Implication of barrier fluctuations on the rate of weakly adiabatic electron transfer. Dybiec, B., Gudowska-Nowak, E., & Góra, P. International Journal of Modern Physics C, 2002. doi abstract bibtex The problem of escape of a Brownian particle in a cusp-shaped metastable potential is of special importance in nonadiabatic and weakly-adiabatic rate theory for electron transfer (ET) reactions. For the weakly-adiabatic reactions, the reaction follows an adiabaticity criterion in the presence of a sharp barrier. In contrast to the nonadiabatic case, the ET kinetics can be, however considerably influenced by the medium dynamics. In this paper, the problem of the escape time over a dichotomously fluctuating cusp barrier is discussed with its relevance to the high temperature ET reactions in condensed media.
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title = {Implication of barrier fluctuations on the rate of weakly adiabatic electron transfer},
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year = {2002},
keywords = {Escape time,Kinetic rate,Numerical evaluation of the resonant activation},
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abstract = {The problem of escape of a Brownian particle in a cusp-shaped metastable potential is of special importance in nonadiabatic and weakly-adiabatic rate theory for electron transfer (ET) reactions. For the weakly-adiabatic reactions, the reaction follows an adiabaticity criterion in the presence of a sharp barrier. In contrast to the nonadiabatic case, the ET kinetics can be, however considerably influenced by the medium dynamics. In this paper, the problem of the escape time over a dichotomously fluctuating cusp barrier is discussed with its relevance to the high temperature ET reactions in condensed media.},
bibtype = {article},
author = {Dybiec, B. and Gudowska-Nowak, E. and Góra, P.F.},
doi = {10.1142/S0129183102004078},
journal = {International Journal of Modern Physics C},
number = {9}
}
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