The role of perovskite composition, dimensionality, and additives in lead-free perovskite solar cell longevity: a review. Diguna, L. J., Lim, A., Firdaus, Y., Widiapradja, L. J., Sidiq, D. H., Melnychenko, A. M., Utomo, S. T., Arramel, A., & Birowosuto, M. D. Sustainable Energy & Fuels, 9(23):6413–6438, 2025. ![The role of perovskite composition, dimensionality, and additives in lead-free perovskite solar cell longevity: a review [link]](https://bibbase.org/img/filetypes/link.svg "link")
Paper doi abstract bibtex This work presents a review of photovoltaic technologies with hybrid perovskite structures stabilized by A-, B-, and X-site tuning. Labeled ions, additives, passivation layers, and protective features highlight enhanced durability and performance. , To date, the future of perovskite solar cells (PSCs) focuses on overcoming stability and toxicity challenges through advanced material engineering and device design. In this review, we present an overview and current progress of lead-free-based PSCs such as tin-, stibium-, bismuth-, and germanium-based systems. Development of B-site doping and A/X-site engineering to mitigate oxidation, defect formation, and phase segregation while maintaining lattice integrity is extensively discussed. Two distinct factors that could influence PSC stability are outlined: intrinsic nature of materials and environmental factors. Thus, we unveil the implications of hybrid two-dimensional/three-dimensional (2D/3D) architectures, exemplifying the synergistic effects of the high charge mobility of 3D perovskites and the environmental robustness of 2D layers. Here, we revisit compositional tuning, dimensionality control, additive engineering, and interfacial passivation, potentially enhancing the next-generation PSCs with high power conversion efficiency and long-term stability. These directions would trigger the realization of environmentally sustainable solar-to-electricity devices, transitioning from lab-scale innovation to renewable energy solutions.
@article{digunaRolePerovskiteComposition2025,
title = {The role of perovskite composition, dimensionality, and additives in lead-free perovskite solar cell longevity: a review},
volume = {9},
issn = {2398-4902},
shorttitle = {The role of perovskite composition, dimensionality, and additives in lead-free perovskite solar cell longevity},
url = {https://xlink.rsc.org/?DOI=D5SE00738K},
doi = {10.1039/D5SE00738K},
abstract = {This work presents a review of photovoltaic technologies with hybrid perovskite structures stabilized by A-, B-, and X-site tuning. Labeled ions, additives, passivation layers, and protective features highlight enhanced durability and performance.
,
To date, the future of perovskite solar cells (PSCs) focuses on overcoming stability and toxicity challenges through advanced material engineering and device design. In this review, we present an overview and current progress of lead-free-based PSCs such as tin-, stibium-, bismuth-, and germanium-based systems. Development of B-site doping and A/X-site engineering to mitigate oxidation, defect formation, and phase segregation while maintaining lattice integrity is extensively discussed. Two distinct factors that could influence PSC stability are outlined: intrinsic nature of materials and environmental factors. Thus, we unveil the implications of hybrid two-dimensional/three-dimensional (2D/3D) architectures, exemplifying the synergistic effects of the high charge mobility of 3D perovskites and the environmental robustness of 2D layers. Here, we revisit compositional tuning, dimensionality control, additive engineering, and interfacial passivation, potentially enhancing the next-generation PSCs with high power conversion efficiency and long-term stability. These directions would trigger the realization of environmentally sustainable solar-to-electricity devices, transitioning from lab-scale innovation to renewable energy solutions.},
language = {en},
number = {23},
urldate = {2026-06-22},
journal = {Sustainable Energy \& Fuels},
author = {Diguna, Lina Jaya and Lim, Alice and Firdaus, Yuliar and Widiapradja, Livia Janice and Sidiq, David Hadid and Melnychenko, Anna Magdalena and Utomo, Setiyadi Tri and Arramel, Arramel and Birowosuto, Muhammad Danang},
year = {2025},
pages = {6413--6438},
}
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Labeled ions, additives, passivation layers, and protective features highlight enhanced durability and performance. , To date, the future of perovskite solar cells (PSCs) focuses on overcoming stability and toxicity challenges through advanced material engineering and device design. In this review, we present an overview and current progress of lead-free-based PSCs such as tin-, stibium-, bismuth-, and germanium-based systems. Development of B-site doping and A/X-site engineering to mitigate oxidation, defect formation, and phase segregation while maintaining lattice integrity is extensively discussed. Two distinct factors that could influence PSC stability are outlined: intrinsic nature of materials and environmental factors. Thus, we unveil the implications of hybrid two-dimensional/three-dimensional (2D/3D) architectures, exemplifying the synergistic effects of the high charge mobility of 3D perovskites and the environmental robustness of 2D layers. 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