LONDON Type: Article Place: 6 CARLTON HOUSE TERRACE, LONDON, ENGLAND SW1Y 5AGabstract bibtex NH3+ ions have been prepared in unique vibration-rotation states v(2)(+), N+, K+, by pulsed-field ionization of high Rydberg states of NH3, populated by two-colour multiphoton excitation. The selected states, ranging from v(2)(+) = 0 to 7 and N+, K+ less than or equal to 4 are accessed via the B and C' states as intermediates. The application of multichannel quantum defect theory to the understanding of the rotational propensities in the mass-analysed threshold ionization spectra is discussed. It is demonstrated that the interactions of the Rydberg pseudo-continuum both with bound Rydberg states and with other continua can be modelled.
@article{softley1997,
title = {Rotational propensities in the state selection of {NH3}+ by pulsed-field ionization},
volume = {355},
abstract = {NH3+ ions have been prepared in unique vibration-rotation states
v(2)(+), N+, K+, by pulsed-field ionization of high Rydberg states
of NH3, populated by two-colour multiphoton excitation. The selected
states, ranging from v(2)(+) = 0 to 7 and N+, K+ less than or equal
to 4 are accessed via the B and C' states as intermediates. The application
of multichannel quantum defect theory to the understanding of the
rotational propensities in the mass-analysed threshold ionization
spectra is discussed. It is demonstrated that the interactions of
the Rydberg pseudo-continuum both with bound Rydberg states and with
other continua can be modelled.},
number = {1729},
journal = {Philosophical Transactions of the Royal Society of London A},
author = {Dickinson, H and Rolland, D and Softley, T P},
month = aug,
year = {1997},
note = {Publisher: ROYAL SOC LONDON
Type: Article
Place: 6 CARLTON HOUSE TERRACE, LONDON, ENGLAND SW1Y 5AG},
keywords = {\#nosource},
pages = {1585--1606},
}
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